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Enhanced magnetoelectric coupling in stretch-induced shear mode magnetoelectric composites

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Abstract

Magnetoelectric (ME) laminates consisting of Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT)-based single crystals have recently attracted significant interest owing to their excellent piezoelectric properties. Particularly, ME laminates with d15-mode single crystals exhibit the strongest ME coupling, but the fabrication of ME laminates with 15 shear modes is challenging. Herein, we propose the generation of a stretch–shear mode (d15-mode) by clamping the opposite ends of the top and bottom magnetostrictive layers in symmetric ME laminates. Two different shear-stress-induced ME laminates were fabricated using Metglas/Galfenol as magnetostrictive layer, and 15-PMN-PZT as a piezoelectric layer. The ME laminates were studied under two different conditions, unclamped and clamped. Under unclamped condition, Galfenol/15-PMN-PZT/Galfenol (Metglas/15-PMN-PZT/Metglas) laminate showed maximum αME value of 1.71 V/cm∙Oe (0.62 V/cm∙Oe), while under clamped condition, Galfenol/d15-PMN-PZT/Galfenol (Metglas/15-PMN-PZT/Metglas) laminate exhibited an enhanced αME value of 2.40 V/cm∙Oe (0.87 V/cm∙Oe), indicating successful generation of the stretch–shear mode. Under clamped condition, αME was enhanced by 140% compared with the that of the unclamped case, suggesting a 40% (0.25 V/cm∙Oe) contribution from the pure shear ME voltage coefficient along with the longitudinal extension contribution.

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Acknowledgements

This study was primarily supported by the Global Frontier R&D Program at the Center for Hybrid Interface Materials (HIM) funded by the Ministry of Science, ICT, and Future Planning Korea (Grant No. NRF-2016M3A6B1925390), the National Research Foundation of Korea (NRF-2019R1A2B5B01070100), and the National Research Council of Science and Technology (NST) grant by the Korean Government (MSIP, No. CAP-17-04-KRISS).

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  1. School of Materials Science and Engineering, Yeungnam University, Gyeongsan, 38541, South Korea

    Deepak Rajaram Patil, Sung Hoon Park, Seema Patil, Ajeet Kumar & Jungho Ryu

  2. Institute of Materials Technology, Yeungnam University, Gyeongsan, 38541, Korea

    Jungho Ryu

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  1. Deepak Rajaram Patil
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Patil, D.R., Park, S.H., Patil, S. et al. Enhanced magnetoelectric coupling in stretch-induced shear mode magnetoelectric composites. J. Korean Ceram. Soc. 58, 700–705 (2021). https://doi.org/10.1007/s43207-021-00144-2

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