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Thermal Properties and Ion Mobility in Complex Fluorides (C2H6NO2)SbF4 and (C2H6NO2)3[InF6]

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Abstract

Thermal properties and ion mobility of (C2H6NO2)SbF4 in antimony(III) fluoride with glycine are studied by DSC, 19F NMR, and 1H NMR methods in the temperature region of 150–450 K. Dynamic processes in complex fluorides (C2H6NO2)SbF4 and (C2H6NO2)3[InF6] are juxtaposed. The NMR data reported earlier for compound (GlyH)3[InF6] are reanalyzed with some corrections. The relationship between NMR data, ion mobility, and the structure of these complexes is discussed. Possible mechanisms of ion mobility developing in complex fluorides Sb(III) and In(III) with glycine are proposed.

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References

  1. M. Fleck and A. M. Petrosyan. Salts of Amino Acids: Crystallization, Structure and Properties. Springer: Netherlands, Dordrecht, 2014).

    Google Scholar 

  2. G. Giester, V. V. Ghazaryan, M. Fleck, and A. M. Petrosyan. J. Fluor. Chem., 2017, 195, 26.

    CAS  Google Scholar 

  3. V. Ya. Kavun, R. L. Davidovich, A. A. Udovenko, M. M. Polyantsev, and V. B. Logvinova. J. Fluorine Chem., 2018, 212, 13.

    Google Scholar 

  4. R. L. Davidovich, V. B. Logvinova, L. A. Zemnukhova, A. A. Udovenko, and I. P. Kondratyuk. Koord. Khim., 1991, 17, 1342.

    CAS  Google Scholar 

  5. L. A. Zemnukhova, R. L. Davidovich, A. A. Udovenko, and E. V. Kovaleva. Russ. J. Coord. Chem, 2005, 31, 115.

    CAS  Google Scholar 

  6. V. Ya. Kavun, N. A. Didenko, N. V. Makarenko, A. B. Slobodyuk, E. B. Merkulov, N. F. Uvarov, and L. A. Zemnukhova. Russ. J. Inorg. Chem., 2012, 57, 1262.

    Google Scholar 

  7. N. V. Makarenko, V. Ya. Kavun, A. A. Udovenko, E. V. Kovaleva, and L. A. Zemnukhova. J. Fluorine Chem., 2018, 213, 56.

    CAS  Google Scholar 

  8. V. Ya. Kavun and V. I. Sergienko. Diffusive Mobility and Ion Transport in Crystalline and Amorphous Group IV Element and Antimony(III) Fluorides [in Rissian]. Dal’nauka: Vladivostok, 2004)

    Google Scholar 

  9. L. A. Zemnukhova and R. L. Davidovich. Z. Naturforsch, Section A-A, J. Phys. Sci., 1998, 53a, 573.

    Google Scholar 

  10. R. Mary Jenila, I. Vetha Potheher, M. Vimalan, and T. R. Rajasekaran. J. Mater. Sci.: Mater Electron, 2015, 26, 6419.

    Google Scholar 

  11. E. Chacko, S. M. Linet, C. M. N. Priya, C. Vesta, B. M. Boaz, and S. J. Dhas. Indian J. Pure Appl. Phys., 2006, 44, 260.

    CAS  Google Scholar 

  12. P. Rawat, S. K. Saroj, J. Kaur, and R. Nagarajan. J. Luminec, 2019, 210, 392.

    CAS  Google Scholar 

  13. C. Besky Job, K. Ganesan, and J. Benet Charles. Der Pharma Chemica, 2011, 3, 41.

    Google Scholar 

  14. M. P. Borzenkova, F. V. Kalinchenko, A. V. Novoselova, A. K. Ivanov-Schits, and N. I. Sorokin. Russ. J. Inorg. Chem., 1984, 29, 703.

    CAS  Google Scholar 

  15. Y. N. Moskvich, B. I. Cherkasov, A. M. Polyakov, A. A. Sukhovskii, and R. L. Davidovich. Phys. Status Solidi B, 1989, 156, 615.

    CAS  Google Scholar 

  16. K. Yamada, Y. Ohnuki, H. Ohki, and T. Okuda. Chem. Lett., 1999, 28, 627.

    Google Scholar 

  17. V. Ya. Kavun, N. F. Uvarov, A. B. Slobodyuk, O. V. Brovkina, L. A. Zemnukhova, and V. I. Sergienko. Russ. J. Electrochem., 2005, 41, 488.

    Google Scholar 

  18. C. Besky Job, R. T. Ananth Kumar, and S. Paulraj. Optik, 2016, 127, 55.

    Google Scholar 

  19. A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva, and R. L. Davidovich. Russ. J. Coord. Chem., 2005, 31, 225.

