Abstract
The current paper experimentally investigates the effects of partial replacement of cement by nano-TiO2 (NT) in concrete in varying proportions by weight. NT was added by weight of cement with partial replacement of 0%, 0.5%, 1.5%, 2.0%, 2.5%, and 3.0% using Portland Pozzolana Cement in C20/25 grade of concrete. The physical and mechanical properties of concrete so produced were evaluated and durability aspects such as slump, sorptivity, half-cell potential, and drying shrinkage were also conducted. The fresh concrete produced showed a drastic reduction of the slump with increasing percentage replacement with 74% reduction at 3.0% replacement compared to the control mix. Further, the 7, 28, 56, and 90 days compressive, flexural, and split tensile strength showed a peak at 1.5% NT after which the values dropped in strength by 34.5%, 27%, and 19% concerning the control mix for 2.0%, 2.5%, and 3.0% replacement levels, respectively. From the microstructural studies, it could be concluded that nano-TiO2 acts as a filler material and can be used as a partial replacement for cement effectively up to 3% of the weight of cement in concrete. Thus, incorporating nanoparticles could cause more strength and resistance to water permeability of the specimens.
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References
Abdalla, J. A., Thomas, B. S., Hawileh, R. A., Yang, J., Jindal, B. B., & Ariyachandra, E. (2022). Influence of nano-TiO2, nano-Fe2O3, nanoclay and nano-CaCO3 on the properties of cement/geopolymer concrete. Cleaner Materials, 4(March), 100061. https://doi.org/10.1016/j.clema.2022.100061
ASTM C1202. (2012). Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. American Society for Testing and Materials. https://doi.org/10.1520/C1202-12.2
Bassuoni, M. T., Nehdi, M. L., & Greenough, T. R. (2006). Enhancing the reliability of evaluating chloride ingress in concrete using the ASTM C 1202 rapid chloride penetrability test. J ASTM Int. https://doi.org/10.1520/jai13403
BIS, “IS 10500. (2012). 2012 Indian Standard Drinking Water Specification (Second Revision),” Bureau of Indian Standards, vol. IS 10500, no. May, pp. 1–11, [Online]. Available: http://cgwb.gov.in/Documents/WQ-standards.pdf
B. of I. S. (BIS). (1970). IS 383: 1970 Specification for coarse and fine aggregates from natural sources for concrete. Indian Standards, pp. 1–24.
B. of I. Standards. (2013). “(Bureau of Indian Standards, ‘IS 12269–2013,’ Indian Stand. ordinary portland-Cement Specification First revision,” Bureau of Indian Standards
1999 BIS (Bureau of Indian Standards, New Delhi):5816:1999. Indian standards for Splitting tensile strength of concrete-method of test, Reaffirmed 1999. “No Title”.
Bureau of Indian Standards, IS 1727. (1967). Methods of test for pozzolanic materials
Bureau of Indian Standards. (2004). Method of tests for strength of concrete, IS: 516-1959b (Reaffirmed 2004), p. New Delhi, India. https://doi.org/10.3403/02128947
Bureau of Indian Standards. (2014) Method of tests for strength of concrete. IS: 516-1959a (Reaffirmed 2014), p. New Delhi, India. https://doi.org/10.3403/02128947.
Bureau of Indian Standards. (2016). Bureau of Indian Standards, ‘IS: 2386–1963,’ Indian Stand. methods test aggregates Concr. (Part-I to Part-VIII). Revision 2016,” Bureau of Indian Standards.
Chen, J., Kou, S. C., & Poon, C. S. (2012). Hydration and properties of nano-TiO2 blended cement composites. Cement and Concrete Composites, 34(5), 642–649. https://doi.org/10.1016/j.cemconcomp.2012.02.009
Detwiler, R. J. (1994). Use of supplementary cementing materials to increase the resistance to chloride ion penetration of concretes cured at elevated temperature. ACI Materials Journal, 91, 63–66.
