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Influence of Small Doses of Electron Beam Radiation on Relaxation Microheterogeneity of Segmental Mobility in Polyvinyl Alcohol

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Abstract

The effect of electron irradiation (doses up to 53 kGy) on the relaxation properties and segmental mobility in polyvinyl alcohol molecules has been studied using relaxation spectrometry. It has been shown that radiolysis leads to the formation of radicals that do not cause crosslinking of polymer chains. Irradiation with electrons causes a linear increase in the relaxation microheterogeneity of the alpha-process in the internal friction spectrum; this change manifests itself in broadening of the corresponding loss peak.

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REFERENCES

  1. Chu, P.K., Chen, J.Y., Wang, L.P., and Huang, N., Mater. Sci. Eng. R, 2002, vol. 36, nos. 5–6, p. 143.

    Article  Google Scholar 

  2. Bauer, S., Shmuki, P., Mark, K., and Park, J., Prog. Mater. Sci., 2013, vol. 58, no. 3, p. 261.

    Article  CAS  Google Scholar 

  3. Chen, M., Zhang, Y., Driver, M.S., Caruso, A.N., Yu, Q., and Wang, Y., Dent. Mater., 2013, vol. 29, no. 8, p. 871.

    Article  Google Scholar 

  4. Tamada, Y. and Ikada, Y., Polymer, 1993, vol. 34, no. 10, p. 2208.

    Article  CAS  Google Scholar 

  5. Chandy, T., Das, G.S., Wilson, R.F., and Rao, G.H.R, Biomaterials, 2000, vol. 21, no. 7, p. 699.

    Article  CAS  Google Scholar 

  6. Pavlenko, V.I., Yastrebinskii, R.N., Edamenko, O.D., and Tarasov, D.G., Vopr. At. Nauki Tekh., 2010, no. 1, p. 129.

  7. Grishina, A.D., Dokl. Akad. Nauk SSSR, 1963, vol. 150, no. 4, p. 809.

    CAS  Google Scholar 

  8. Ignat’eva, L.N., Kuryavyi, V.G., Kaidalova, T.A., Buznik, V.M., and Korchagin, A.I., Zh. Strukt. Khim., 2005, vol. 46, no. 5, p. 870.

    Google Scholar 

  9. Zlobin, A.M., Vakhmistrov, V.A., German, V.N., Zav’yalov, N.V., et al., Materialy kitaisko-rossiiskouj seminara ”Energoemkie materialy: fundamental’nye issledovaniya, zhiznennyi tsikl, bezopasnost” (Proceedings of the Chinese–Russian Workshop “Energy-Intensive Materials: Basic Research, Life Cycle, Safety”), November 2012, Nizhny Novgorod, p. 518.

  10. Demina, T.S., Gilman, A.B., Akopova, T.A., and Zelenetskii, A.N., High Energy Chem., 2014, vol. 48, no. 5, p. 293.

    Article  CAS  Google Scholar 

  11. Tarasyuk, V.T., Strokova, N.E., Sazhnev, N.A., Prokopenko, A.V., and Kil’deeva, N.R., Food Syst., 2018, vol. 1, no. 4, p. 10.

    Article  Google Scholar 

  12. Kulyukhin, S.A., Mizina, L.V., Gorbacheva, M.P., Lomovskoi, V.A., and Saunin, E.I., Radiochemistry, 2014, vol. 56, no. 2, p. 177.

    Article  CAS  Google Scholar 

  13. Lomovskoy, V.A., Fiziko-khimicheskaya mekhanika. Osnovnye polozheniya (Physicochemical Mechanics: Fundamentals), Moscow: IFKhE RAN, 2019.

  14. Lomovskoy, V.A., Abaturova, A.N., Lomovskaya, N.Y., and Khlebnikova, O.A., Polym. Sci., Ser. A, 2015, vol. 57, no. 2, p. 123.

    Article  CAS  Google Scholar 

  15. Lomovskoy, V.A., Abaturova, N.A., Lomovskaya, N.Y., et al., Inorg. Mater.: Appl. Res., 2017, vol. 8, no. 1, p. 84.

    Article  Google Scholar 

  16. Lomovskoy, V.A., Abaturova, N.A., Lomovskaya, N.Y., and Khlebnikova, O.A., Mech. Compos. Mater., 2019, vol. 54, no. 6, p. 815.

    Article  CAS  Google Scholar 

  17. Lomovskoi, V.A., Nauchn. Priborostr., 2019, vol. 29, no. 1, p. 33.

    Article  Google Scholar 

  18. Lomovskoy, V.A., Nekrasova, N.V., Lomovskaya, N.Yu., Khlebnicova, O.A., Abaturova, N.A., Galushko, T.B., and Corbunov, A.M., Mech. Compos. Mater, 2020, vol. 30, no. 12, p. 685.

    Article  Google Scholar 

  19. Lomovskoy, V.A., Abaturova, N.A., Lomovskaya, N.Yu., and Galushko, T.B., Mekh. Kompoz. Mater., 2020, vol. 56, no. 1, p. 43.

    Google Scholar 

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Funding

The work was carried out in accordance with State Assignment, state registration no. AAAA-A19-119011790097-9 of January 17, 2019.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, 119071, Moscow, Russia

    V. A. Lomovskoy, O. V. Suvorova, N. A. Abaturova, N. Yu. Lomovskaya, S. A. Shatokhina & S. A. Kulyukhin

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  1. V. A. Lomovskoy
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  2. O. V. Suvorova
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  3. N. A. Abaturova
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  4. N. Yu. Lomovskaya
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  5. S. A. Shatokhina
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  6. S. A. Kulyukhin
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Corresponding authors

Correspondence to V. A. Lomovskoy or N. A. Abaturova.

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Translated by S. Zatonsky

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Lomovskoy, V.A., Suvorova, O.V., Abaturova, N.A. et al. Influence of Small Doses of Electron Beam Radiation on Relaxation Microheterogeneity of Segmental Mobility in Polyvinyl Alcohol. High Energy Chem 55, 216–221 (2021). https://doi.org/10.1134/S0018143921030073

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  • DOI: https://doi.org/10.1134/S0018143921030073

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