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Revealing the charge transfer mechanism in Er ion-doped Bi4O5Br2/g-C3N5 nanocomposite for efficient photocatalytic degradation of antibiotic tetracycline

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Abstract

Pharmaceutical products occurring in freshwater bodies create numerous problems for the water bodies owing to their bio-toxic nature. In order to remove such pharmaceutical pollutants, a novel Er-doped Bi4O5Br2/g-C3N5 nanocomposite was prepared by one-pot synthesis and applied for the photocatalytic removal process. The Er ions doped on the surface of Bi4O5Br2/g-C3N5 nanocomposite exhibited 97% degradation of tetracycline in 60 min under visible light irradiation, which is higher than pure g-C3N5 and Bi4O5Br2 photocatalysts. The improved photocatalytic properties are attributed to the outstanding visible light harvesting capacity and quick charge carrier separation efficiency which greatly reduced the recombination rate in the heterojunctions. Based on radical trapping experiments, the •O2−, h+ and •OH radicals played a prominent role in the photodegradation reactions under visible light. Finally, the ternary Er-doped Bi4O5Br2/g-C3N5 nanocomposite is effectively recyclable with quite a stable photocatalytic removal rate. This work enables a new perspective on the rational design of rare-earth-based nanocomposites for various pharmaceutical pollutants treatment processes.

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References

  1. Yang M, Chen Y, Wang H, Zou Y, Wu P, Zou J, Jiang J (2022) Solvothermal preparation of CeO2 nanoparticles-graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol. Carbon Lett 32:1277–1285

    Google Scholar 

  2. Syed N, Huang J, Feng Y (2022) CQDs as emerging trends for future prospect in enhancement of photocatalytic activity. Carbon Lett 32:81–97

    Google Scholar 

  3. Ge J, Zhang Z, Ouyang Z, Shang M, Liu P, Li H, Guo X (2022) Photocatalytic degradation of (micro)plastics using TiO2-based and other catalysts: properties, influencing factor, and mechanism. Environ Res 209:112729

    CAS  Google Scholar 

  4. Jia Y, Liu P, Wang Q, Wu Y, Cao D, Qiao Q (2021) Construction of Bi2S3-BiOBr nanosheets on TiO2 NTA as the effective photocatalysts: pollutant removal, photoelectric conversion and hydrogen generation. J Colloid Interface Sci 585:459–469

    CAS  Google Scholar 

  5. Jiang J, Xiong Z, Wang H, Liao G, Bai S, Zou J, Wu P, Zhang P, Li X (2022) Sulfur-doped g-C3N4/g-C3N4 isotype step-scheme heterojunction for photocatalytic H2 evolution. J Mater Sci Technol 118:15–24

    CAS  Google Scholar 

  6. Zou J, Liao G, Wang H, Ding Y, Wu P, Hsu J, Jiang J (2022) Controllable interface engineering of g-C3N4/CuS nanocomposite, photocatalysts. J Alloy Compd 911:165020

    CAS  Google Scholar 

  7. Wang Y, Rao L, Wang P, Shi Z, Zhang L (2020) Photocatalytic activity of N-TiO2/O-doped N vacancy g-C3N4 and the intermediates toxicity evaluation under tetracycline hydrochloride and Cr (VI) coexistence environment. Appl Catal B-Environ 262:118308

    CAS  Google Scholar 

  8. Khan M, Fung CSL, Kumar A, Lo IMC (2019) Magnetically separable BiOBr/ Fe3O4@SiO2 for visible-light-driven photocatalytic degradation of ibuprofen: mechanistic investigation and prototype development. J Hazard Mater 365:733–743

    CAS  Google Scholar 

  9. Guo Y, Zhang J, Zhou DD, Dong SS (2018) Fabrication of Ag/CDots/BiOBr ternary photocatalyst with enhanced visible-light driven photocatalytic activity for 4- chlorophenol degradation. J Mol Liq 262:194–203

    CAS  Google Scholar 

  10. Wang Q, Wang W, Zhong LL, Liu DM, Cao XZ, Cui FY (2018) Oxygen vacancy rich 2D/2D BiOCl-g-C3N4 ultrathin heterostructure nanosheets for enhanced visible light-driven photocatalytic activity in environmental remediation. Appl Catal B Environ 220:290–302

