Plasmonic applications, which are determined by the strong interaction between an electromagnetic wave and free electrons in nanostructures, are among the possible applications of silver nanoparticles. It appears that the frequency and intensity of the plasmon resonance depend on the polarization charge distribution determined by the shape and structure of a nanoparticle. Consequently, the control of the structure of nanoclusters allows varying the wavelengths of light that are scattered or absorbed on them. In this work, the limits of the thermal stability of the initial amorphous phase in silver clusters with sizes smaller than 2.0 nm with the number of atoms corresponding to the “magic” numbers of the fcc structure are studied by the molecular dynamics method with the modified TB-SMA tight-binding potential. The results are compared with the data for a similar set of particles with the initial fcc structure. It is shown that the characters of thermally induced structural transitions in the studied groups of nanoclusters are drastically different. This property can allow fabricating small silver clusters with the required internal structure.
Similar content being viewed by others
REFERENCES
D. Hua and Y. Hongtao, Adv. Nat. Sci. 8, 1 (2015).
J. Natsuki, T. Natsuki, and Y. Hashimoto, Int. J. Mater. Sci. Appl. 4, 325 (2015).
P. Horta-Fraijo, M. Cortez-Valadez, R. Britto Hurtado, R. A. Vargas-Ortiz, A. Perez-Rodriguez, and M. Flores-Acosta, Phys. E (Amsterdam, Neth.) 97, 111 (2018).
C. Guo and J. Irudayaraj, Anal. Chem. 83, 2883 (2011).
T. C. Dakal, A. Kumar, R. S. Majumdar, and V. Yadav, Front. Microbiol. 7, 1831 (2016).
A.-C. Burdusel, O. Gherasim, A. M. Grumezescu, L. Mogoanta, A. Ficai, and E. Andronescu, Nanomaterials 8, 681 (2018).
I. Ghiuta and D. Cristea, Nanoeng. Biomater. Adv. Drug Deliv., 347 (2020). https://doi.org/10.1016/B978-0-08-102985-5.00015-2
S. Alkis, J. L. Krause, J. N. Fry, and H.-P. Cheng, Phys. Rev. B 79, 121402(R) (2009).
H. Akbarzadeh and H. Yaghoubi, J. Colloid Interface Sci. 418, 178 (2014).
A. S. Kuznetsov, N. T. Cuong, V. K. Tikhomirov, M. Jivanescu, A. Stesmans, L. F. Chibotaru, J. J. Velázquez, V. D. Rodríguez, D. Kirilenko, G. van Tendeloo, and V. V. Moshchalkov, Opt. Mater. 34, 616 (2012).
J. J. Velázquez, V. K. Tikhomirov, L. F. Chibotaru, N. T. Cuong, A. S. Kuznetsov, V. D. Rodríguez, M. T. Nguyen, and V. V. Moshchalkov, Opt. Express 20, 13582 (2012).
J. D. Padmos, R. T. M. Boudreau, D. F. Weaver, and P. Zhang, J. Phys. Chem. C 119, 24627 (2015).
M. Rycenga, C. M. Cobley, J. Zeng, W. Li, Ch. H. Moran, Q. Zhang, D. Qin, and Y. Xia, Chem. Rev. 111, 3669 (2011).
L. V. Redel’, Yu. Ya. Gafner, and S. L. Gafner, Phys. Solid State 57, 2117 (2015).
Y. Gafner, S. Gafner, and D. Bashkova, J. Nanopart. Res. 21, 243 (2019).
Y.-P. Chiu, Ch.-M. Wei, and Ch.-S. Chang, Phys. Rev. B 78, 115402 (2008).
D. Liu, Z. Wen, and Q. Jiang, Curr. Nanosci. 7, 463 (2011).
D. T. Tran, I. P. Jones, R. L. Johnston, J. A. Preece, and C. R. van den Brom, J. Phys.: Conf. Ser. 241, 012086 (2010).
V. M. Samsonov, S. A. Vasilyev, K. K. Nebyvalova, V. Talyzin, N. Y. Sdobnyakov, D. N. Sokolov, and M. I. Alimov, J. Nanopart. Res. 22, 247 (2020).
F. Cleri and V. Rosato, Phys. Rev. B 48, 22 (1993).
S. M. Novikov, V. N. Popok, A. B. Evlyukhin, M. Hanif, P. Morgen, J. Fiutowski, J. Beermann, H.-G. Rubahn, and S. I. Bozhevolnyi, Langmuir 33, 6062 (2017).
S. L. Gafner, L. V. Redel, Zh. V. Golovenko, Yu. Ya. Gafner, V. M. Samsonov, and S. S. Kharechkin, JETP Lett. 89, 364 (2009).
W. Demtröder, Molekülphysik: Theoretische Grundlagen und experimentelle Methoden (Oldenburg, Heidelberg, 2000).
A. K. Starace, C. M. Neal, B. Cao, M. F. Jarrold, A. Aguado, and J. M. Lopez, J. Chem. Phys. 129, 144702 (2008).
I. L. Garzon, K. Michaelian, M. R. Beltan, A. Posada-Amarillas, P. Ordejon, E. Artacho, D. Sanchez-Portal, and J. M. Soler, Eur. Phys. J. D 9, 211 (1999).
I. L. Garzon, K. Michaelian, M. R. Beltrán, A. Posada-Amarillas, P. Ordejón, E. Artacho, D. Sánchez-Portal, and J. M. Soler, Phys. Rev. Lett. 81, 1600 (1998).
Funding
This work was supported by the Russian Foundation for Basic Research (project no. 19-48-190002).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by R. Tyapaev
Rights and permissions
About this article
Cite this article
Ryzhkova, D.A., Gafner, S.L. & Gafner, Y.Y. Effect of “Magic” fcc Numbers on the Stability of the Structure of Small Silver Nanoclusters. Jetp Lett. 113, 638–645 (2021). https://doi.org/10.1134/S002136402110009X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S002136402110009X