Skip to main content
Log in

Investigation of the Thermal and Mechanical Properties of Organic Waste Reinforced Polyester Composites

  • Research Paper
  • Published:
Iranian Journal of Science and Technology, Transactions of Civil Engineering Aims and scope Submit manuscript

Abstract

The aim of the research is to investigate the usability of composites produced using the organic waste from hazelnut and corn processing in the Black Sea Region in constructional applications with regard to mechanical and thermal conduction. Polymer composite test samples were produced to which hazelnut shells, corn stalk, nettle stalk (excl. fibres) and nettle fibres had been added in varying (5, 10, 15, 20%) weights to the polyester matrix. Thermal conductivity coefficients were determined in the context of the thermal properties of composite samples. In addition, mechanical properties were determined by compression strength and a three-point bending test. The physical properties of the wastes were determined via XRD, glass transition temperature, one of the thermal features of the composites that is found via DSC and, lastly, the thermal conductivity and specific heat capacity are determined via a heat flow meter. The effect of organic waste amounts and their chemical and physical features on composites’ mechanical and thermal properties are discussed in this study. The results of the study show that nettle stalk-reinforced composites have a low density and more advantageous features than the other composites tested in terms of their thermal conductivities.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Abbreviations

ASTM:

American Society for Testing and Materials

EN:

European Standards

DSC:

Differential scanning calorimetry

MPa:

Megapascal

XRD:

X-ray diffraction

CrI:

Crystallinity index

Q :

Heat flow

C p :

Specific heat capacity

References

  • Abdou AA, Budaiwi IM, Al-Homoud M (2005) Comparison of thermal conductivity measurement of building insulation materials under various operating temperatures. J Build Phys 29:171–184

    Article  Google Scholar 

  • Agarwal R, Saxena NS, Sharma KB, Thomas S, Pothan LA (2003) Thermal conduction and diffusion through polyester composites. Indian J Pure Appl Phys 41:448–452

    Google Scholar 

  • Aslı M, Brachelet F, Chauchoıs A, Antczak E, Defer D (2019) Numerical and experimental investigation of heat and mass transfer with in bio based material. Therm Sci 23(1):23–31. https://doi.org/10.2298/TSCI161019175A

    Article  Google Scholar 

  • ASTM Standard specification for load bearing concrete masonry units ASTM C90-11b, international (2011)

  • ASTM Standard Test Method for Flexural Strength and Modulus of Elasticity of Chemical-Resistant Mortars, Grouts, Monolithic Surfacings, and Polymer Concretes. (ASTM C580) American Society for Testing and Materials (ASTM), Annual Book of ASTM Standards, 100 Barr Harbor Drive, West Conshohocken, PA. www.astm.org

  • Benítez-Guerreroa M, Pérez-Maquedab LA, Artiagac A, SánchezJiménezb PE, Pascual-Cosp J (2017) Structural and chemical characteristics of sisal fiber and its components: effect of washing and grinding. J Nat Fibers 14(1):26–39

    Article  Google Scholar 

  • Bertoncelj B, Vojisavljević K, Vrabelj M, Barbara Malič B (2015) Thermal properties of polymer-matrix composites reinforced with E-glass fibers. Informacije MIDEM. J Microelectron Electron Compon Mater 45:216–221

    Google Scholar 

  • Bledzki AK, Gassan J (1999) Composites reinforced with cellulose-based fibres. Prog Polym Sci 24:221–274

    Article  Google Scholar 

  • Borysiak S (2013) Influence of cellulose polymorphs on the polypropylene crystallization. J Therm Anal Calorim 113(1):281–289

    Article  Google Scholar 

  • Cerqueiraa EF, BaptistabCARP Mulinari DR (2011) Mechanical behaviour of polypropylene reinforced sugarcane bagasse fibers composites. Procedia Eng 10:2046–2051

    Article  Google Scholar 

  • Devireddy SBR, Biswas S (2016) Physical and thermal properties of unidirectional banana–jute hybrid fiber-reinforced epoxy composites. J Reinf Plast Compos 35(15):1157–1172. https://doi.org/10.1177/0731684416642877