    CAS  Google Scholar 

  11. Zhao WL, Wang WL, Shi HF (2020) 2D/2D Z-scheme BiO1-XBr/g-C3N4 heterojunction with rich oxygen vacancies as electron mediator for enhanced visible light degradation activity. Appl Surf Sci 528:146925

    CAS  Google Scholar 

  12. Zhang Y, Ma Y, Liu Q, Jiang H, Wang Q, Qu D, Shi J (2017) Synthesis of Er3+/Zn2+ co-doped Bi2WO6 with highly efficient photocatalytic performance under natural indoor weak light illumination. Ceram Int 43(2):2598–2605

    CAS  Google Scholar 

  13. Yi F, Ma J, Lin C, Wang L, Zhang H, Qian Y, Zhang K (2020) Insights into the enhanced adsorption/photocatalysis mechanism of a Bi4O5Br2/g-C3N4 nanosheet. J Alloys Compd 821:153557

    CAS  Google Scholar 

  14. Cai Z, Huang Y, Ji H, Liu W, Fu J, Sun X (2022) Type-II surface heterojunction of bismuth-rich Bi4O5Br2 on nitrogen-rich g-C3N5 nanosheets for efficient photocatalytic degradation of antibiotics. Sep Purif Technol 280:119772

    CAS  Google Scholar 

  15. Huang R, Wu J, Zhang M, Liu B, Zheng Z, Luo D (2021) Strategies to enhance photocatalytic activity of graphite carbon nitride-based photocatalysts. Mater Design 210:110040

    CAS  Google Scholar 

  16. Liu W, Zhang D, Wang R, Zhang Z, Qiu S (2022) 2D/2D interface engineering promotes charge separation of Mo2C/g-C3N4 nanojunction photocatalysts for efficient photocatalytic hydrogen evolution. ACS Appl Mater Interfaces 14(28):31782–31791

    CAS  Google Scholar 

  17. Meng F, Chang Y, Qin W, Yuan Z, Zhao J, Zhang J et al (2019) ZnO-reduced graphene oxide composites sensitized with graphitic carbon nitride nanosheets for ethanol sensing. ACS Appl Nano Mater 2(5):2734–2742

    CAS  Google Scholar 

  18. Ong W-J, Tan L-L, Ng YH, Yong S-T, Chai S-P (2016) Graphitic carbon nitride (g-C3N4)-based photocatalysts for artificial photosynthesis and environmental remediation: are we a step closer to achieving sustainability? Chem Rev 116(12):7159–7329

    CAS  Google Scholar 

  19. Ramachandra M, Devi Kalathiparambil Rajendra Pai S, ResnikJaleel UJ, Pinheiro D (2020) Improved photocatalytic activity of g-C3N4/ZnO: a potential direct Z-scheme nanocomposite. ChemistrySelect 5:11986–11995

    CAS  Google Scholar 

  20. Kang J, Jin C, Li Z, Wang M, Chen Z, Wang Y (2020) Dual Z-scheme MoS2/gC3N4/Bi24O31Cl10 ternary heterojunction photocatalysts for enhanced visible-light photodegradation of antibiotic. J Alloys Compd 825:153975

    CAS  Google Scholar 

  21. Mao DJ, Ding SS, Meng LJ, Dai YX, Sun C, Yang SG, He H (2017) One-pot microemulsion-mediated synthesis of Bi-rich Bi4O5Br2 with controllable morphologies and excellent visible-light photocatalytic removal of pollutants. Appl Catal B Environ 207:153–165

    CAS  Google Scholar 

  22. Yang LW, Liang LL, Wang LJ, Zhu JC, Gao SW, Xia XF (2019) Accelerated photocatalytic oxidation of carbamazepine by a novel 3D hierarchical protonated gC3N4/BiOBr heterojunction: performance and mechanism. Appl Surf Sci 473:527–539

    CAS  Google Scholar 

  23. Xu MW, Ye MY, Zhou X, Cheng JS, Huang C, Wong WL, Wang ZG (2020) One-pot controllable synthesis of BiOBr/β-Bi2O3 nanocomposites with enhanced photocatalytic degradation of norfloxacin under simulated solar irradiation. J Alloys Compd 816:152664

