Skip to main content
SpringerLink
Log in

Some General Aspects of the Liquid–Glass Transition in Sodium Germanate Glasses

  • Published:
Inorganic Materials Aims and scope

Abstract—

This paper is concerned with the temperature dependence of viscosity for sodium germanate glasses differing in sodium oxide content and discusses some aspects of the liquid–glass transition in them, including a kinetic glass transition criterion. Using parameters of the Williams–Landel–Ferry (WLF) equation, we have calculated the temperature range characterizing the glass transition region and the structure relaxation time at the glass transition temperature of the glassed studied. We propose generalization and substantiation of the Schmelzer kinetic glass transition criterion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Sanditov, D.S. and Bartenev, G.M., Fizicheskie svoistva neuporyadochennykh struktur (Physical Properties of Disordered Structures), Novosibirsk: Nauka, 1982.

  2. Rostiashvili, V.G., Irzhak, V.I., and Rozenberg, B.A., Steklovanie polimerov (Glass Transition of Polymers), Leningrad: Khimiya, 1987.

  3. Mazurin, O.V., Problems of compatibility of the values of glass transition temperatures published in the world literature, Glass Phys. Chem., 2007, vol. 33, no. 1, pp. 22–36.

    Article  CAS  Google Scholar 

  4. Frenkel, J., Vvedenie v teoriyu metallov (Introduction to the Theory of Metals), Leningrad: Gostekhizdat, 1948.

  5. Ferry, J.D., Viscoelastic Properties of Polymers, New York: Wiley, 1961

    Book  Google Scholar 

  6. Sanditov, D.S., On the nature of the liquid-to-glass transition equation, J. Exp. Theor. Phys., 2016, vol. 123, no. 3, pp. 429–442.

    Article  CAS  Google Scholar 

  7. Sanditov, D.S. and Badmaev, S.S., Glass transition of liquids and frozen deformation of glass, Inorg. Mater., 2019, vol. 55, no. 10, pp. 1046–1053.

    Article  CAS  Google Scholar 

  8. MDL SciGlass-7.8, Shrewsbury: Inst. of Theoretical Chemistry, 2012.

  9. Sanditov, D.S., Model of delocalized atoms in the physics of the vitreous state, J. Exp. Theor. Phys., 2012, vol. 115, no. 1, pp. 112–124.

    Article  CAS  Google Scholar 

  10. Sanditov, D.S. and Badmaev, S.S., Delocalized-atom model and properties of sulfophosphate glasses, Inorg. Mater., 2019, vol. 55, no. 1, pp. 55–60.

    Google Scholar 

  11. Bartenev, G.M., Effect of cooling/heating rate on the glass transition temperature of silicate glass, Dokl. Akad. Nauk SSSR, 1951, vol. 76, no, 2, pp. 227–230.

    CAS  Google Scholar 

  12. Vol’kenshtein, M.V. and Ptitsyn, O.B., Relaxation theory of vitrification, Zh. Tekh. Fiz., 1956, vol. 26, no. 10, pp. 2204–2222.

    Google Scholar 

  13. Nemilov, S.V., Maxwell equation and classical theories of glass transition as a basis for direct calculation of viscosity at glass transition temperature, Glass Phys. Chem., 2013, vol. 39, no. 6, pp. 609–623.

    Article  CAS  Google Scholar 

  14. Schmelzer, J.W.P., Kinetic criteria of glass formation and the pressure dependence of the glass transition temperature, J. Chem. Phys., 2012, vol. 36, paper 074512. https://doi.org/10.1063/1.3685510

  15. Tropin, T.V., Shmelzer, J.W.P., and Aksenov, V.L., Modern aspects of the kinetic theory of glass transition, Usp. Fiz. Nauk, 2016, vol. 186, no. 1, pp. 47–73.

    Article  Google Scholar 

  16. Bartenev, G.M., Stroenie i mekhanicheskie svoistva neorganicheskikh stekol (Structure and Mechanical Properties of Inorganic Glasses), Moscow: Stroiizdat, 1966.

  17. Bartenev, G.M. and Luk’yanov, I.A., Effect of heating rate on the glass transition temperature of amorphous substances and correlation between their glass transition temperature and activation energy, Zh. Fiz. Khim., 1955, vol. 29, no. 8, pp. 1486–1498.

    CAS  Google Scholar 

  18. Ojovan, M.I., Viscosity and glass transition in amorphous oxides, Adv. Cond. Matter. Phys., 2008, paper 817829.

Download references

Funding

This work was supported by the Banzarov State University federal state budget funded educational institution of higher education, grant. no. 2206-0502.

Author information

Authors and Affiliations

  1. Banzarov State University, 670000, Ulan-Ude, Buryat Republic, Russia

    D. S. Sanditov & A. A. Mashanov

  2. Institute of Materials Physics, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, Buryat Republic, Russia

    D. S. Sanditov

Authors
  1. D. S. Sanditov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Mashanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Mashanov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by O. Tsarev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sanditov, D.S., Mashanov, A.A. Some General Aspects of the Liquid–Glass Transition in Sodium Germanate Glasses. Inorg Mater 58, 630–635 (2022). https://doi.org/10.1134/S0020168522060115

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168522060115

Keywords:

Search

Navigation