Abstract
The aim of this work is to scientifically substantiate the mechanisms of plasma-chemical modification of polymeric materials in radio-frequency (RF) low-pressure discharge plasma. Using the method of molecular dynamics, a model describing the mechanisms of formation of oxygen- and nitrogen-containing functional groups on the surface of polymeric materials as a result of plasma modification was developed. The established mechanisms include multistep chemical reactions with the formation of alkyl dioxyl and alkoxyl radicals and unstable hydroperoxide groups.
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Timoshina, Y.A., Voznesensky, E.F., Teptina, A.I. et al. Model of the Interaction of Reactive Gases with Polymer Materials in Low-Pressure Radio-Frequency Plasma. High Energy Chem 57 (Suppl 1), S234–S237 (2023). https://doi.org/10.1134/S0018143923070536
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DOI: https://doi.org/10.1134/S0018143923070536