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1,4-dithiane radical cations in the CF3CCl3 matrix: Photoisomerization mechanism

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Abstract

It has been established that the photoinduced process observed in EPR and in optical absorption spectra for 1,4-dithiane radical cations in the CF3CCl3 matrix at 77 K can be ascribed to a “boat”—“twist boat” conformational transition.

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Authors and Affiliations

  1. Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskiye gory, 1/3, Moscow, 119991, Russian Federation

    I. D. Sorokin, O. I. Gromov, V. I. Pergushov & M. Ya. Melnikov

  2. N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina street, 4, Moscow, 119991, Russian Federation

    O. I. Gromov

Authors
  1. I. D. Sorokin
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  2. O. I. Gromov
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  3. V. I. Pergushov
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  4. M. Ya. Melnikov
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Correspondence to I. D. Sorokin.

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Original Russian Text © I.D. Sorokin, O.I. Gromov, V.I. Pergushov, M.Ya. Melnikov, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 5, pp. 382—387.

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Sorokin, I.D., Gromov, O.I., Pergushov, V.I. et al. 1,4-dithiane radical cations in the CF3CCl3 matrix: Photoisomerization mechanism. High Energy Chem 50, 362–367 (2016). https://doi.org/10.1134/S0018143916050155

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  • DOI: https://doi.org/10.1134/S0018143916050155

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