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First complexes of diphenylphosphorylalkanones with titanium tetrafluoride

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Abstract

The reaction of TiF4 with a twofold excess of Ph2P(O)CH2C(O)Me (L) (one of the simplest and, very likely, most practically interesting representatives of a new class of organophosphorus ligands—diorganylphosphorylalkanones) in CH2Cl2 has been studied.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. G. Il’in, A. S. Parshakov & V. G. Yarzhemskii

  2. Peoples’ Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia

    V. V. Danilov

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    G. V. Bodrin, E. I. Goryunov & E. E. Nifant’ev

Authors
  1. E. G. Il’in
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  2. A. S. Parshakov
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  3. V. G. Yarzhemskii
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  4. V. V. Danilov
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  5. G. V. Bodrin
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  6. E. I. Goryunov
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  7. E. E. Nifant’ev
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Correspondence to E. G. Il’in.

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Original Russian Text © E.G. Il’in, A.S. Parshakov, V.G. Yarzhemskii, V.V. Danilov, G.V. Bodrin, E.I. Goryunov, E.E. Nifant’ev, 2015, published in Doklady Akademii Nauk, 2015, Vol. 465, No. 3, pp. 314–319.

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Il’in, E.G., Parshakov, A.S., Yarzhemskii, V.G. et al. First complexes of diphenylphosphorylalkanones with titanium tetrafluoride. Dokl Chem 465, 272–277 (2015). https://doi.org/10.1134/S0012500815110075

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  • DOI: https://doi.org/10.1134/S0012500815110075

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