Skip to main content
SpringerLink
Log in

Crystal structure of a μ-oxo-bridged dimeric iron(III) complex

  • Structure and Properties of Coordination Compounds
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A dimeric [{Fe(5-ClL1)}2(μ-O)], [H2-5-ClL1 = N,N′-bis(5-chloro-2-hydroxybenzylidene)-2-methylpropane-1,2-diamine] tetradentate Schiff-base complex, 1, has been synthesized and its crystal structure has been determined by single crystal X-ray diffraction analysis. Structural analysis of complex 1 shows that the complex is a centrosymmetric dimer. Each of the Fe(III) ions has a five-coordinate geometry and one oxygen atom bridges two Fe(III) ions to form a μ-oxo structure. The geometry around iron atom can be described as a square based pyramid with the FeN2O2 coordination plane and oxo ligand.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Tatsumi and R. Hoffmann, J. Am. Chem. Soc., 103, 3328 (1981).

    Article  CAS  Google Scholar 

  2. L. Que Jr., Coord. Chem. Rev., 50, 73 (1983).

    Article  Google Scholar 

  3. R. N. Mukherjee, T. D. P. Stack, and R. Holm, J. Am. Chem. Soc., 110, 1850 (1988).

    Article  CAS  Google Scholar 

  4. P. J. Nichols, G. D. Fallon, K. S. Murray, and B. O. West, Inorg. Chem., 27, 2795 (1988).

    Article  CAS  Google Scholar 

  5. S. J. Lippard, Angew. Chem., Int. Ed. Engl., 27, 344 (1988).

    Article  Google Scholar 

  6. W. Chiang, D. Vanengen, and M. E. Thompson, Polyhedron, 15, 2369 (1996).

    Article  CAS  Google Scholar 

  7. S. Hayami, K. Inoue, and Y. Maeda, Mol. Cryst. Liq. Cryst., 335, 1285 (1999).

    Article  CAS  Google Scholar 

  8. E. Q. Gao, L. H. Yin, J. K. Tang, P. Cheng, D. Z. Liao, Z. H. Jiang, and S. P. Yan, Polyhedron, 20, 669 (2001).

    Article  CAS  Google Scholar 

  9. H. Fujii and Y. Funahashi, Angew. Chem., Int. Ed., 41, 3638 (2002).

    Article  CAS  Google Scholar 

  10. M. A. Torzilli, S. Colquhoun, J. Kim, and R. H. Beer, Polyhedron, 21, 705 (2002).

    Article  CAS  Google Scholar 

  11. A. Elmali, Y. Elerman, C. T. Zeyrek, and I. Svoboda, Z. Naturforsch., 58b, 433 (2003).

    Google Scholar 

  12. Z. L. You and H. L. Zhu, Acta Crystallogr., E60, m1046 (2004).

    Google Scholar 

  13. A. Karakas, E. Donmez, H. Kara, and A. Elmali, J. Nonlinear Opt. Phys. Mater., 16, 329 (2007).

    Article  CAS  Google Scholar 

  14. Y. Yahsi, H. Kara, L. Sorace, and O. Buyukgungor, Inorg. Chim. Acta, 366, 191 (2011).

    Article  CAS  Google Scholar 

  15. K. P. Bryliakov and E. P. Talsi, Angew. Chem., Int. Ed., 43, 5228 (2004).

    Article  CAS  Google Scholar 

  16. T. Katsuki, Chem. Soc. Rev., 33, 437 (2004).

    Article  CAS  Google Scholar 

  17. A. Boettcher, M. W. Grinstaff, J. A. Labinger, and H. B. Gray, J. Mol. Catal. A: Chem., 113, 191 (1996).

    Article  CAS  Google Scholar 

  18. C. T. Brewer, G. Brewer, G. B. Jameson, P. Kamaras, L. May, and M. Rapta, J. Chem. Soc., Dalton Trans., 37 (1995).

    Google Scholar 

  19. M. M. Bhadbhade and D. Srinivas, Polyhedron, 17, 2699 (1998).

    Article  CAS  Google Scholar 

  20. H. Fujii, T. Kurahashi, and T. Ogura, J. Inorg. Biochem., 96, 133 (2003).

    Article  Google Scholar 

  21. E. Y. Tshuva and S. J. Lippard, Chem. Rev., 104, 987 (2004).

    Article  CAS  Google Scholar 

  22. S. V. Kryatov, E. V. Rybak-Akimova, and S. Schindler, Chem. Rev., 105, 2175 (2005).

    Article  CAS  Google Scholar 

  23. E. I. Solomon, T. C. Brunold, M. I. Davis, J. N. Kemsley, S. K. Lee, N. Lehnert, F. Neese, A. J. Skulan, Y. S. Yang, and J. Zhou, Chem. Rev., 100, 235 (2000).