    CAS  Google Scholar 

  20. L. A. Zemnukhova, R. L. Davidovich, A. A. Udovenko, and E. V. Kovaleva. Russ. J. Coord. Chem., 2005, 31, 115.

    CAS  Google Scholar 

  21. A. A. Udovenko, R. L. Davidovich, L. A. Zemnukhova, E. V. Kovaleva, and N. V. Makarenko. J. Struct. Chem., 2010, 51, 540–544.

    CAS  Google Scholar 

  22. A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, L. A. Zemnukhova, and E. V. Kovaleva. J. Struct. Chem., 2010, 51, 765–768.

    CAS  Google Scholar 

  23. A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, L. A. Zemnukhova, and E. V. Kovaleva. J. Struct. Chem., 2010, 51, 904.

    CAS  Google Scholar 

  24. A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, L. A. Zemnukhova, and E. V. Kovaleva. J. Struct. Chem., 2011, 52, 616.

    CAS  Google Scholar 

  25. V. Ya. Kavun, A. A. Udovenko, A. B. Slobodyuk, N. V. Makarenko, E. V. Kovaleva, and L. A. Zemnukhova. J. Fluorine Chem., 2019, 217, 50.

    Google Scholar 

  26. S. E. Ashbrook and D. M. Dawson. Nucl. Magn. Reson., 2016, 45, 1.

    CAS  Google Scholar 

  27. A. G. Lundin and E. I. Fedin. NMR Spectroscopy [in Russian]. Nauka: Moscow, 1986).

    Google Scholar 

  28. R. Youngman. Materials, 2018, 11, 476.

    PubMed Central  Google Scholar 

  29. S. P. Gabuda and A. G. Lundin. Internal Mobility in Solids [in Russian]. Nauka: Novosibirsk, 1986).

    Google Scholar 

  30. G. Scholz, T. Krahl, M. Ahrens, C. Martineau, J. Y. Buzaré, C. Jäger, and E. Kemnitz. J. Fluorine Chem., 2011, 132, 244.

    CAS  Google Scholar 

  31. W. Levason, M. E. Light, S. Maheshwari G. Reid, and W. Zhang. Dalton Trans., 2011, 40, 5291.

    CAS  PubMed  Google Scholar 

  32. V. Ya. Kavun, A. A. Udovenko, N. V. Makarenko, L. A. Zemnukhova, and A. B. Podgorbunskii. J. Struct. Chem., 2016, 57, 658.

    Google Scholar 

  33. V. Ya. Kavun, N. F. Uvarov, A. B. Slobodyuk, E. B. Merkulov, and M. M. Polyantsev. J. Solid State Chem., 2018, 263, 203.

    Google Scholar 

  34. V. Ya. Kavun, E. B. Merkulov, A. B. Slobodyuk, M. M. Polyantsev, and O. V. Brovkina. J. Struct. Chem., 2018, 59, 1572.

    Google Scholar 

  35. V. Ya. Kavun, N. F. Uvarov, V. K. Goncharuk, E. B. Merkulov, A. S. Ulikhin, I. A. Telin, and V. I. Kharchenko. Solid State Ionics, 2014, 257, 17.

    Google Scholar 

  36. V. Ya. Kavun, A. V. Gerasimenko, N. F. Uvarov, M. M. Polyantsev, and L. A. Zemnukhova. J. Solid State Chem., 2016, 241, 9.

    Google Scholar 

  37. H. S. Gutowsky and G. E. Pake. J. Chem. Phys., 1950, 18, 162.

    CAS  Google Scholar 

  38. R. Stephen Berry. J. Chem. Phys., 1960, 32, 933.

    Google Scholar 

  39. S. P. Gabuda, V. Ya. Kavun, S. G. Kozlova, and V. V. Terskikh. Russ. J. Coord. Chem., 2003, 29, 1.

    CAS  Google Scholar 

  40. B. I. Cherkasov, Yu. N. Moskvich, A. A. Sukhovskii, and R. L. Davidovich. Phys. Solid State, 1988, 30, 1652.

    CAS  Google Scholar 

  41. T. Merle, J. P. Laval, B. Frit, J. Senegas, G. Grimberg, and J. Strahle. Eur. J. Solid State Inorg. Chem., 1994, 31, 463.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    V. Ya. Kavun, L. A. Zemnukhova, A. A. Udovenko, M. M. Polyantsev, N. V. Makarenko & O. V. Brovkina

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  1. V. Ya. Kavun
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  2. L. A. Zemnukhova
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  3. A. A. Udovenko
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  4. M. M. Polyantsev
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  5. N. V. Makarenko
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  6. O. V. Brovkina
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Correspondence to V. Ya. Kavun.

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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 5, pp. 734–747.

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Kavun, V.Y., Zemnukhova, L.A., Udovenko, A.A. et al. Thermal Properties and Ion Mobility in Complex Fluorides (C2H6NO2)SbF4 and (C2H6NO2)3[InF6]. J Struct Chem 61, 694–706 (2020). https://doi.org/10.1134/S0022476620050042

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  • DOI: https://doi.org/10.1134/S0022476620050042

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