    CAS  Google Scholar 

  24. Vadivel S, Hariganesh S, Paul Mamba G, Puviarasu P (2020) Highly active novel CeTi2O6/g-C3N4 photocatalyst with extended spectral response towards removal of endocrine disruptor 2, 4-dichlorophenol in aqueous medium. Colloids Surf A Physicochem Eng Asp 592:124583

    CAS  Google Scholar 

  25. Ehsan MF, Fazal A, Hamid S, Arfan M, Khan I, Usman M, Shafiee A, Ashiq MN (2020) CoFe2O4 decorated g-C3N4 nanosheets: new insights into superoxide anion mediated photomineralization of methylene blue. J Environ Chem Eng 8:104556

    CAS  Google Scholar 

  26. Xie Z, Feng Y, Wang F, Chen D, Zhang Q, Zeng Y, Lv W, Liu G (2018) Construction of carbon dots modified MoO3/g-C3N4 Z-scheme photocatalyst with enhanced visible-light photocatalytic activity for the degradation of tetracycline. Appl Catal B Environ 229:96–104

    CAS  Google Scholar 

  27. You Q, Zhang Q, Gu M, Du R, Chen P, Huang J, Wang Y, Deng S, Yu G (2022) Self-assembled graphitic carbon nitride regulated by carbon quantum dots with optimized electronic band structure for enhanced photocatalytic degradation of diclofenac. Chem Eng J 431:133927

    CAS  Google Scholar 

  28. Chen B, Zhou L, Tian YH, Yu J, Lei JY, Wang LZ, Liu YD, Zhang JL (2019) Z-scheme inverse opal CN/BiOBr photocatalysts for highly efficient degradation of antibiotics. Phys Chem Chem Phys 21:12818–12825

    CAS  Google Scholar 

  29. Chen M, Bai RN, Jin P, Li JW, Yan Y, Peng AZ, He JL (2021) A facile hydrothermal synthesis of few-layer oxygen-doped g-C3N4 with enhanced visible light-responsive photocatalytic activity. J Alloys Compd 869:159292

    CAS  Google Scholar 

  30. Feng Z, Zeng L, Zhang QL, Ge SF, Zhao XY, Lin HJ, He YM (2020) In situ preparation of g-C3N4 /Bi4O5I2 complex and its elevated photoactivity in methyl orange degradation under visible light. J Environ Sci 87:149–162

    CAS  Google Scholar 

  31. Guo FR, Chen JC, Zhao JZ, Chen Z, Xia DS, Zhan ZL, Wang Q (2020) Zscheme heterojunction g-C3N4@PDA/BiOBr with biomimetic polydopamine as electron transfer mediators for enhanced visible-light driven degradation of sulfamethoxazole. Chem Eng J 386:124014

    CAS  Google Scholar 

  32. Hao JQ, Wang QF, Zhao ZB (2017) Synthesis and characterization of g-C3N4/ BiNbO4 composite materials with visible light photocatalytic activity. J Photochem Photobiol A 335:94–101

    CAS  Google Scholar 

  33. Hou YP, Gan YY, Yu ZB, Chen XX, Qian L, Zhang BG, Huang LR, Huang J (2017) Solar promoted azo dye degradation and energy production in the biophotoelectrochemical system with a g-C3N4/BiOBr heterojunction photocathode. J Power Sour 371:26–34

    CAS  Google Scholar 

  34. Vesali-Kermani E, Habibi-Yangjeh A, Ghosh S (2020) Visible-light-induced nitrogen photofixation ability of g-C3N4 nanosheets decorated with MgO nanoparticles. J Ind Eng Chem 84:185–195

    CAS  Google Scholar 

  35. Zhu BL, Li XF, Wang Y, Liu N, Tian Y, Yang JH (2021) Visiblelight-driven photocatalytic degradation of RhB by carbon-quantum-dot-modifed g-C3N4 on carbon cloth. Cryst Eng Commun 23:4782–4790

    CAS  Google Scholar 

  36. Velmurugan P, Kuma RV, Sivakumar S, Ravi AV (2022) Fabrication of blue fuorescent carbon quantum dots using green carbon precursor Psidium guajava leaf extract and its application in water treatment. Carbon Lett 32:119–129