    Article  Google Scholar 

  • Dong C, Davies IJ (2012) Flexural properties of macadamia nutshell particle reinforced polyester Composites. Compos Part B 43:2751–2756

    Article  Google Scholar 

  • Dong Z, Dıng RY, Zheng L, Zhang X, Yu CW (2015) Thermal properties of flax fiber scoured by different methods. Therm Sci 19(3):939–945

    Article  Google Scholar 

  • Donnell OA, Dweib MA, Wool RP (2004) Natural fibre composites with plant oil-based resin. Compos Sci Tecnol 64:1135–1145

    Article  Google Scholar 

  • EN 12089 (2013) Thermal insulating products for building applications—determination of bending behaviour. European Standards

  • EN 826 (2013) Thermal insulating products for building applications—determination of compression behaviour. European Standards

  • Garcia-Garcia D, Quiles-Carrillo L, Montanes N, Fombuena V, Balart R (2018) Manufacturing and characterization of composite fibreboards with Posidonia oceanica wastes with an environmentally-friendly binder from epoxy resin. Materials (Basel) 11(1):35. https://doi.org/10.3390/ma11010035

    Article  Google Scholar 

  • Gu J, Zhang Q, DangJ XieC (2012) Thermal conductivity epoxy resin composites filled with boron Nitride. Polym Adv Technol 23:1025–1028

    Article  Google Scholar 

  • Hancox NL (1981) Fibre composite hybrid materials. Macmillan Publishing Co, New York

    Google Scholar 

  • Hepworth DG, Hobson RN, Bruce DM, Farrent JW (2000) The use of unretted hemp fibre in composite manufacture. Compos Part A 3:1279–1283

    Article  Google Scholar 

  • Hossain MF, Shuvo SN, Islam MA (2014) Effect of types of wood on the thermal conductivities of wood saw dust particle reinforced composites. 10th International conference on mechanical engineering. ICME 2013 Procedia Engineering, vol 90, pp 46–51

  • Hurtado PL, Rouilly A, Vandenbossche V, Raynaud C (2016) A review on the properties of cellulose fibre insulation. Build Environ 96:170–177

    Article  Google Scholar 

  • Jonoobi M, Harun J, Tahir P, Zaini L, SaifluAzry S, Makinejad M (2010) Characteristics of nanofibers extracted from kenaf core. BioResources 5(4):2556–2566

    Google Scholar 

  • Kittel C (2005) Introduction to solid state physics, 8th ed. Uno R, Tsuya N, Niizeki K et al (eds) Maruzen, Tokyo, John Wiley & Sons, New York

  • Korkmaz N, Çakmak E, Dayık M (2016) Dokuma karbon elyaf takviyeli karbon nano tüp-epoksikompozit malzemelerin mekanik ve termal karakterizasyonu. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 20(2):338–353

    Article  Google Scholar 

  • Kumara R, Kumarb K, Sahooc P, Bhowmika S (2014) Study of mechanical properties of wood dust reinforced epoxy composite. 3rd International conference on materials processing and characterisation (ICMPC 2014). Procedia Materials Science, vol 6, pp 551–556

  • Low IM, McGrath M, Lawrence D, Schmidt P, Lane J, Latella BA, Sim KS (2007) Mechanical and fracture properties of cellulose-fibre-reinforced epoxy laminates. Compos Part A 38:963–974

    Article  Google Scholar 

  • Mishra S, Tripathy SS, Misra M, Mohanty AK, Nayak SK (2002) Novel eco-friendly biocomposites: biofibre reinforced biodegradable polyester amide composites—fabrication and properties evaluation. J Reinf Plast Compos 21:55–70

    Google Scholar 

  • Mohanty AK, Misra M, Drzal LT (2001) Surface modifications of natural fibres and performance of the resulting biocomposites: an overview. Compos Interfaces 8:313–343

    Article  Google Scholar 

  • Mohapatra RC, Mıshrab A, Choudhury BB (2017) Determınatıon of thermal conductivity of pine wood dust filled epoxy composites. Therm Sci 21(1A):199–210

