Skip to main content
SpringerLink
Log in

Structural evolution of Li-exchaned natrolite at pressure-induced over-hydration: An X-ray diffraction study

  • Applications of Synchrotron Radiation in Structural Chemistry
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The behavior of Li-exchanged natrolite Li1.92Na0.10[Al2.02Si2.98O10]∙2H2O at compression in penetrating (water-containing) medium was studied by in situ synchrotron powder diffraction in diamond anvil cell up to 2.5 GPa. Within 0-1.3 GPa the compression is almost isotropic, and upon the further pressure increase the sample undergoes additional hydration, leading to abrupt volume expansion by 22%, a record value for natrolite. In the proposed model for the high-pressure phase Li2[Al2Si3O10]∙6H2O the Li+ cations have no contact with the framework O-atoms and are surrounded by “water-jacket” in the form of semi-octahedron (tetragonal pyramid) composed of five H2O molecules. Such polyhedra, lining up along the channel axis, are joined through their edges and create a “water” column expanding the structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. A. Belitsky, B. A. Fursenko, S. P. Gabuda, et al., Phys. Chem. Miner., 18, 497 (1992).

    Article  Google Scholar 

  2. Yu. V. Seryotkin, V. V. Bakakin, B. A. Fursenko, et al., Eur. J. Mineral., 17, 305 (2005).

    Article  CAS  Google Scholar 

  3. M. Colligan, Y. Lee, T. Vogt, et al., J. Phys. Chem. B, 109, 18223 (2005).

    Article  CAS  Google Scholar 

  4. Yu. V. Seryotkin and V. V. Bakakin, Eur. J. Mineral., 19, 593 (2007).

    Article  CAS  Google Scholar 

  5. A. Yu. Likhacheva, Yu. V. Seryotkin, A. Yu. Manakov, et al., Z. Kristallogr. Suppl., 26, 405 (2007).

    Article  Google Scholar 

  6. W. H. Baur, D. Kassner, Ch.-H. Kim, and N. H. W. Sieber, Eur. J. Mineral., 2, 761 (1990).

    Article  CAS  Google Scholar 

  7. E. Krogh Andersen, I. G. Krogh Andersen, and G. Ploug-Sørensen, Eur. J. Mineral., 2, 799 (1990).

    Article  CAS  Google Scholar 

  8. Y. Lee, D. Seoung, and Y. Lee, Am. Mineral., 96, 1718 (2011).

    Article  CAS  Google Scholar 

  9. Y. Lee, D. Seoung, Y.-N. Jang, et al., Chem. Eur. J., 19, 5806 (2013).

    Article  CAS  Google Scholar 

  10. D. Seoung, Y. Lee, C.-C. Kao, et al., Chem. Eur. J., 19, 10876 (2013).

    Article  CAS  Google Scholar 

  11. G. M. Sheldrick, Acta Crystallorg., A64, 112 (2008).

  12. R. Boehler, Rev. Sci. Instrum., 77, No. 11, 115103 (2006).

    Article  Google Scholar 

  13. A. Budzianowski and A. Katrusiak, in: High-Pressure Crystallography, A. Katrusiak and P. F. McMillan (eds.), Kluwer Academic Publishers, Dordrecht (2004), pp. 101–112.

  14. R. J. Angel, J. Appl. Crystallorg., 37, 486 (2004).

    Article  CAS  Google Scholar 

  15. S. V. Rashchenko, A. Yu. Likhacheva, and T. B. Bekker, High Pressure Res., 33, 702 (2013).

    Article  Google Scholar 

  16. A. I. Ancharov, A. Yu. Manakov, N. A. Mezentsev, et al., Nucl. Instrum. Methods Phys. Res., Sect. A, 470, 80 (2001).

    Article  CAS  Google Scholar 

  17. A. P. Hammersley, S. O. Svensson, M. Hanfland, et al., High Pressure Res., 14, 235 (1996).

    Article  Google Scholar 

  18. A. C. Larson and R. B. Von Dreele, General Structure Analysis System (GSAS), Los Alamos National Laboratory Report LAUR 86–748 (2000).

    Google Scholar 

  19. R. D. Shannon and C. T. Prewitt, Acta Crystallorg., B 25, 925 (1969).

    Article  CAS  Google Scholar 

  20. V. V. Bakakin and Yu. V. Seryotkin, J. Struct. Chem., 50, S116–S123 (2009).

    Article  CAS  Google Scholar 

  21. W. P. Kuhs, J. L. Fynney, C. Vettier, and D. V. Bliss, J. Chem. Phys., 81, 3612 (1984).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Seryotkin, A. Yu. Likhacheva & S. V. Rashchenko

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    Yu. V. Seryotkin & S. V. Rashchenko

  3. Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. Yu. Likhacheva

Authors
  1. Yu. V. Seryotkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Likhacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Rashchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. V. Seryotkin.

Additional information

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 7, pp. 1453-1462, September-October, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Seryotkin, Y.V., Likhacheva, A.Y. & Rashchenko, S.V. Structural evolution of Li-exchaned natrolite at pressure-induced over-hydration: An X-ray diffraction study. J Struct Chem 57, 1377–1385 (2016). https://doi.org/10.1134/S0022476616070118

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476616070118

Keywords

Search

Navigation