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Crystal and Molecular Structures of Two Salts Based on Polyamine Deribatives

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Abstract

The crystal structures of salts (C18H22N3)(NO3) (I) and (C8H24N4)[ZnCl4]Cl2(II), based on protonated polyamines (diethylenetriamine and N,N′-bis(2-aminoethyl)piperazine) are studied by single crystal X-ray diffraction. Salt I exhibits a wave-like 1D chain formed by N-H⋯O hydrogen bonds from monoprotonated (C18H22N3)+ cations and NO −3 anions. In salt II, multi-protonated N,N′-bis(2-aminoethyl)piperazinium ions are connected into two types of infinite subloop chains through N-H⋯Cl and C-H⋯Cl halogen bonding contacts from (C8H24N4)4+ cations and [ZnCl4]2− and Cl− anions. The analysis of the Hirshfeld surfaces shows the intermolecular interactions involved in the crystal structures. The corresponding quantitative information is presented by fingerprint plots.

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Authors and Affiliations

  1. Department of Chemistry, Changzhi University, Changzhi, P.R. China

    C.-Y. Zhou, F. Su, B.-X. Zhang & C. Han

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  1. C.-Y. Zhou
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  2. F. Su
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  3. B.-X. Zhang
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  4. C. Han
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Correspondence to C.-Y. Zhou.

Additional information

Zhurnal Strukturnoi Khimii, Vol. 60, No. 2, pp. 329–337, February, 2019.

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Zhou, CY., Su, F., Zhang, BX. et al. Crystal and Molecular Structures of Two Salts Based on Polyamine Deribatives. J Struct Chem 60, 315–323 (2019). https://doi.org/10.1134/S0022476619020203

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  • DOI: https://doi.org/10.1134/S0022476619020203

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