    Article  CAS  Google Scholar 

  24. K. S. Min, A. M. Arif, and J. S. Miller, Inorg. Chim. Acta, 360, 1854 (2007).

    Article  CAS  Google Scholar 

  25. A. Caneschi, A. Cornia, A. C. Fabretti, D. Gatteschi, and W. Malavasi, Inorg. Chem., 34, 4660 (1995).

    Article  CAS  Google Scholar 

  26. F. L. Gall, F. F. de Biani, A. Caneschi, P. Cinelli, A. Cornia, A. C. Fabretti, and D. Gatteschi, Inorg. Chim. Acta, 262, 123 (1997).

    Article  Google Scholar 

  27. O. Ciftja, M. Luban, M. Auslender, and J. H. Luscombe, Phys. Rev. B, 60, 10122 (1999).

    Article  CAS  Google Scholar 

  28. O. Ciftja, Nanoscale Res. Lett., 2, 168 (2007).

    Article  CAS  Google Scholar 

  29. K. S. Murray, Coord. Chem. Rev., 12, 1 (1974).

    Article  CAS  Google Scholar 

  30. D. M. Kurtz, Chem. Rev., 90, 585 (1990).

    Article  CAS  Google Scholar 

  31. H. Weihe and H. U. Güdel, J. Am. Chem. Soc., 119, 6539 (1997).

    Article  CAS  Google Scholar 

  32. R. G. Wollmann and D. N. Hendrickson, Inorg. Chem., 16, 723 (1977).

    Article  CAS  Google Scholar 

  33. C. G. Wahlgren, A. M. Addison, S. Burman, L. K. Thompson, E. Sinn, and T. M. Rowe, Inorg. Chim. Acta, 166, 59 (1989).

    Article  CAS  Google Scholar 

  34. N. Arulsamy, D. J. Hodgson, and J. Glerup, Inorg. Chim. Acta, 209, 61 (1993).

    Article  CAS  Google Scholar 

  35. R. Hotzelmann, K. Wieghardt, U. Flörke, H.-J. Haupt, D. C. Weatherburn, J. Bonvoisin, G. Blondin, and J.-J. Girerd, J. Am. Chem. Soc., 114, 1681 (1992).

    Article  CAS  Google Scholar 

  36. T. J. Mizoguchi, R. M. Davidov, and S. J. Lippard, Inorg. Chem., 38, 4098 (1999).

    Article  CAS  Google Scholar 

  37. J. A. Thich, C. C. Ou, D. Powers, B. Vasiliou, D. Mastropaolo, J. A. Potenza, and H. J. Schugar, J. Am. Chem. Soc., 98, 1425 (1976).

    Article  CAS  Google Scholar 

  38. J. T. Wrobleski and D. B. Brown, Inorg. Chim. Acta, 35, 109 (1975).

    Article  Google Scholar 

  39. J. T. Wrobleski and D. B. Brown, Inorg. Chem., 17, 2529 (1978).

    Article  Google Scholar 

  40. G. H. Long, Inorg. Chem., 17, 2702 (1978).

    Article  CAS  Google Scholar 

  41. C.-H. S. Wu, G. R. Rossman, H. B. Gray, G. S. Hammond, and H. J. Schugar, Inorg. Chem., 11, 990 (1972).

    Article  CAS  Google Scholar 

  42. J. A. Bertrand, J. L. Breece, and P. G. Eller, Inorg. Chem., 13, 125 (1974).

    Article  CAS  Google Scholar 

  43. Y. Nishida, M. Takeuchi, H. Shimo, and S. Kida, Inorg. Chim. Acta, 90, 115 (1984).

    Article  Google Scholar 

  44. L. Yin, P. Cheng, X. Yao, and H. Wang, J. Chem. Soc., Dalton. Trans., 2109 (1997).

    Google Scholar 

  45. Y. Yahsi, H. Kara, C. Kazak, A. Iakovenko, and L. Sorace, J. Optoelectron. Adv. Mater.–Symposia, 1, 566 (2009).

    Google Scholar 

  46. M. Gerloch and F. E. Mabbs, J. Chem. Soc. A, 1900 (1967).

    Google Scholar 

  47. A. Elmali, Y. Elerman, I. Svoboda, and H. Fuess, J. Mol. Struct., 516, 43 (2000).

    Article  CAS  Google Scholar 

  48. Stoe & Cie X-AREA (Version 1.18) and X-RED (Version 1.04), Stoe & Cie, Darmstadt, Germany (2002).

  49. G. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr., 64, 112 (2008).

    Article  CAS  Google Scholar 

  50. R. Werner, S. Ostrowvsky, K. Griesar, and W. Haase, Inorg. Chim. Acta, 326, 78 (2001).

    Article  CAS  Google Scholar 

  51. E. Ruiz and S. Alvarez, ChemPhysChem, 6, 1094 (2005).

    Article  CAS  Google Scholar 

  52. T. Kojima, R. A. Leising, S. Yan, and L. Que Jr., J. Am. Chem. Soc., 115, 11328 (1993).

    Article  CAS  Google Scholar 

  53. E. Wilkinson, Y. Dong, and L. Que Jr., J. Am. Chem. Soc., 116, 8394 (1994).

    Article  CAS  Google Scholar 

  54. R. H. Fish, M. S. Konnings, K. J. Oberhausen, R. H. Fong, W. M. Yu, G. Christou, J. B. Vincent, D. K. Coggin, and R. M. Buchanan, Inorg. Chem., 30, 3002 (1991).

