Abstract
Thin-film coatings of tin oxide on the surface of a chemically thinned section of a single-mode quartz fiber have been obtained and experimentally characterized. The materials were synthesized on the fiber surface by metal-organic chemical vapor deposition (MOCVD). To change the surface morphology, we used different amounts of tetramethyltin (SnMe4) supplied by a carrier gas (dried air) to the deposition zone by varying the temperature of the bubbler with the reagent. During deposition, the transmission spectrum of the optical path was recorded in real time, and the temperature of the bubbler in the experiments varied from –20 to +20°С. After studying the surface on a scanning electron microscope, the deposited films were tested for chemical resistance to an aqueous solution of sulfuric acid and the sensitivity of the lossy mode resonance (LMR) to changes in the refractive index of the environment in the range from 1.35 to 1.41 was evaluated. Samples produced at higher reagent flow rates exhibited a greater resonance sensitivity of 3800 nm/refractive index unit (RIU) for the first-order TM component of the resonance, but such coatings dissolve noticeably in concentrated sulfuric acid solutions, in contrast to coatings obtained with low reagent consumption.
Similar content being viewed by others
REFERENCES
Kersey, A.D., Opt. Fiber Technol., 1996, vol. 2, p. 291. https://doi.org/10.1006/ofte.1996.0036
Franzão, O., Santos, J.L., Araújo, F.M., and Ferreira, L.A., Laser Photonics Rev., 2008, vol. 2, p. 449. https://doi.org/10.1002/lpor.200810034
Roriz, P., Franzão, O., Lobo-Ribeiro, A.B., Santos, J.L., and Simoes, J.A., J. Biomed. Opt., 2013, vol.18, no. 5, p. 050903. https://doi.org/10.1117/1.jbo.18.5.050903
Del Villar, I., Arregui, F.J., Zamarreno, C.R., Corres, J.M., Bariain, C., Goicoechea, J., Elosua, C., Hernaez, M., Rivero, P.J., Socorro, A.B., Urrutia, A., Sanchez, P., Zubiate, P., Lopez, D., De Acha, N., et al., Sens. Actuators, B, 2017, vol. 240, p. 174. https://doi.org/10.1016/j.snb.2016.08.126
Kerttula, J., Filippov, V., Chamorovskii, Yu., Ustimchik, V., Golant, K., and Okhotnikov, O.G., Proc. SPIE, 2012, vol. 8237, p. 82370W. https://doi.org/10.1117/12.908147
Dianov, E., Light: Sci. Appl., 2012, vol. 1, p. e12. https://doi.org/10.1038/lsa.2012.12
Dejneka, M. and Samson, B., MRS Bull., 1999, vol. 24, p. 39. https://doi.org/10.1557/S0883769400053057
Sanada, K., Shamoto, T., and Inada, K., J. Non-Cryst. Solids, 1995, vol. 189, p. 283. https://doi.org/10.1016/0022-3093(95)00233-2
Ascorbe, J., Corres, J.M., Matias, I.R., and Arregui, F.J., Sens. Actuators, B, 2016, vol. 233, p. 7. https://doi.org/10.1016/j.snb.2016.04.045
Zhu, S., Pang, F., Huang, S., Zou, F., Dong, Y., and Wang, T., Opt. Express, 2015, vol. 23, p. 13880. https://doi.org/10.1364/OE.23.013880
Arregui, F.J., Del Villar, I., Zamarreno, C.R., Zubiate, P., and Matias, I.R., Sens. Actuators, B, 2016, vol. 232, p. 660. https://doi.org/10.1016/j.snb.2016.04.015
