Abstract—
A highly porous material based on submicron titanium carbide powder has been prepared using a pore former. General mechanisms underlying the formation of the pore structure of the material have been identified as functions of the volume fraction of the pore former and sintering temperature, varied in the ranges 75–85% and 1200–1500°C, respectively. Increasing the porosity of the material has been shown to raise its permeability and reduce its strength. At a given porosity, raising the sintering temperature from 1200 to 1500°C allows a material with higher permeability to be obtained, which is accompanied by an increase in its strength.
Similar content being viewed by others
REFERENCES
Fadeeva, I.V., Ryzhov, A.P., Titov, D.D., Filippov, Ya.Yu., Tyut’kova, Yu.B., Davydova, G.A., and Barinov, S.M., Barium-substituted tricalcium phosphate ceramics, Inorg. Mater., 2022, vol. 58, no. 3, pp. 317–324. https://doi.org/10.1134/S0020168522030037
Wang, J.W., Li, N.X., Li, Z.R., Wang, J.R., Xu, X., and Chen, C.S., Preparation and gas separation properties of zeolitic imidazolate frameworks-8 (ZIF-8) membranes supported on silicon nitride ceramic hollow fibers, Ceram. Int., 2016, vol. 42, no. 7, pp. 8949–8954. https://doi.org/10.1016/j.ceramint.2016.02.153
Yu, L., Kanezashi, M., Nagasawa, H., and Tsuru, T., Phase inversion/sintering-induced porous ceramic microsheet membranes for high-quality separation of oily wastewater, J. Membr. Sci., 2020, vol. 595, p. 117477. https://doi.org/10.1016/j.memsci.2019.117477
Chang, Y., Sun, X., Ma, M., Mu, C., Li, P., Li, L., Li, M., Nie, A., Xiang, J., Zhao, Z., He, J., Wen, F., Liu, Z., and Tian, Y., Application of hard ceramic materials B4C in energy storage: design B4C@C core–shell nanoparticles as electrodes for flexible all-solid-state micro-supercapacitors with ultrahigh cyclability, Nano Energy, 2020, vol. 75, p. 104947. https://doi.org/10.1016/j.nanoen.2020.104947
Shi, Y., Zheng, D., Zhang, X., Lv, K., Wang, F., Dong, B., Wang, S., Yang, C., Li, J., Yang, F., Hao, L.Y., Yin, L., Xu, X., Xian, Y., and Agathopoulos, S., Self-supported ceramic electrode of 1T–2H MoS2 grown on the TiC membrane for hydrogen production, Chem. Mater., 2021, vol. 33, no. 15, pp. 6217–6226. https://doi.org/10.1021/acs.chemmater.1c01965
Mao, H., Shen, F., Zhang, Y., Wang, J., Cui, K., Wang, H., Lv, T., Fu, T., and Tan, T., Microstructure and mechanical properties of carbide reinforced TiC-based ultra-high temperature ceramics: a review, Coatings, 2021, vol. 11, no. 12, p. 1444. https://doi.org/10.3390/coatings11121444
Popovska, N., Streitwieser, D.A., Xu, C., and Gerhard, H., Paper derived biomorphic porous titanium carbide and titanium oxide ceramics produced by chemical vapor infiltration and reaction (CVI-R), J. Eur. Ceram. Soc., 2005, vol. 25, no. 6, pp. 829–836. https://doi.org/10.1016/j.jeurceramsoc.2004.04.007
Moriwaki, H., Kitajima, S., Shirai, K., Kiguchi, K., and Yamada, O., Application of the powder of porous titanium carbide ceramics to a reusable adsorbent for environmental pollutants, J. Hazard. Mater., 2011, vol. 185, nos. 2–3, pp. 725–731. https://doi.org/10.1016/j.jhazmat.2010.09.079
Christians, H., Brunnengräber, K., Glasel, J., and Etzold, B.J., Mesoporous and crystalline carbide-derived carbons: towards a general correlation on synthesis temperature and precursor structure influence, Carbon, 2021, vol. 175, pp. 215–222. https://doi.org/10.1016/j.carbon.2021.01.003
Muscat, D. and Drew, R.A.L., Modeling the infiltration kinetics of molten aluminum into porous titanium carbide, Metall. Mater. Trans. A, 1994, vol. 25, no. 11, pp. 2357–2370. https://doi.org/10.1007/BF02648856
Alymov, M.I., Shustov, V.S., Kasimtsev, A.V., Zhigunov, V.V., Ankudinov, A.B., and Zelenskii, V.A., Synthesis of titanium carbide nanopowders and production of porous materials on their basis, Nanotechnol. Russ., 2011, vol. 6, no. 1, pp. 130–136. https://doi.org/10.1134/S1995078011010022
Gnedovets, A.G., Zelensky, V.A., Ankudinov, A.B., Shustov, V.S., and Alymov, M.I., Highly porous, hierarchically structured nickel nanomaterials consolidated by powder metallurgy methods, J. Phys. Conf. Ser., 2021, vol. 1942, no. 1, p. 012019. https://doi.org/10.1088/1742-6596/1942/1/012019
Funding
This work was supported by the Russian Science Foundation, grant no. 22-29-00748 (federal state budget funded science institution Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Shustov, V.S., Zelensky, V.A., Ankudinov, A.B. et al. Strength and Permeability of a Porous Material Based on Submicron Titanium Carbide Powder. Inorg Mater 58, 1011–1016 (2022). https://doi.org/10.1134/S0020168522100120
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168522100120