    Article  CAS  Google Scholar 

  55. R. M. Buchanan, S. Chen, J. F. Richardson, M. Bressan, L. Forti, A. Morvillo, and R. H. Fish, Inorg. Chem., 33, 3208 (1994).

    Article  CAS  Google Scholar 

  56. Y. Dong, H. Fujii, M. P. Hendrich, R. A. Leising, G. Pan, C. R. Randall, E. C. Wilkinson, Y. Zang, and L. Que, J. Am. Chem. Soc., 117, 2778 (1995).

    Article  CAS  Google Scholar 

  57. X. Wang, S. Wang, L. Li, E. B. Sundberg, and G. P. Gacho, Inorg. Chem., 42, 7799 (2003).

    Article  CAS  Google Scholar 

  58. F. Corazza, C. Floriani, and M. Zehnder, J. Chem. Soc., Dalton Trans., 709 (1987).

    Google Scholar 

  59. G. Das, R. Shukla, S. Mandal, R. Singh, and P. K. Bharadwaj, Inorg. Chem., 36, 323 (1997).

    Article  CAS  Google Scholar 

  60. A. R. Li, H. H. Wei, and L. L. Gang, Inorg. Chim. Acta, 290, 51 (1999).

    Article  CAS  Google Scholar 

  61. K. Oyaizu, E. L. Dewi, and E. Tsuchida, Inorg. Chim. Acta, 321, 205 (2001).

    Article  CAS  Google Scholar 

  62. S. Koner, S. Iijima, M. Watanabe, and M. Sato, J. Coord. Chem., 56, 103 (2003).

    Article  CAS  Google Scholar 

  63. W. J. Ruan, G. H. Hu, S. J. Wang, J. H. Tian, Q. L. Wang, and Z. A. Zhu, Chin. J. Chem., 23, 709 (2005).

    Article  CAS  Google Scholar 

  64. Z. L. You, L. L. Tang, and H. L. Zhu, Acta Crystallogr., E61, m36 (2005).

    Google Scholar 

  65. G. Ilyashenko, M. Motevalli, and M. Watkinson, Tetrahedron: Asymmetry, 17, 1625 (2006).

    Article  CAS  Google Scholar 

  66. Q. Meng, L. Wang, Y. Liu, and Y. Pang, Acta Crystallogr., E64, m63 (2008).

    Google Scholar 

  67. L. N. Rusere, T. Shalumova, J. M. Tanski, and L. A. Tyler, Polyhedron, 28, 3804 (2009).

    Article  CAS  Google Scholar 

  68. R. Mayilmurugan, H. Stoeckli-Evans, E. Suresh, and M. Palaniandavar, Dalton Trans., 5101 (2009).

    Google Scholar 

  69. J. H. Yan, X. P. Shen, and H. Zhou, Acta Crystallogr., E66, m1090 (2010).

    Google Scholar 

  70. J. B. H. Strautmann, C.-G. F. von Richthofen, G. Heinze-Brückner, S. DeBeer, E. Bothe, E. Bill, T. Weyhermüller, A. Stammler, H. Bögge, and T. Glaser, Inorg. Chem., 50, 155 (2011).

    Article  CAS  Google Scholar 

  71. R. Biswas, M. G. B. Drew, C. Estarellas, A. Frontera, and A. Ghosh, Eur. J. Inorg. Chem., 2558 (2011).

    Google Scholar 

  72. M. S. Shongwe, U. A. Al-Zaabi, F. Al-Mjeni, C. S. Eribal, E. Sinn, I. A. Al-Omari, H. H. Hamdeh, D. Matoga, H. Adams, M. J. Morris, A. L. Rheingold, E. Bill, and D. J. Sellmyer, Inorg. Chem., 51, 8241 (2012).

    Article  CAS  Google Scholar 

  73. S. Jana, S. Chatterjee, and S. Chattopadhyay, Polyhedron, 48, 189 (2012).

    Article  CAS  Google Scholar 

  74. Cambridge Structural Database. Version 5.26, University of Cambridge, UK.

Download references

Author information

Authors and Affiliations

  1. Faculty of Art and Science, Department of Physics, Balikesir University, Balikesir, Turkey

    Y. Yahsi, E. Gungor & H. Kara

  2. Faculty of Art and Science, Department of Physics, Ondokuz Mayis University, Samsun, Turkey

    C. Kazak

  3. Department of Physics, Faculty of Science, Mugla Sikti Koçman University, Mugla, Turkey

    H. Kara

Authors
  1. Y. Yahsi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Gungor
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Kazak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Kara
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. Yahsi.

Additional information

Original Russian Text © 2015 Y. Yahsi, E. Gungor, C. Kazak, H. Kara.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1601-1605, December, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yahsi, Y., Gungor, E., Kazak, C. et al. Crystal structure of a μ-oxo-bridged dimeric iron(III) complex. J Struct Chem 56, 1540–1544 (2015). https://doi.org/10.1134/S0022476615080120

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615080120

Keywords

Search

Navigation