Wang, J., Luo, Z., Zhou, M., Ye, C., Fu, H., Cai, Z., Cheng, H., Xu, H., and Qi, W., IEEE Photonics J., 2012, vol. 4, p. 1295. https://doi.org/10.1109/JPHOT.2012.2208736
Lee, J., Koo, J., Jhon, Y.M., and Lee, J.H., Opt. Express, 2014, vol. 22, p. 6165. https://doi.org/10.1364/OE.22.006165
Lee, H., Kwon, W.S., Kim, J.H., Kang, D., and Kim, S., Opt. Express, 2015, vol. 23, p. 22116. https://doi.org/10.1364/OE.23.022116
Henry, W.M., Proc. SPIE, 1994, vol. 2293. https://doi.org/10.1117/12.190957
Wang, Z., Zhu, G., Wang, Y., Li, M., Singh, R., Zhang, B., and Kumar, S., Appl. Opt., 2021, vol. 60, p. 2077. https://doi.org/10.1364/ao.418875
Tabassum, S. and Kumar, R., Adv. Mater. Technol., 2020, vol. 5, p. 1900792. https://doi.org/10.1002/admt.201900792
Paliwal, N. and John, J., IEEE Sens. J., 2015, vol. 15, p. 5361. https://doi.org/10.1109/JSEN.2015.2448123
Wang, X., Wang, Q., Song, Z., and Qi, K., AIP Adv., 2019, vol. 9, p. 095005. https://doi.org/10.1063/1.5112090
Urrutia, A., Del Villar, I., Zubiate, P., and Zamarreño, C.R., Laser Photonics Rev., 2019, vol. 13, no. 11, p. 1900094. https://doi.org/10.1002/lpor.201900094
Ozcariz, A., Ruiz-Zamarreño, C., and Arregui, F.J., Sensors, 2020, vol. 20, p. 1972. https://doi.org/10.3390/s20071972
Usha, S.P., Mishra, S.K., and Gupta, B.D., Sens. Actuators, B, 2015, vol. 218, p. 196. https://doi.org/10.1016/j.snb.2015.04.108
Sanchez, P., Mendizabal, D., Zamarreno, C.R., Matias, I.R., and Arregui, F.J., Proc. SPIE, 2015, vol. 9634, p. 96347M. https://doi.org/10.1117/12.2195177
Matias, I.R., Ikezawa, S., and Corres, J., Fiber Optic Sensors: Status and Future Possibilities, Springer Int. Publ., 2017, vol. 21, p. 51. https://doi.org/10.1007/978-3-319-42625-9
Li, W., Zhang, A., Cheng, Q., Sun, C., and Li, Y., Optik, 2020, vol. 213, p. 164696. https://doi.org/10.1016/j.ijleo.2020.164696
Savelyev, E.A., Eur. Phys. J. D, 2021, vol. 75, p. 285. https://doi.org/10.1140/epjd/s10053-021-00296-0
Kuznetsov, P.I., Sudas, D.P., and Savel’ev, E.A., Instrum. Exp. Tech., 2020, vol. 63, p. 516. https://doi.org/10.1134/S0020441220040302
Kuznetsov, P.I., Sudas, D.P., Yapaskurt, V.O., and Savelyev, E.A., Opt. Mater. Express, 2021, vol. 11, p. 2650. https://doi.org/10.1364/OME.433169
Kuznetsov, P.I., Sudas, D.P., and Savelyev, E.A., Sens. Actuators, A, 2021, vol. 321, p. 112576. https://doi.org/10.1016/j.sna.2021.112576
ACKNOWLEDGMENTS
The authors are grateful to V.O. Yapaskurt for the images obtained with a scanning electron microscope.
Funding
The work was supported by the Russian Science Foundation (grant no. 21-19-00259).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
International conference “Optical Reflectometry, Metrology & Sensing 2023ˮ, Russia, Perm, 24–26, May 2023.
Rights and permissions
About this article
Cite this article
Sudas, D.P., Kuznetsov, P.I. Tin (IV) Oxide Coatings with Different Morphologies on the Surface of a Thinned Quartz Fiber for Sensor Application. Instrum Exp Tech 66, 875–880 (2023). https://doi.org/10.1134/S0020441223050226
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020441223050226