Abstract
The processes of freezing of water droplets sitting on a substrate after exposure to nanosecond spark discharges have been experimentally studied. It has been found that the droplets subjected to spark discharge treatment freeze much earlier than those unexposed to discharges. The analogy of the observed processes with the well-known Mpemba effect is noted. A qualitative explanation is given for the observed effect: rapid freezing is due to hydrated electrons, which are formed upon contact of water with plasma and play the role of crystallization centers.
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REFERENCES
Mpemba, E.B. and Osborne, D.G., Phys. Educ., 1969, vol. 4, no. 3, p. 172.
Bechhoefer, J., Kumar, A., and Chétrite, R., Nat. Rev. Phys., 2021, vol. 3, no. 8, p. 534.
Tang, Z., Huang, W., Zhang, Y., Liu, Y., and Zhao, L., InfoMat, 2023, vol. 5, no. 2, p. e12352.
Geng, M., Am. J. Phys., 2006, vol. 74, no. 6, p. 514.
Olmo, A., Baena, R., and Risco, R., Int. J. Refrig., 2008, vol. 31, no. 2, p. 262.
Esposito, S., De Risi, R., and Somma, L., Physica A (Amsterdam), 2008, vol. 387, no. 4, p. 757.
Katz, J.I., Am. J. Phys., 2009, vol. 77, no. 1, p. 27.
Vynnycky, M. and Mitchell, S.L., Heat Mass Transfer, 2010, vol. 46, nos. 8–9, p. 881.
Brownridge, J.D., Am. J. Phys., 2011, vol. 79, no. 1, p. 78.
Vynnycky, M. and Maeno, N., Int. J. Heat Mass Transfer, 2012, vol. 55, nos. 21–22, p. 6238.
Vynnycky, M. and Maeno, N., Int. J. Heat Mass Transfer, 2012, vol. 55, nos. 23–24, p. 7297.
Takada, S., Hayakawa, H., and Santos, A., Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top., 2021, vol. 103, no. 3, p. 032901.
Biswas, A., Prasad, V.V., and Rajesh, R., Europhys. Lett., 2021, vol. 136, no. 4, p. 46001.
Dubinov, A.E., Kozhayeva, J.P., Lyubimtseva, V.A., and Selemir, V.D., IEEE Trans. Plasma Sci., 2017, vol. 45, no. 12, p. 3094.
Dubinov, A.E., Kozhayeva, J.P., Lyubimtseva, V.A., and Selemir, V.D., Magnetohydrodynamics, 2018, vol. 54, no. 3, p. 261.
Dubinov, A.E., Kozhayeva, J.P., Lyubimtseva, V.A., and Selemir, V.D., Adv. Colloid Interface Sci., 2019, vol. 271, no. 1, p. 101986.
Dubinov, A.E., Iskhakova, D.N., and Lyubimtseva, V.A., Phys. Fluids, 2021, vol. 33, no. 6, p. 061707.
Dubinov, A.E., Kozhayeva, J.P., and Selemir, V.D., High Temp., 2018, vol. 56, no. 3, p. 451.
Dubinov, A.E. and Lyubimtseva, V.A., Surf. Eng. Appl. Electrochem., 2023, vol. 59, no. 2, p. 251.
Dubinov, A.E. and Lyubimtseva, V.A., Surf. Eng. Appl. Electrochem., 2023, vol. 59, no. 2, p. 251.
Zhang, X., Liu, X., Min, J., and Wu, X., Appl. Therm. Eng., 2019, vol. 147, no. 1, p. 927.
Zhao, Y., Yang, C., and Cheng, P., Appl. Phys. Lett., 2021, vol. 118, no. 14, p. 141602.
Singh, D.P. and Singh, J.P., Appl. Phys. Lett., 2013, vol. 102, no. 24, p. 243112.
Alterkop, B.A., Dubinova, I.D., and Dubinov, A.E., J. Exp. Theor. Phys., 2006, vol. 102, no. 1, p. 173.
Fedorov, V.A., Plasma Phys. Rep., 2014, vol. 40, no. 10, p. 836.
Piskarev, I.M., High Energy Chem., 2021, vol. 55, no. 2, p. 145.
Hart, E.J. and Anbar, M., The Hydrated Electron, New York: Wiley–Interscience, 1970.
Herbert, J.M. and Coons, M.P., Ann. Rev. Phys. Chem., 2017, vol. 68, no. 1, p. 447.
Gopalakrishnan, R., Kawamura, E., Lichtenberg, A.J., Lieberman, M.A., and Graves, D.B., J. Phys. D: Appl. Phys., 2016, vol. 49, no. 29, p. 295205.
Martin, D.C., Bartels, D.M., Rumbach, P., and Go, D.B., Plasma Sources Sci. Technol., 2021, vol. 30, no. 3, p. LT01.
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Translated by S. Zatonsky
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Dekhtyar, V.A., Dubinov, A.E. & Kolesov, H.N. Observation of a Plasma Analogue of the Mpemba Effect. High Energy Chem 57, 293–297 (2023). https://doi.org/10.1134/S0018143923040070
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DOI: https://doi.org/10.1134/S0018143923040070