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Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study

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Abstract

Behaviour of hingganite-(Y), Y2□Be2Si2O8(OH)2, on compression to 47 GPa has been studied by synchrotron-based in situ high-pressure single-crystal X-ray diffraction at room temperature in a diamond anvil cell. In the studied pressure range no obvious phase transitions have been observed. The compression of hingganite-(Y) crystal structure is anisotropic, with b axis showing the maximal compressibility. A fit of the experimental pressure–volume data by the Birch-Murnaghan third-order equation of state yielded the bulk modulus of 131(2) GPa and its pressure first derivative of 3.5(2). The difference between high-pressure behaviour of hingganite-(Y) and structurally related datolite is governed by the different chemical nature of interlayer cations.

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Acknowledgments

In situ high-pressure single-crystal X-ray diffraction measurements were carried out at the PETRA III light source at DESY, a member of the Helmholtz Association (HGF). This research was funded by the Russian Science Foundation, grant number 19-77-00038 (to LAG). LSD acknowledge financial support by DFG (DU 393/9-2) grant.

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Authors and Affiliations

  1. Department of Crystallography, Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia

    Liudmila A. Gorelova & Sergey V. Krivovichev

  2. Deutsches Elektronen-Synchrotron (DESY), Petra III, Hamburg, Germany

    Anna S. Pakhomova

  3. Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia

    Sergey V. Krivovichev

  4. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia

    Anatoly V. Kasatkin

  5. Bayerisches Geoinstitut, University of Bayreuth, Bayreuth, Germany

    Leonid S. Dubrovinsky

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  1. Liudmila A. Gorelova
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Correspondence to Liudmila A. Gorelova.

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Gorelova, L.A., Pakhomova, A.S., Krivovichev, S.V. et al. Compressibility of hingganite-(Y): high-pressure single crystal X-ray diffraction study. Phys Chem Minerals 47, 22 (2020). https://doi.org/10.1007/s00269-020-01090-x

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