Abstract
This paper reports on the functional, economic, and environmental performance of sustainable concrete prepared from the waste materials like ferrochrome ash (FCA) and air-cooled ferrochrome slag (ACFS). FCA and ACFS are metallurgical waste materials from the ferrochrome industry, which contain residual chromium and face disposal problems. The leaching of chromium from FCA is reported to be 26 times more than the regulatory limit, as such banned for landfilling. The sustainable management of these metal residues in concrete making through the combined use of FCA (up to 40%) and ACFS (100%) for part replacement of the cement and total replacement of virgin coarse aggregate was examined. The technical performance of such concrete when examined in terms of compressive strength, modulus of rupture, and sulfate resistance has better performances up to 11% than conventional concrete. Environmental performances when examined through global warming potential (GWP), ozone depletion potential (ODP), abiotic depletion potential (ADP), photochemical ozone creation potential (POCP), eutrophication potential (EP), and acidification potential (AP) have advantages up to 47% when compared to normal concrete. The leaching of hexavalent chromium from such concrete is far below the regulatory limit. The economic performance of such concrete is found 22% cheaper than normal concrete. The microstructure of ferrowaste concrete is found denser than control concrete.
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Mishra J, Nanda B, Patro SK, Das SK, Mustakim SM (2021) Strength and microstructural characterization of ferrochrome ash- and ground granulated blast furnace slag-based geopolymer concrete. J Sustain Metall. https://doi.org/10.1007/s40831-021-00469-6
Acharya PK, Patro SK (2016) Utilization of ferrochrome wastes such as ferrochrome ash and ferrochrome slag in concrete manufacturing. Waste Manage Res 34:764–774
Niemela P, Kauppi M (2007) Production, characteristics and use of ferrochromium slags. The Indian Ferro Alloy Producers Association, Infacon XI, pp 171–179
Moodie E (2016) The benefits of using ferrochrome slag as course aggregate in South Africa. M.Sc. Thesis, Department of Geography and Environmental Management, North-West University
Yılmaz A, Karasahin M (2010) Mechanical properties of ferrochromium slag in granular layers of flexible pavements. Mater Struct 43(3):309–317
Panda CR, Mishra KK, Panda KC, Nayak BD, Nayak BB (2013) Environmental and technical assessment of ferrochrome slag as concrete aggregate material. Constr Build Mater 49:262–271
Scope C, Vogel M, Guenther E (2021) Greener, cheaper, or more sustainable: Reviewing sustainability assessments of maintenance strategies of concrete structures. Sustain Prod Consumption 26:838–858
Sanjuan MA, Andrade C, Mora P, Zarogoza A (2020) Carbon dioxide uptake by cement based materials: a Spanish case study. Appl Sci 10:339. https://doi.org/10.3390/app10010339
Sanjuan MA, Argiz C, Mora P, Zarogoza A (2020) Carbon dioxide uptake in road map 2050 of the Spanish cement industry. Energies 10:3452. https://doi.org/10.3390/en13133452
Menéndez E, Álvaro AM, Hernandez MT, Parra JL (2014) New methodology for assessing the environmental burden of cement mortars with partial replacement of coal bottom ash and fly ash. J Environ Manage 133:275–283
Chatveera B, Lertwattanaruk P (2011) Durability of conventional concrete containing black rice husk ash. J Environ Manage 92(1):59–66
Kunal SR, Rajor A (2012) Use of cement kiln dust in cement concrete and its leachate characteristics. Resour Conserv Recycl 61(10):59–68
Caijun S, Christian M, Ali B (2008) Utilization of copper slag in cement and concrete. Resour Conserv Recycl 52(10):1115–1120
Fairbairn EMR, Americano BB, Cordeiro GC, Paula TP, Silvoso MM (2010) Cement replacement by sugarcane ash: CO2 emission reduction and pollution for carbon credits. J Environ Manag 91(9):1864–1871
Acharya PK, Patro SK (2015) Effect of lime and ferrochrome ash (FA) as partial replacement of cement on strength, ultrasonic pulse velocity and permeability of concrete. Constr Build Mater 94:448–457
Acharya PK, Patro SK (2016) Acid resistance, sulphate resistance and strength properties of concrete containing ferrochrome ash (FA) and lime. Constr Build Mater 120:241–250
Acharya PK, Patro SK (2016) Use of ferrochrome ash and lime dust in concrete preparation. J Clean Prod 131:237–246
Acharya PK, Patro SK (2016) Strength, sorption and abrasion characteristics of concrete using ferrochrome ash (FCA) and lime as partial replacement of cement. Cement Concr Compos 74:16–25