Du, S., Wu, J., Alshareedah, O., & Shi, X. (2019). Nanotechnology in cement-based materials: A review of durability, modeling, and advanced characterization. Nanomaterials. https://doi.org/10.3390/nano9091213
Du, Y., Yang, J., Skariah Thomas, B., Li, L., Li, H., & Nazar, S. (2020). Hybrid graphene oxide/carbon nanotubes reinforced cement paste: An investigation on hybrid ratio. Construction and Building Materials, 261, 119815. https://doi.org/10.1016/j.conbuildmat.2020.119815
Du, Y., et al. (2020b). Influence of hybrid graphene oxide/carbon nanotubes on the mechanical properties and microstructure of magnesium potassium phosphate cement paste. Construction and Building Materials, 260, 120449. https://doi.org/10.1016/j.conbuildmat.2020.120449
Essawy, A. A., & Abd, S. (2014). Physico-mechanical properties, potent adsorptive and photocatalytic efficacies of sulfate resisting cement blends containing micro silica and nano-TiO2. Construction and Building Materials, 52, 1–8. https://doi.org/10.1016/j.conbuildmat.2013.11.026
Gailius, A., & Kosior-Kazberuk, M. (2008). Monitoring of concrete resistance to chloride penetration. Medziagotyra, 14(4), 350–355.
Guo, Z., Chen, C., Lehman, D. E., Xiao, W., Zheng, S., & Fan, B. (2020). Mechanical and durability behaviours of concrete made with recycled coarse and fine aggregates. European Journal of Environmental and Civil Engineering, 24(2), 171–189. https://doi.org/10.1080/19648189.2017.1371083
IS 5816–1999. (1999). Indian standard Splitting tensile strength of concrete-method of test. Bureau of Indian Standards, pp. 1–14
IS 456:2000 (2000). Plain and reinforced concrete-code of practice (Fourth Revision). Bureau of Indian Standards, New Delhi, India, no. July, p. New Delhi, India
IS 516:2014. (2004). Method of tests for strength of concrete. IS: 516-1959 (Reaffirmed 2004), New Delhi, India
IS 10262. (2009) Guidelines for concrete mix design proportioning (CED 2: Cement and Concrete). Bureau of Indian Standards, New Delhi, p. New Delhi, India
IS 2386- Part III. (2016). Method of test for aggregate for concrete. Part III-Specific gravity, density, voids, absorption and bulking. Bureau of Indian Standards, New Delhi, 2016.
Isfahani, F. T., Redaelli, E., Lollini, F., Li, W., & Bertolini, L. (2016). Effects of nanosilica on compressive strength and durability properties of concrete with different water to binder ratios. Advances in Materials Science and Engineering. https://doi.org/10.1155/2016/8453567
Janus, M., Madraszewski, S., Zajac, K., Kusiak-Nejman, E., Morawski, A. W., & Stephan, D. (2019). Photocatalytic activity and mechanical properties of cements modified with TiO2/N. Materials. https://doi.org/10.3390/ma12223756
Jayapalan, A. R., Lee, B. Y., & Kurtis, K. E. (2009). Effect of Nano-sized titanium dioxide on early age hydration of portland cement. Nanotechnology in Construction, 3, 267–273. https://doi.org/10.1007/978-3-642-00980-8_35
Joshaghani, A. (2018). Evaluating the effects titanium dioxide on resistance of cement mortar against combined chloride and sulfate attack. Structural Concrete, 19(5), 1318–1327. https://doi.org/10.1002/suco.201800002
Khataee, R., Heydari, V., Moradkhannejhad, L., Safarpour, M., & Joo, S. W. (2013). Self-cleaning and mechanical properties of modified white cement with nanostructured TiO2. Journal of Nanoscience and Nanotechnology, 13(7), 5109–5114. https://doi.org/10.1166/jnn.2013.7586
