Abstract
Ion microprobe data for minerals from the eclogites of the Atbashi Range (South Tianshan) constrain the distribution of trace (Rb, Sr, Ba, Cr, V, Zr, Hf, Nb, Ta, U, Th, and Y) and rare-earth elements (REE) in zoned garnets and mineral inclusions in them. This study showed that garnets from the Atbashi eclogites are the main hosts for heavy REE; epidotes are important hosts for REE, Y, Sr, Th, and U; and omphacites are depleted in almost all trace elements compared with the bulk-rock compositions. Garnet, as well as epidote and omphacite inclusions exhibit systematic rimward depletion in a number of trace elements, which is related to the depletion of the rock matrix in these elements during crystallization. Deviations from this trend, including the enrichment of garnet rims in HREE and strong variations in the REE contents of garnets and mineral inclusions, can be explained by metamorphic reactions involving the destabilization of REE-bearing minerals. Our data suggest that the mobility of trace elements under eclogites-facies conditions is mainly controlled by the stability of certain minerals.
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References
P. J. O’Brien, “Garnet zoning and reaction textures in overprinted eclogites, Bohemian Massif, European Variscides: a record of their thermal history during exhumation,” Lithos 41, 119–133 (1997).
Eclogites and Glaucophane Schists in Folded Areas, Ed. by N. L. Dobretsov, N. V. Sobolev, and V. S. Shatsky (Nauka, Novosibirsk, 1989) [in Russian].
N. I. Volkova and V. I. Budanov, “Geochemical discrimination of metabasalt rocks of the Fan-Karategin transitional blueschist/greenschist belt, South Tianshan, Tajikistan: seamount volcanism and accretionary tectonics,” Lithos 47, 201–216 (1999).
J. Gao and R. Klemd, “Formation of HP-LT rocks and their tectonic implications in the western Tianshan Orogen, NW China: geochemical and age constraints,” Lithos 66, 1–22 (2003).
C. J. Wei, R. Powell, and L. F. Zhang, “Eclogites from the South Tienshan, NW China: petrological characteristic and calculated mineral equilibria in the Na2O-CaO-FeO-MgO-Al2O3-SiO2-H2O system,” J. Metamorph. Geol. 21, 163–179 (2003).
W. Lin and M. Enami, “Prograde pressure-temperature path of jadeite-bearing eclogites and associated high-pressure/low-temperature rocks from Western Tianshan, Northwest China,” Island Arc 15, 483–502 (2006).
V. S. Burtman, “Tien Shan, Pamir, and Tibet: history and geodynamics of Phanerozoic oceanic basins,” Geotectonics, 44(5), 388–404 (2010).
Q. Li, W. Lin, W. Su, X. Li, Y. Shi, Y. Liu, and G. Tang, “SIMS U-Pb rutile age of low-temperature eclogites from southwestern Chinese Tianshan, NW China,” Lithos 122, 76–86 (2011).
Z. Lü, L. Zhang, J. Du, and K. Bucher, “Coesite inclusions in garnet from eclogitic rocks in western Tianshan, Northwest China: convincing proof of UHP metamorphism,” Am. Mineral. 93, 1845–1850 (2008).
V. A. Simonov, K. S. Sakiev, N. I. Volkova, S. I. Stupakov, A. V. Travin, “Conditions of formation of the Atbashi Ridge eclogites (South Tien Shan),” Russ. Geol. Geophys. 49(11), 803–815 (2008).
E. Hegner, R. Klemd, A. Kroner, M. Corsini, D. V. Alexeiev, L. M. Iacherri, T. Zack, P. Duski, X. Xia, and B. F. Windley, “Mineral ages and P-T conditions of Late Paleozoic high-pressure eclogite and provenance of melange sediments from Atbashi in the South Tienshan Orogen of Kyrgyzstan,” Am. J. Sci. 310, 916–950 (2010).
M. Tagiri, T. Yano, A. Bakirov, T. Nakajima, and S. Uchiumi, “Mineral parageneses and metamorphic P-T paths of ultrahigh-pressure eclogites from Kyrghyzstan Tien-Shan,” Island Arc 4, 280–292 (1995).
A. B. Bakirov, M. Tagiri, and K. S. Sakiev, “Rocks of ultrahigh-pressure metamorphic facies in the Tien-Shan,” Geol. Geofiz. 39, 1722–1732 (1998).
L. F. Zhang, Y. L. Ai, X. P. Li, D. Rubatto, B. Song, S. Williams, S. G. Song, D. Ellis, and J. G. Liou, “Triassic collision of western Tianshan Orogenic Belt, China: evidence from SHRIMP U-Pb dating of zircon from HP/UHP eclogitic rocks,” Lithos 96, 266–280 (2007).
R. Klemd, M. Brocker, B. R. Hacker, J. Gao, P. Gans, and K. Wemmer, “New age constraints on the metamorphic evolution of the high-pressure/low-temperature belt in the western Tianshan Mountains, NW China,” J. Geol. 113, 157–168 (2005).
B. Wang, M. Faure, L. Shu, K. de Jong, J. Charvet, D. Cluzel, B.-M. Jahn, Y. Chen, and G. Ruffet, “Structural and geochronological study of high-pressure metamorphic rocks in the Kekesu section (Northwestern China): implications for the Late Paleozoic tectonics of the Southern Tianshan,” J. Geol. 118, 59–77 (2010).
W. Su, J. Gao, R. Klemd, J. L. Li, X. Zhang, X. H. Li, N. S. Chen, and L. Zhang, “U-Pb zircon geochronology of Tianshan eclogites in NW China: implication for the collision between the Yili and Tarim blocks of the southwestern Altaids,” Eur. J. Mineral. 22, 473–478 (2010).
