Abstract
For the first time, an interdisciplinary approach has been conceived to address environmental hazards of brine sludge and fly ash waste, from chloral alkali industry by developing non-toxic, geopolymeric (cement-free) materials for sustainable development. The process enables the utilization of two industrial wastes, namely fly ash and brine sludge. The utilization of brine sludge in making geopolymeric (cement-free) paver blocks and bricks and its effect on the engineering properties of these products are discussed. The XRD, IR and SEM studies have also been presented. The compressive strength of geopolymeric mortar made using brine sludge could be achieved up to 20 MPa. These results clearly exhibit that brine sludge can be utilized for making geopolymeric (cement-free) paver blocks and bricks. The geopolymerization of brine sludge converts it into non-toxic material which is confirmed by leachability studies. The utilization of brine sludge in making geopolymeric (cement-free) paver blocks and bricks as construction materials could serve as an attractive approach to solve its disposal issue, thereby saving non-renewable natural resources otherwise required for making paver blocks and bricks.
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References
Abdullah MMA, Hussin K, Bnhussain M, Ismail KN, Ibrahim WMW (2011) Mechanism and chemical reaction of fly ash geopolymer cement—a review. Int J Pure Appl Sci Technol 6:35–44
Arioz E, Arioz O, Koçkar OM (2003) The effect of curing conditions on the properties of geopolymer samples. Int J Chem Eng Appl 4:423. https://doi.org/10.7763/ijcea.2013.v4.339423
Bankowski P (2004) Reduction of metal leaching in brown coal fly ash using geopolymers. J Hazard Mater 114(1–3):59–67
Boonserm K, Sata V, Pimraksa K, Chindaprasirt P (2012) Microstructure and strength of blended FEC-PCC fly ash geopolymeric containing gypsum as an additive. Sci Asia 38:175–181
Cheng TW, Chiu JP (2003) Fire-resistant geopolymer produced by granulated blast furnace slag. Miner Eng 16(3):205–210
Chlor alkali process—Wikipedia, the free encyclopedia. https://en.wikipedia.org/wiki/Chloralkali_process. Accessed on 17 Sep 2014
Chukanov NV (2014) Infrared spectra of mineral species. Springer, Dordrecht
CPCB report on ‘review of environmental standards of caustic soda industry (membrane cell) and preparation of COINDS on caustic soda’, 9 (2013)
Criado M, Palomo A, Fernandez-Jimenez A (2005) Alkali activation of fly ashes. Part 1: effect of curing conditions on the carbonation of the reaction products. Fuel 84:2048. https://doi.org/10.1016/j.fuel.2005.03.030
Davidovits J (1999) Chemistry of geopolymeric systems terminology. In: Geopolymer, vol 99 international conferences, France
Fly ash—lime bricks—specification. IS: 12894-(1999). Bureau of Indian Standards, New Delhi
Deventer JSJ, Lorenzen L (1998) Factors affecting the immobilization of metals in geopolymerized flyash. Mater Trans B 29B:283–291. https://doi.org/10.1007/s11663-998-0032-z
El-Eswed BI et al (2015) Stabilization/solidification of heavy metals in kaolin/zeolite based geopolymers. Int J Miner Process 137:34–42
Galiano YL et al (2011) Stabilization/solidification of a municipal solid waste incineration residue using fly ash-based geopolymers. J Hazard Mater 185:373–381
Garg M, Pundir A (2014a) Investigation of properties of fluoro gypsum-slag composite binders-hydration, strength and microstructure. Cem Concr Compos 45:227–233. https://doi.org/10.1016/j.cemconcomp.2013.10.010
Garg M, Pundir A (2014b) Investigation of properties of fluorogypsum-slag composite binders–hydration, strength and microstructure. Cem Concr Compos 45:227–233. https://doi.org/10.1016/j.cemconcomp.2013.10.010
