Abstract
The effect of nano-scale non-reactive anatase titanium dioxide (TiO2) on early age hydration of cement was experimentally studied. Isothermal calorimetry was performed on cement pastes with two different particle sizes of TiO2 at replacement levels of 5, 7.5 and 10%. The addition of TiO2 to cement increased the heat of hydration and accelerated the rate of reaction at early stages of hydration. This increase was found to be proportional to the percentage addition and the fineness of TiO2. These results demonstrate that the addition of non-reactive nano-scale fillers could affect the rate of cement hydration by heterogeneous nucleation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Gutteridge, W.A., Dalziel, J.A.: The effect of the secondary component on the hydration of Portland cement: Part I. A fine non-hydraulic filler. Cement Concrete Res 20(5), 778–782 (1990)
Kadri, E., Duval, R.: Effect of ultrafine particles on heat of hydration of cement mortars. ACI Mater J. 99(2), 138–142 (2002)
Lothenbach, B., et al.: Influence of limestone on the hydration of Portland cements. Cement Concrete Res. 38(6), 848–860 (2008)
Lawrence, P., Cyr, M., Ringot, E.: Mineral admixtures in mortars - Effect of inert materials on short-term hydration. Cement Concrete Res. 33(12), 1939–1947 (2003)
Zelic, J., et al.: The role of silica fume in the kinetics and mechanisms during the early stage of cement hydration. Cement Concrete Res. 30(10), 1655–1662 (2000)
Gutteridge, W.A., Dalziel, J.A.: Filler cement: The effect of the secondary component on the hydration of Portland cement: Part 2: Fine hydraulic binders. Cement Concrete Res. 20(6), 853–861 (1990)
Tanaka, K., Capule, M.F.V., Hisanaga, T.: Effect of crytallinity of TiO2 on its photocatalytic action. Chem. Phys. Lett. 187(1-2), 73–76 (1991)
Bianchi, C.L., et al.: The role of the synthetic procedure of nano-crystalline TiO2 on the photodegradation of toluene. In: International RILEM Symposium on Photocatalysis, Environment, and Construction Materials - TDP 2007, Rilem Publications, Florence (2007)
Jo, B.W., et al.: Characteristics of cement mortar with nano-SiO2 particles. Constr. Build. Mater. 21(6), 1351–1355 (2007)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Jayapalan, A.R., Lee, B.Y., Kurtis, K.E. (2009). Effect of Nano-sized Titanium Dioxide on Early Age Hydration of Portland Cement. In: Bittnar, Z., Bartos, P.J.M., Němeček, J., Šmilauer, V., Zeman, J. (eds) Nanotechnology in Construction 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-00980-8_35
Download citation
DOI: https://doi.org/10.1007/978-3-642-00980-8_35
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-00979-2
Online ISBN: 978-3-642-00980-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)