    Google Scholar 

  37. Jin CY, Kang J, Li ZL, Wang M, Wu ZM, Xie YH (2020) Enhanced visible light photocatalytic degradation of tetracycline by MoS2/Ag/ g-C3N4 Z-scheme composites with peroxymonosulfate. Appl Surf Sci 514:146076

    CAS  Google Scholar 

  38. Chenrayan S, Chandra K, Manickam S (2017) Ultrathin MoS2 sheets supported on N-rich carbon nitride nanospheres with enhanced lithium storage properties. Appl Surf Sci 410:215–224

    CAS  Google Scholar 

  39. Liu CB, Mao DX, Pan J, Qian JC, Zhang WY, Chen F, Chen ZG, Song YN (2019) Fabrication of highly efficient heterostructured Ag-CeO2/g-C3N4 hybrid photocatalyst with enhanced visible-light photocatalytic activity. J Rare Earths 37(12):1269–1278

    CAS  Google Scholar 

  40. Huang J, Nie G, Ding YB (2020) Metal-free enhanced photocatalytic activation of di oxygen by g-C3N4 doped with abundant oxygen-containing functional groups for selective N-deethylation of rhodamine B. Catalysts 10:6

    CAS  Google Scholar 

  41. Zhao Y et al (2016) Fabrication of BiOBr nanosheets@ TiO2 nanobelts p–n junction photocatalysts for enhanced visible-light activity. Appl Surf Sci 365:209–217

    CAS  Google Scholar 

  42. Zou X et al (2017) The highly enhanced visible light photocatalytic degradation of gaseous o-dichlorobenzene through fabricating like-flowers BiPO4/BiOBr pn heterojunction composites. Appl Surf Sci 391:525–534

    CAS  Google Scholar 

  43. Guo Y et al (2015) In situ crystallization for fabrication of a core-satellite structured BiOBr–CdS heterostructure with excellent visible-light-responsive photoreactivity. Nanoscale 7(27):11702–11711

    CAS  Google Scholar 

  44. Yu X et al (2017) A three-dimensional BiOBr/RGO heterostructural aerogel with enhanced and selective photocatalytic properties under visible light. Appl Surf Sci 396:1775–1782

    CAS  Google Scholar 

  45. Zheng M et al (2020) Novel recyclable BiOBr/Fe3O4/RGO composites with remarkable visible-light photocatalytic activity. RSC Adv 10(34):19961–19973

    CAS  Google Scholar 

  46. Yaghoubi-berijani M, Bahramian B (2021) Preparation and measurement of properties of BiOBr/BiOCl/PANI ternary nanocomposite for highly efficient visible light photocatalytic applications. Res Chem Intermed 47(6):2311–2330

    CAS  Google Scholar 

  47. Jia X et al (2017) Transforming type-I to type-II heterostructure photocatalyst via energy band engineering: a case study of I-BiOCl/I-BiOBr. Appl Catal B Environ 204(2017):505–514

    CAS  Google Scholar 

  48. Guan S et al (2020) Preparation and promising application of novel LaFeO3/BiOBr heterojunction photocatalysts for photocatalytic and photo-Fenton removal of dyes. Opt Mater 100:109644

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering and Technology, SRM Institute of Science and Technology, Kattankulathur, Chennai, Tamil Nadu, 603202, India

    Sethumathavan Vadivel

  2. Departamento de Ingenieria Mecanica, Facultad de Ingenieria, Universidad de Tarapaca, Avda. General Velasquez, 1775, Arica, Chile

    Lalitha Gnanasekaran

  3. Centre for Energy Storage Technologies Anna University, Chennai, Tamil Nadu, 600025, India

    N. Balasubramanian

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  1. Sethumathavan Vadivel
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  2. Lalitha Gnanasekaran
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  3. N. Balasubramanian
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Correspondence to Sethumathavan Vadivel.

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Vadivel, S., Gnanasekaran, L. & Balasubramanian, N. Revealing the charge transfer mechanism in Er ion-doped Bi4O5Br2/g-C3N5 nanocomposite for efficient photocatalytic degradation of antibiotic tetracycline. Carbon Lett. 33, 2277–2286 (2023). https://doi.org/10.1007/s42823-023-00549-5

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