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Calculation Aspects of Diffusion Coefficients in Micellar Solutions of Ionic Surfactants

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Abstract

Results of calculating diffusion coefficients of ionic surfactants as functions of their concentration in micellar solutions have been analyzed within the framework of the quasi-chemical variant of the law of mass action. Diffusion coefficients have been evaluated for an ideal mixture of monomeric molecules and micelles, as well as taking into account the correction for the variability of the aggregation number of a surfactant using aqueous solutions of hexadecyltrimethylammonium bromide, hexadecylpyridinium chloride and bromide, and alkyltriphenylphosphonium bromides as examples.

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 14-13-00112.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    T. G. Movchan, A. I. Rusanov & E. V. Plotnikova

  2. Mendeleev Center, St. Petersburg State University, 199034, St. Petersburg, Russia

    A. I. Rusanov

Authors
  1. T. G. Movchan
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  2. A. I. Rusanov
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  3. E. V. Plotnikova
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Correspondence to T. G. Movchan.

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Translated by A. Kirilin

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Movchan, T.G., Rusanov, A.I. & Plotnikova, E.V. Calculation Aspects of Diffusion Coefficients in Micellar Solutions of Ionic Surfactants. Colloid J 80, 660–666 (2018). https://doi.org/10.1134/S1061933X1806008X

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  • DOI: https://doi.org/10.1134/S1061933X1806008X

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