Kim, J. H., Sung, J. H., Jeon, C. S., Lee, S. H., & Kim, H. S. (2019). A study on the properties of recycled aggregate concrete and its production facilities. Applied Sciences (Switzerland). https://doi.org/10.3390/app9091935
Kou, S. C., Poon, C. S., & Agrela, F. (2011). Comparisons of natural and recycled aggregate concretes prepared with the addition of different mineral admixtures. Cement and Concrete Composites, 33(8), 788–795. https://doi.org/10.1016/j.cemconcomp.2011.05.009
H. Layssi, P. Ghods, A. R. Alizadeh, & M. Salehi. (2015). Electrical resistivity of concrete: Concepts, applications, and measurement techniques. Concrete International, pp. 41–46
Lee, B. Y., & Kurtis, K. E. (2010). Influence of TiO2 nanoparticles on early C3S hydration. Journal of the American Ceramic Society, 93(10), 3399–3405. https://doi.org/10.1111/j.1551-2916.2010.03868.x
Li, H., Hua Zhang, M., & Ping Ou, J. (2006). Abrasion resistance of concrete containing nano-particles for pavement. Wear, 260(11–12), 1262–1266. https://doi.org/10.1016/j.wear.2005.08.006
Li, H., Hua Zhang, M., & Ping Ou, J. (2007). Flexural fatigue performance of concrete containing nano-particles for pavement”. International Journal of Fatigue, 29(7), 1292–1301. https://doi.org/10.1016/j.ijfatigue.2006.10.004
Loto, C. A., Joseph, O. O., Loto, R. T., & Popoola, A. P. I. (2015). Effect of zinc oxide on the corrosion inhibition of mild steel embedded in concrete in 3.5% NACL solution. Der Pharma Chemica, 7(12), 85–96.
D. Menetrier, I. Jawed, & J. Skalny. (1980). Effect of gypsum on C 3 S hydration. Cement and Concrete Research, I(c), 697–701 [Online]. Available at http://www.sciencedirect.com/science/article/pii/0008884680900332
Methods of test for Strength of Concrete.(1999). Bureau of Indian BIS: 516–1959 and I. Standard, New Delhi-1999, “No Title”.
Method of analysis and sampling of concrete. (2002). Bureau of Indian Standards, “IS:1199–1999, “No Title”.
Mohammadi, M., Hesaraki, S., & Hafezi-Ardakani, M. (2014). Investigation of biocompatible nanosized materials for development of strong calcium phosphate bone cement: Comparison of nano-titania, nano-silicon carbide and amorphous nano-silica. Ceramics International, 40(6), 8377–8387. https://doi.org/10.1016/j.ceramint.2014.01.044
Nazari, A. (2011). The effects of curing medium on flexural strength and water permeability of concrete incorporating TiO2 nanoparticles. Materials and Structures/Materiaux et Constructions, 44(4), 773–786. https://doi.org/10.1617/s11527-010-9664-y
Nazari, A., & Riahi, S. (2011a). The effects of ZnO2 nanoparticles on strength assessments and water permeability of concrete in different curing media. Materials Research, 14(2), 178–188. https://doi.org/10.1590/S1516-14392011005000030
Nazari, A., & Riahi, S. (2011b). TiO2 nanoparticles’ effects on properties of concrete using ground granulated blast furnace slag as binder. Science China Technological Sciences, 54(11), 3109–3118. https://doi.org/10.1007/s11431-011-4421-1
Nazari, A., Riahi, S., Riahi, S., Shamekhi, S. F., & Khademno, A. (2010). Improvement the mechanical properties of the cementitious composite by using TiO2 nanoparticles. Journal of American Science, 6(4), 98–101.
