Abstract
Using the method of microsecond flash photolysis with UV and visible light, the spectral and kinetic characteristics of intermediate products of photolysis in toluene and methanol solutions of a new biphotochromic compound have been studied, in which two photochromic moieties, spironaphthoxazine and azomethine, are linked to each other in such a way that there is conjugation between π-electronic systems of the moieties in the ground state of the molecule. Two intermediate products have detected, whose relative efficiency of formation substantially depends on the solvent and the wavelength of excitation light.
Similar content being viewed by others
References
Minkin, V.I, Usp. Khim., 2013, vol. 82, no. 1, p. 1.
De Silva, A.P. and McClenaghan, N.D., Chem.-Eur. J., 2004, no. 7, p. 574.
Samat, A., Lokshin, V., Chamontin, K., Levi, D., Pepe, G., and Guglielmetti, R., Tetrahedron, 2001, vol. 57, p. 7349.
Berthet, J., Micheau, J.-C., Metelitsa, A., Vermeersch, G., and Delbaere, S., J. Phys. Chem. A, 2004, vol. 108, p. 10934.
Frigoly, M. and Mehl, G.H., Angew. Chem. Int. Ed., 2005, vol. 44, p. 5048.
Myles, A.J., Wigglesworth, N.J., and Branda, N.R., Adv. Mater., 2003, vol. 15, p. 745.
Molecular Switches, 2 vols., Feringa, B.I. and Browne, W.R., Eds., Weinheim Wiley–VCH, 2011.
Shienok, A.I, Kol’tsova, L.S., Zaichenko, N.L., and Marevtsev, V.S., Izv. Akad. Nauk, Ser. Khim., 2003, no. 10, p. 2169.
Zaichenko, N.L., Levin, P.P., Mardaleishvili, I.R., Shienok, A.I., Kol’tsova, L.S., Os’kina, O.Yu., and Tatikolov, A.S., Izv. Akad. Nauk, Ser. Khim., 2008, no. 11, p. 2346.
Levin, P.P., Tatikolov, A.S., Zaichenko, N.L., Shienok, A.I., Kol’tsova, L.S., Mardaleishvili, I.R., Popov, L.D., Levchenkov, S.I., and Berlin, A.A., High Energy Chem., 2012, vol. 46, p. 259.
Zaichenko, N.L. N.L., Shienok, A.I., Kol’tsova, L.S., Mardaleishvili, I.R., Tatikolov, A.S Levin, P.P., and Berlin, A.A. Phys. Status Solidi. A, 2010. p. 2746.
Zaichenko, N.L., Kol’tsova, L.S., Shcherbakova, I.M., Os’kina, O.Yu., Voznesenskii, V.N., Mardaleishvili, I.R., and Shienok, A.I., Izv. Akad. Nauk, Ser. Khim., 2011, no. 3., p. 520.
Mitra, S. and Tamai, N., Phys. Chem. Chem. Phys., 2003, vol. 5, p. 4647.
Ziolek, M., Kubicki, J., Maciejewski, A., Naskrecki, R., and Grabowska, A., Phys. Chem. Chem. Phys., 2004, vol. 6, p. 4682.
Ziolek, M., Kubicki, J., Maciejewski, A., Naskrecki, R., Luniewska, W., and Grabowska, A., J. Photochem. Photobiol., A, 2006, vol. 180, p. 101.
Sliwa, M., Mouton, N., Ruckebusch, C., Poisson, A., Idrissi, L., Aloise, S., Potier L., Dubois J., Poizat O., and Buntinx. G, Photochem. Photobiol. Sci., 2010, vol. 9, p. 661.
Fabian, W.M.F., Antonov, M.L., Nedeltcheva, D., Kamounah, F.S., and Taylor, P.J., J. Phys. Chem. A, 2004, vol. 108, p. 7603.
Ziolek, M., Kubicki, J., Maciejewski, A., Naskrecki, R., and Grabowska, A., J. Chem. Phys., 2006, vol. 124, p. 124518.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © P.P. Levin, N.L. Zaichenko, A.S. Tatikolov, A.I. Shienok, L.S. Kol’tsova, I.M. Shcherbakova, O.Yu. Os’kina, I.R. Mardaleishvili, A.O. Ait, A.A. Berlin, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 4, pp. 270–276.
Rights and permissions
About this article
Cite this article
Levin, P.P., Zaichenko, N.L., Tatikolov, A.S. et al. Kinetics of photochemical reactions of a new biphotochromic compound upon photolysis with light of different wavelengths. High Energy Chem 50, 259–265 (2016). https://doi.org/10.1134/S001814391604010X
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S001814391604010X