Glasser FP (1997) Fundamental aspects of cement solidification and stabilization. J Hazard Mater 52(2–3):151–170. https://doi.org/10.1016/S0304-3894(96)01805-5
Hale D, Chaudhary R (2007) Mechanism of geo polymerization and factors influencing its development: a review. J Mater Sci 42:729–746. https://doi.org/10.1007/s10853-006-0401-4
Harja M, Bărbuţă M, Gavrilescu M (2009) Utilization of coal fly ash from power plants II. Geopolymer obtaining. Environ Eng Manag J 8:513
Indian standard methods of test for aggregates for concrete. IS: 2386-1963 (Part 1, 3, 4). Bureau of Indian Standards, New Delhi, India
IS 516 (1959) Method of tests for strength of concrete [CED 2: cement and concrete]
IS (2005) Methods of chemical analysis of hydraulic cement. IS 4032-2005. Bureau of Indian Standards, New Delhi
IS (2006) Precast concrete blocks for paving-specification. IS 15658-2006. Bureau of Indian Standards, New Delhi
IS: 4031–2005 (2005) Methods of physical tests for hydraulic cements. Bureau of Indian Standards, New Delhi
IS: 4139 (1989) Specification for calcium silicate bricks. Bureau of Indian Standards, New Delhi
IS:10500 (2012) Standards for discharge of environmental pollutants in inland surface water. Bureau of Indian Standards, New Delhi, p 2012
Jaarsveld J, Deventer JSJ (1999) The effect of alkali metal activator on the properties of the fly ash based geopolymers. Ind Eng Res 38:3932–3991. https://doi.org/10.1021/ie980804b
Kumar S et al (2004) Synthesis of Mullite aggregates from fly ash: effect of thermo mechanical behavior of low cement castables. Br Ceram Trans 103(4):176–180
Lima AT et al (2012) Assessing fly ash treatment: remediation and stabilization of heavy metals. J Environ Manag 95:110–115
López FJ, Sugita S, Tagaya M, Kobayashi T (2014) Metakaolin-based geopolymers for targeted adsorbents to heavy metal ion separation. J Mater Sci Chem Eng 2:16. https://doi.org/10.4236/msce.2014.27002
Mucsi G, Lakatos J, Molnár Z, Szabó R (2014) The 9th international conference on environmental engineering. eISSN 2029-7092/eISBN 978-609-457-640-9
Palomo A, Grutzeck MW, Bolanco MT (1999) Alkali activated fly ashes—a cement for the future. Cem Concr Res 29(8):1323–1329
Panias D, Giannopoulou IP (2006) Development of inorganic polymeric materials based on fired coal fly ash. Acta Metall Slovaca 12:321
Powder diffraction file, alphabetical index inorganic phases (1984) Published By JCPDS International Centre for Diffraction Data 1601, Park Lane Swarthmore, Pennsylvania 19081 USA
Swanepoel JC, Strydom CA (2002) Utilisation of fly ash in a geopolymeric material. J Appl Geochem 17:1143–1148
Van Jaarsveld JGS, Van Deventer JJ, Lorenzen L (1996) The potential use of geopolymeric materials to immobilize toxic metals: Part 1. Theory and applications. Miner Eng 10(7):659–669
Zheng Lei et al (2011) Immobilization of MSWI fly ash through geopolymerization: effects of water-wash. Waste Manag 31:311–317
Xu JZ et al (2006) Study on the factors of affecting the immobilization of heavy metals in fly ash-based geopolymers. Mater Lett 60(6):820–822
Acknowledgements
Authors are grateful to Director CSIR-AMPRI Bhopal for providing necessary institutional facilities and encouragement. Thanks are also due to Dr. O.P. Modi, Mr. Deepak Kashyap and Mr. Mohd. Shafique, CSIR-AMPRI for analysis of samples on SEM and providing XRD data of samples. Dr Neelesh Jain, SIRT, Bhopal, for providing facilities for IR spectra.
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Verma, S., Amritphale, S.S. & Khan, M.A. Utilization of Brine Sludge and Fly Ash Waste as Complementary Resources, for Making Non-toxic, Geopolymeric (Cement-Free) Materials. Iran J Sci Technol Trans Civ Eng 43 (Suppl 1), 603–614 (2019). https://doi.org/10.1007/s40996-018-0191-3
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DOI: https://doi.org/10.1007/s40996-018-0191-3