Nazar, S., Yang, J., Thomas, B. S., Azim, I., & Ur Rehman, S. K. (2020). Rheological properties of cementitious composites with and without nano-materials: A comprehensive review. Journal of Cleaner Production, 272(July), 122701. https://doi.org/10.1016/j.jclepro.2020.122701
NT Build 492. (1999). Concrete, mortar and cement-based repair materials: Chloride migration coefficient from non-steady-state migration experiments. Measurement, 1–8
Saleem, H., Zaidi, S. J., & Alnuaimi, N. A. (2021). Recent advancements in the nanomaterial application in concrete and its ecological impact. Materials. https://doi.org/10.3390/ma14216387
Salemi, N. (2014). Effect of nanoparticles on frost durability of crvihoefcf. 15(3): 411–420
Saloma, A. N., Imran, I., & Abdullah, M. (2015). Improvement of concrete durability by nanomaterials. Procedia Engineering, 125, 608–612. https://doi.org/10.1016/j.proeng.2015.11.078
Senff, L., Tobaldi, D. M., Lucas, S. S., Hotza, D., Ferreira, V. M., & Labrincha, J. A. (2013). Formulation of mortars with nano-SiO2 and nano-TiO2 for degradation of pollutants in buildings. Composites Part B: Engineering, 44(1), 40–47. https://doi.org/10.1016/j.compositesb.2012.07.022
Shekari, A. H., & Razzaghi, M. S. (2011). Influence of nano particles on durability and mechanical properties of high performance concrete. Procedia Engineering, 14, 3036–3041. https://doi.org/10.1016/j.proeng.2011.07.382
Shen, W., Zhang, C., Li, Q., Zhang, W., Cao, L., & Ye, J. (2015). Preparation of titanium dioxide nano particle modified photocatalytic self-cleaning concrete. Journal of Cleaner Production, 87(C), 762–765. https://doi.org/10.1016/j.jclepro.2014.10.014
Sorathiya, J., Shah, S., & Kacha, S. (2018). Effect on addition of nano "titanium dioxide” (TiO2) on compressive strength of cementitious concrete. Kalpa Publications in Civil Engineering, 1, 219–211. https://doi.org/10.29007/sq9d
Tam, V. W. Y., Wang, K., & Tam, C. M. (2008). Assessing relationships among properties of demolished concrete, recycled aggregate and recycled aggregate concrete using regression analysis. Journal of Hazardous Materials, 152(2), 703–714. https://doi.org/10.1016/j.jhazmat.2007.07.061
Wang, H., Zhao, P., Wang, S., Lu, L., & Cheng, X. (2017). Effect of well-dispersed nano-TiO2 on sulphoaluminate cement hydration and its application in photo-degradation. Ceramics-Silikaty, 61(4), 301–308. https://doi.org/10.13168/cs.2017.0029
Wang, J., Zhang, J., Cao, D., Dang, H., & Ding, B. (2020). Comparison of recycled aggregate treatment methods on the performance for recycled concrete. Construction and Building Materials, 234, 117366. https://doi.org/10.1016/j.conbuildmat.2019.117366
Xuan, D., Zhan, B., & Poon, C. S. (2017). Durability of recycled aggregate concrete prepared with carbonated recycled concrete aggregates. Cement and Concrete Composites, 84, 214–221. https://doi.org/10.1016/j.cemconcomp.2017.09.015
Zhang, M. H., & Li, H. (2011). Pore structure and chloride permeability of concrete containing nano-particles for pavement. Construction and Building Materials, 25(2), 608–616. https://doi.org/10.1016/j.conbuildmat.2010.07.032
Zhang, R., Cheng, X., Hou, P., & Ye, Z. (2015). Influences of nano-TiO2 on the properties of cement-based materials: Hydration and drying shrinkage. Construction and Building Materials, 81, 35–41. https://doi.org/10.1016/j.conbuildmat.2015.02.003
Zhang, H., Wang, Y., Lehman, D. E., Geng, Y., & Kuder, K. (2020). Time-dependent drying shrinkage model for concrete with coarse and fine recycled aggregate. Cement and Concrete Composites, 105(May 2019), 103426. https://doi.org/10.1016/j.cemconcomp.2019.103426
Zhang, J., Shen, C., & Diao, G. (2022). Application and microstructure properties of nanomaterials in new concrete materials. Journal of Nanomaterials. https://doi.org/10.1155/2022/7396295
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The authors wish to thank to the faculties and staff of Department of Civil Engineering at Jaypee University of Engineering and Technology, Guna, for the technical support.
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Garima Rawat and Yogesh Murthy wrote the main manuscript text and Yogesh prepared figures. All authors reviewed the manuscript
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Rawat, G., Gandhi, S. & Murthy, Y.I. Strength and rheological aspects of concrete containing nano-titanium dioxide. Asian J Civ Eng 23, 1197–1208 (2022). https://doi.org/10.1007/s42107-022-00476-2
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DOI: https://doi.org/10.1007/s42107-022-00476-2