Skip to main content
SpringerLink
Log in

Luminescent Composites Based on Tetrafluoroethylene Copolymer Porous Films Produced by the Diffusion Embedding of Semiconductor Nanoparticles in a Supercritical Medium

  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

A method for creating film composites based on a new material—a fibrous copolymer of tetrafluoroethylene and vinylidene fluoride—using the diffusion embedding of ready-made nanoparticles into a porous matrix in a supercritical (SC) carbon dioxide medium is developed. The method of cold or hot pressing of impregnated porous films was used at the final stage of creation of such composites. The peculiarities of the effect of the supercritical fluid treatment of porous copolymer films on the surface structure of pressed films are discussed. Luminescent composites with semiconductor nanoparticles of cadmium selenide and nanocrystalline silicon are obtained; their radiation covers a range of 500–1000 nm. The change in the luminescence properties of the resulting nanocomposites under the action of excitation laser radiation at 405 nm is demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Nanosilicon, Ed. by V. Kumar (Elsevier, Amsterdam, 2008).

  2. Nanostructured Materials. Processing, Properties and Applications, Ed. by C. C. Koch (William Andrew, New York, 2009).

  3. Biorelated Polymers and Gels, Ed. by T. Okano (Academic, San Diego, 1998).

  4. D. Bera, L. Qian, T-K. Tseng, and P. H. Holloway, Materials 3, 2260 (2010).

    Article  CAS  PubMed Central  Google Scholar 

  5. Y. He, C. Fan, and P. H. Lee, Nano Today 5, 282 (2010).

    Article  CAS  Google Scholar 

  6. R. N. Khramov, I. M. Santalova, L. I. Fakhranurova, A. A. Manokhin, N. B. Simonova, D. I. Rzhevsky, and A. N. Murashev, Biophysics 55, 447 (2010).

    Article  Google Scholar 

  7. A. B. Gapeev, L. I. Fakhranurova, S. I. Paskevich, A. A. Manokhin, S. V. Gudkov, N. B. Simonova, M. S. Vakshtein, and R. N. Khramov, Tekhnol. Zhiv. Sist., No. 6, 16 (2012).

    Google Scholar 

  8. O. E. Semonin, J. M. Luther, and M. C. Beard, Mater. Today 15, 508 (2012).

    Article  CAS  Google Scholar 

  9. V. N. Bagratashvili, M. S. Vakshtein, Yu. S. Zavorotnyi, L. I. Krotova, A. O. Manyashin, V. K. Popov, A. O. Rybaltovskii, I. I. Taraskina, and P. S. Timashev, Perspekt. Mater., No. 2, 39 (2010).

    Google Scholar 

  10. V. N. Bagratashvili, S. G. Dorofeev, A. A. Ischenko, V. V. Koltashev, N. N. Kononov, A. A. Krutikova, A. O. Rybaltovskii, and G. V. Fetisov, Russ. J. Phys. Chem. B 4, 1164 (2010).

    Article  Google Scholar 

  11. V. K. Popov, V. N. Bagratashvili, L. I. Krotova, A. O. Rybaltovskii, D. C. Smith, P. S. Timashev, J. Yang, Yu. S. Zavorotnyi, and S. M. Howdle, Green Chem. 3, 2696 (2011).

    Article  CAS  Google Scholar 

  12. A. O. Rybaltovskii, Yu. S. Zavorotnyi, N. V. Minaev, V. K. Popov, D. S. Rubashnaya, and P. S. Timashev, Russ. J. Phys. Chem. B 10, 1033 (2016).

    Article  CAS  Google Scholar 

  13. A. O. Rybaltovskii, Yu. S. Zavorotnyi, A. P. Sviridov, E. D. Feklichev, A. A. Ishchenko, and V. N. Bagratashvili, Nanotechnol. Russ. 10, 802 (2015).

