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Synthesis and Study of Thermophysical Properties of Polystyrenes Prepared in the Presence of Conjugated α-Dinitrones Based on Glyoxal

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Abstract

A one-step convergent method was proposed for the synthesis of branched macromolecules in the presence of conjugated dinitrones (N,N-dimethylglyoxal dinitrone, N,N-di-tert-butylglyoxal dinitrone, and N,N- diphenylglyoxal dinitrone) under radical initiation. It was found that branched polystyrene macromolecules synthesized with participation of α-dinitrones have lower glass transition temperatures than their linear analogues. Modification methods for the prepared polymers containing alkoxyamine moieties with the goal to increase their thermal stability were developed.

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Funding

This study was supported by the Russian Foundation for Basic Research (project no. 20-03-00150).

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod—National Research University, 603950, Nizhny Novgorod, Russia

    A. B. Alyeva, E. V. Kolyakina, S. A. Stakhi, S. S. Sologubov, A. V. Markin &  D. F. Grishin

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  1. A. B. Alyeva
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  2. E. V. Kolyakina
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  3. S. A. Stakhi
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  4. S. S. Sologubov
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  5. A. V. Markin
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  6. D. F. Grishin
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Correspondence to D. F. Grishin.

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Translated by Z. Svitanko

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Alyeva, A.B., Kolyakina, E.V., Stakhi, S.A. et al. Synthesis and Study of Thermophysical Properties of Polystyrenes Prepared in the Presence of Conjugated α-Dinitrones Based on Glyoxal. Dokl Chem 501, 225–232 (2021). https://doi.org/10.1134/S001250082111001X

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  • DOI: https://doi.org/10.1134/S001250082111001X

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