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Effect of Ionizing Irradiation on the Segmental Mobility of Polyvinyl Alcohol Macromolecular Chains

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Abstract

The effect of ionizing radiation on the segmental mobility of chains of polyvinyl alcohol (PVA) macromolecules has been studied by relaxation spectrometry. It has been shown that depending on the electron beam radiation dose, the degree of relaxational microinhomogeneity of the α-relaxation process increases significantly due to the scission of macromolecule chains or their crosslinking and structural rearrangement. No significant changes in the mechanical properties of PVA depending on the γ-radiation dose at absorbed doses in the range from 700 to 1500 kGy have been revealed.

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Funding

The work was carried out in the framework of a state task according to the plan for 2022.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    V. A. Lomovskoy, O. V. Suvorova, N. A. Abaturova, N. Yu. Lomovskaya, S. A. Kulyukhin & Yu. S. Pavlov

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  1. V. A. Lomovskoy
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  2. O. V. Suvorova
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  3. N. A. Abaturova
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  4. N. Yu. Lomovskaya
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  5. S. A. Kulyukhin
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  6. Yu. S. Pavlov
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Correspondence to V. A. Lomovskoy.

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Translated by S. Zatonsky

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Lomovskoy, V.A., Suvorova, O.V., Abaturova, N.A. et al. Effect of Ionizing Irradiation on the Segmental Mobility of Polyvinyl Alcohol Macromolecular Chains. High Energy Chem 56, 363–373 (2022). https://doi.org/10.1134/S0018143922050101

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