    Article  Google Scholar 

  • Mwaikambo LY, Ansell MP (2002) Chemical modification of hemp, sisal, jute, and kapok fibres by Alkalisation. J Appl Polym Sci 84:2222–2234

    Article  Google Scholar 

  • Nan CW, Birringer R, Clarke DR, Gleiter H (1997) Effective thermal conductivity of particulate composites with interfacial thermal resistance. J Appl Phys 81(10):6692–6699

    Article  Google Scholar 

  • Peng Y, Wu S (2010) The structural and thermal characteristics of wheat straw hemicellulose. J Anal Appl Pyrol 88:134–139

    Article  Google Scholar 

  • Poliya (2017). https://www.poliya.com/tr/dokum-tipi

  • Rasat MSM, Wahab R, Sulaiman O, Moktar J, Mohamed A, Tabet TA, Khalid İ (2011) Properties of composite boards from oil palm frond agricultural waste. BioResources 6(4):4389–4403

    Google Scholar 

  • Sawpan MA, Pickering KL, Fernyhough A (2012) Flexural properties of hemp fibre reinforced polylactide and unsaturated polyester composites. Compos A Appl Sci Manuf 43(3):519–526

  • Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29(10):786–794

    Article  Google Scholar 

  • Shibata S, Cao Y, Isao Fukumoto I (2005) Effect of bagasse fiber on the flexural properties of biodegradable composites. Polym Compos 26(5):689–694

    Article  Google Scholar 

  • Stark NM, Berger MJ (1997) Effect of particle size on properties of wood-flour reinforced polypropylene composites. Fourth international conference on woodfiber-plastic composites: May 12–14, the Madison, Wisconsin

  • Tajvidi M, Falk RH, Hermanson JC (2006) Effect of natural fibers on thermal and mechanical properties of natural fiber polypropylene composites studied by dynamic mechanical analysis. J Appl Polym Sci 101:4341–4349

    Article  Google Scholar 

  • Teja MS, Ramana MV, Sriramulu D, Rao CJ (2016) Experimental investigation of mechanical and thermal properties of sisal fibre reinforced composite and effect of SiC filler material. IOP Conf. Series: Materials Science and Engineering, 149, 012095. https://doi.org/10.1088/1757-899x/149/1/012095

  • Teng H (2010) Stiffness properties of particulate composites containing debonded particles. Int J Solids Struct 47:2191–2200

    Article  Google Scholar 

  • Tian M, Qu L, Zhang X (2014) Enhanced mechanical and thermal properties of regenerated cellulose/graphene composite fibers. Carbohydr Polym 111:456–462

    Article  Google Scholar 

  • Tutuş A, Çıçekler M, Özkan HG (2017) Fireproof paper production from Turkish red pine (Pinus brutia Ten.) using fire retardants. Kastamonu Uni., Orman Fakültesi Dergisi. J For Fac 17(2):275–281. https://doi.org/10.17475/kastorman.285252

  • Venkatram B, Kailasanathan C, Seenikannan P, Paramasamy S (2016) Study on the evaluation of mechanical and thermal properties of natural sisal fiber/general polymer composites reinforced with nanoclay, I. J Poly Anal Charact 21(7):647–656

    Article  Google Scholar 

  • Wakili KG, Binder B, Vonbank R (2003) A simple method to determine the specific heat capacity of thermal insulations used in building construction. Energy Build 35:413–415

    Article  Google Scholar 

  • Wypych G (2012) Effect of plasticizers on properties of plasticized materials. In: Wypych G (ed) Handbook of plasticizers, 2nd edn. ChemTec Publishing, Toronto, pp 193–272

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kenan Büyükkaya.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Büyükkaya, K., Güler, B. & Koru, M. Investigation of the Thermal and Mechanical Properties of Organic Waste Reinforced Polyester Composites. Iran J Sci Technol Trans Civ Eng 45, 757–766 (2021). https://doi.org/10.1007/s40996-020-00517-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40996-020-00517-3

Keywords

Navigation