    Article  CAS  Google Scholar 

  14. V. M. Buznik, Yu. M. Vol’fkovich, V. I. Gryaznov, O. V. Dvoretskaya, M. A. Smul’skaya, V. E. Sosenkin, P. S. Timashev, V. K. Ivanov, A. A. Fomkin, and G. Yu. Yurkov, Perspekt. Mater., No. 9, 59 (2015).

    Google Scholar 

  15. V. M. Buznik and V. G. Kuryavyi, Ross. Khim. Zh. 52 (3), 131 (2008).

    CAS  Google Scholar 

  16. V. N. Bagratashvili, S. G. Dorofeev, N. N. Kononov, G. V. Fetisov, and A. A. Ishchenko, Nanotekhnika 8 (4), 57 (2011).

    Google Scholar 

  17. A. A. Ishchenko, G. V. Fetisov, and L. A. Aslanov, Nanosilicon: Properties, Production, Application, Study and Control Methods (Fizmatlit, Moscow, 2014) [in Russian].

    Book  Google Scholar 

  18. A. A. Ischenko, Y. S. Zavorotny, A. V. Garschev, S. G. Dorofeev, N. N. Kononov, N. V. Minaev, S. A. Mnaeva, A. P. Sviridov, P. S. Timashev, I. I. Khodos, V. I. Yusupov, M. A. Lasov, V. Ya. Panchenko, and V. N. Bagratashvili, J. Mater. Sci. 50, 2247 (2015).

    Article  CAS  Google Scholar 

  19. S. G. Dorofeev, V. N. Bagratashvili, V. P. Dyatchenko, N. N. Kononov, A. O. Rybaltovskii, A. P. Sviridov, G. V. Fetisov, S. I. Tsypina, and A. A. Ishchenko, Nanotekhnika 9 (1), 79 (2012).

    Google Scholar 

  20. W. G. J. H. M. van Sark, P. L. T. M. Frederix, D. J. van den Heuvel, H. C. Gerritsen, A. A. Bol, J. N. J. van Lingen, C. de Mello Donegá, and A. Meijerink, J. Phys. Chem. B 105, 8281 (2001).

    Article  CAS  Google Scholar 

  21. Y. Wang, Z. Tang, M. A. Correa-Duarte, I. Pastoriza-Santos, M. Giersig, N. A. Kotov, and L. M. J. Liz-Marzán, Phys. Chem. B 108, 15461 (2004).

    Article  CAS  Google Scholar 

  22. S. C. Sharma, J. Murphree, and T. Chakraborty, J. Lumin. 128, 1771 (2008).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Skobeltsyn Institute of Nuclear Physics, Moscow State University, Moscow, 199991, Russia

    A. O. Rybaltovskii & Yu. S. Zavorotny

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, 119334, Russia

    V. M. Buznik

  3. Institute of Photonic Technologies, Federal Research Center “Crystallography and Photonics,”, Russian Academy of Sciences, Moscow, 119333, Russia

    P. S. Timashev, S. N. Churbanov & V. N. Bagratashvili

  4. Institute of Regenerative Medicine, Sechenov University, Moscow, 123424, Russia

    P. S. Timashev

Authors
  1. A. O. Rybaltovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Buznik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. S. Zavorotny
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. S. Timashev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. N. Churbanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. N. Bagratashvili
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. O. Rybaltovskii.

Additional information

Original Russian Text © A.O. Rybaltovskii, V.M. Buznik, Yu.S. Zavorotny, P.S. Timashev, S.N. Churbanov, V.N. Bagratashvili, 2017, published in Sverkhkriticheskie Flyuidy. Teoriya i Praktika, 2017, Vol. 12, No. 3, pp. 20–31.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rybaltovskii, A.O., Buznik, V.M., Zavorotny, Y.S. et al. Luminescent Composites Based on Tetrafluoroethylene Copolymer Porous Films Produced by the Diffusion Embedding of Semiconductor Nanoparticles in a Supercritical Medium. Russ. J. Phys. Chem. B 12, 1112–1119 (2018). https://doi.org/10.1134/S1990793118070102

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793118070102

Keywords

Search

Navigation