V. S. Shatsky, E. Jagoutz, and N. V. Sobolev, “Age of eclogites of some metamorphic complexes of the USSR,” in Composition and Processes in the Deep Zones of Continental Lithosphere. Proceedings of International Symposium, Novosibirsk, 1988 (Novosibirsk, IGG SO PAN, 1988), pp. 72–73.
N. G. Udovkina, Eclogites of the USSR (Nauka, Moscow, 1985) [in Russian].
V. S. Shatskii, E. S. Sitnikova, O. A. Koz’menko, S. V. Palesskii, I. V. Nikolaeva, and A. A. Zayachkovskii, “Behavior of incompatible elements during ultrahigh-pressure metamorphism (by the example of rocks of the Kokchetav Massif),” Russ. Geol. Geophys. 47(4), 482–496 (2006).
A. V. Sobolev, “Melt inclusions in minerals as a source of principle petrological information,” Petrology 4(3), 209–220 (1996).
W. V. Boynton, “Cosmochemistry of the rare earth elements: meteorite studies,” in Rare Earth Element Geochemistry, Ed. by P. Henderson (Elsevier, Amsterdam, 1984), pp. 63–114.
S.-S. Sun and W. F. McDonough, “Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes,” in Magmatism in Ocean Basins, Ed. by A.D. Saunders and M.J. Norry (Geol. Soc. Spec. Publ., London, 1989), pp. 313–345.
E. J. K. Ravna and J. Paquin, “Thermobarometric methodologies applicable to eclogites and garnet ultrabasites,” EMU Notes Mineral. 5, 229–259 (2003).
D. J. Waters and H. N. Martin, “Geobarometry in phengite-bearing eclogites,” Terra Abstr. 5, 410–411 (1993).
C. Spandler, J. Hermann, R. Arculus, and J. Mavrogenes, “Redistribution of trace elements during prograde metamorphism from lawsonite blueschist to eclogite facies: implications for deep subduction-zone processes,” Contrib. Mineral. Petrol. 146, 205–222 (2003).
C. Miller, A. Zanetti, M. Thoni, and J. Konzett, “Eclogitization of gabbroic rocks: redistribution of trace elements and Zr in rutile thermometry in an Eo-Alpine subduction zone (Eastern Apls),” Chem. Geol. 239, 96–123 (2007).
T. Usui, K. Kobayashi, E. Nakamura, and H. Helmstaedt, “Trace element fractionation in deep subduction zones inferred from a lawsonite-eclogite xenolith from the Colorado Plateau,” Chem. Geol. 239, 336–351 (2007).
A. El Korh, S. Th. Schmidt, A. Ulianov, and S. Potel, “Trace element partitioning in HP-LT metamorphic assemblages during subduction-related metamorphism, Ile De Groix, France: a detailed LA-ICPMS study,” J. Petrol. 50, 1107–1148 (2009).
E. H. Hauri, T. P. Wagner, and T. L. Grove, “Experimental and natural partitioning of Th, U, Pb and other trace elements between garnet, clinopyroxene and basaltic melts,” Chem. Geol. 117, 149–166 (1994).
S. G. Skublov, Extended Abstract of Doctoral Dissertation in Geology and Mineralogy (IGGD RAN, St. Petersburg, 2005).
J. E. Otamendi, J. D. Rosa, A. E. P. Douce, and A. Castro, “Rayleigh fractionation of heavy rare earths and yttrium during metamorphic garnet growth,” Geology 30, 159–162 (2002).
M. Konrad-Schmolke, T. Zack, P. J. O’Brien, and D. R. Jacob, “Combined thermodynamic and rare earth element modelling of garnet growth during subduction: examples from ultrahigh-pressure eclogite of the Western Gneiss Region, Norway,” Earth Planet. Sci. Lett. 272, 488–498 (2008).
R. Y. Zhang, J. G. Liou, J. P. Zheng, W. L. Griffin, Y.-H. Yang, and B.-M. Jahn, “Petrogenesis of eclogites enclosed in mantle-derived peridotites from the Sulu UHP Terrane: constraints from trace elements in minerals and Hf isotopes in zircon,” Lithos 109, 176–192 (2009).
L.-G. Zhou, Q.-X. Xia, Y.-F. Zheng, and R.-X. Chen, “Multistage growth of garnet in ultrahigh-pressure eclogite during continental collision in the Dabie orogen: constrained by trace elements and U-Pb ages,” Lithos 127, 101–127 (2011).
D. Frei, A. Liebscher, G. Franz, and P. Dulski, “Trace element geochemistry of epidote minerals,” Rev. Mineral. Geochem. 56, 553–605 (2004).
K.-Q. Zong, Y.-Sh. Liu, X.-M. Liu, and B.-H. Zhang, “Trace elemental records of short-lived heating during exhumation of the CCSD eclogites,” Chin. Sci. Bull. 52(6), 813–824 (2007).
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Original Russian Text © N.I. Volkova, S.V. Kovyazin, S.I. Stupakov, V.A. Simonov, K.S. Sakiev, 2014, published in Geokhimiya, 2014, No. 11, pp. 1001–1024.
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Volkova, N.I., Kovyazin, S.V., Stupakov, S.I. et al. Trace element distribution in mineral inclusions in zoned garnets from eclogites of the Atbashi Range (South Tianshan). Geochem. Int. 52, 939–961 (2014). https://doi.org/10.1134/S0016702914090092
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DOI: https://doi.org/10.1134/S0016702914090092