Kumar BC, Yaragal SC, Das BB (2020) Ferrochrome as-its use potential in alkali-activated slag mortars. J Clean Prod 257:120577
Acharya PK, Patro SK, Moharana NC (2016) Effect of lime on mechanical and durability properties of blended cement. J Inst Eng (India) Ser A 97(2):71–79
Al-Jabri K, Shoukry H, Khalil IS, Nasir S, Hassan HF (2018) Reuse of waste ferrochrome slag in the production of mortar with improved thermal and mechanical performance. J Mater Civ Eng 30(8):04018152
Fares AI, Sohel KMA, Al-Jabri K, Ai-Mamun A (2021) Characteristics of ferrochrome slag aggregate and its uses as a green material in concrete—a review. Constr Build Mater 294:123552
Nath SK (2018) Geopolymerization behaviour of ferrochrome slag and fly ash blends. Constr Build Mater 181:487–494
Holappa L, Kekkonen M, Jokilaakso A, Koskinen J (2021) A review of circular economy prospects for stainless steelmaking slags. J Sustain Metall 7:806–817. https://doi.org/10.1007/s40831-021-00392-w
Faleschini F, Brunelli K, Zanini MA, Dabala M, Pellegrino C (2016) Electric arc furnace slag as coarse recycled aggregate for concrete production. J Sustain Metall 2:44–50. https://doi.org/10.1007/s40831-015-0029-1
Kurda R, Silvestre JD, de Brito J (2018) Toxicity and environmental and economic performance of fly ash and recycled aggregates use in concrete: a review. Heliyon 4:e00611. https://doi.org/10.1016/j.heliyon.2018.e00611
Joyce PJ, Bjorklund A (2019) Using life cycle thinking to assess the sustainability benefits of complex valorization pathways for bauxite residue. J Sustain Metall 5:69–84. https://doi.org/10.1007/s40831-019-00209-x
Acharya PK, Patro SK (2018) Bond permeability and acid resistance characteristics of ferrochrome waste concrete. ACI Mater J 115(3):01–10
IS 8112 (2013) 43 grade ordinary Portland cement—specification. Bureau of Indian Standards, New Delhi
Rao DS, Angadi SI, Muduli SD, Nayak BD (2010) Valuable waste. Res Dev Miner Process Engl Ed 51(5):2–6
Dash MK, Patro SK (2018) Performance assessment of ferrochrome slag as partial replacement of fine aggregate in concrete. European J Environ Civil Eng. https://doi.org/10.1080/19648189.2018.1539674
ASTM C 311 (2007) Standard test methods for sampling and testing fly ash or natural pozzolans for use in Portland cement concrete. American Society for Testing and Materials International, West Conshohocken
IS 383 (1970, Reaffirmed 2002) Specifications for coarse and fine aggregates from natural sources for concrete, Bureau of Indian Standards, New Delhi, India.
IS 10500 (2012) Drinking water—specification, Bureau of Indian Standards, New Delhi
IS 516 (1959, Reaffirmed 2004) Indian standard code of practice—methods of test for strength of concrete. Bureau of Indian Standards, New Delhi
IS 5816 (1939, Reaffirmed 2004) Splitting tensile strength of concrete—test method. Bureau of Indian Standards, New Delhi
ASTM C 856 (2004) Practice for petrographic examination of hardened concrete. American Society for Testing and Materials International, West Conshohocken
IS 4031 (Part-II) (1999, Reaffirmed 2004) Method of physical tests for hydraulic cement (determination of fineness by Blaine air permeability method). Bureau of Indian Standards. New Delhi
IS 5514 (1996, Reaffirmed 2004) Apparatus used in Le-Chatelier test specifications, Bureau of Indian Standards, New Delhi, India.
IS 4031 (Part-III) (1988, Reaffirmed 2005) Method of physical tests for hydraulic cement (determination of soundness), Bureau of Indian Standards, New Delhi
Shetty MS (2005) Concrete technology (theory and practice). S. Chand and Company Ltd., New Delhi
Chongiang Du (2005) A review of magnesium oxide in concrete. Concrete International December: 45–50.
Shi HS, Kan LL (2009) Study on the properties of chromium residue-cement matrices (CRCM) and the influence of superplasticizers on chromium (VI)—immobilizing capability of cement matrices. J Hazard Mater 162:913–919
Inoue R, Uchidate M, Kusukawa S, Kado N, Takasaki Y, Ueda S (2021) Control of hydration of free magnesia in steelmaking slag. J Sustain Metall 7:810–830
Alam B, Ashraf M, Shahzada K, Afzal S, Khan K (2012) Sulphate attack in high-performance concrete—a review. Int J Adv Struct Geotech Eng 1:15–18
Schlegel T, Shtiza A (2014) Environmental footprint study of mortar, render and plaster formulations. In: 9th International masonry conference, vol 19(5), pp 370–382
Govt. of Odisha (Works Department) (2017) Schedule of rates. File No. 07556900012013-13827/W.
USEPA 311 (1990) Toxicity characterization leaching procedure (TCLP). US Environmental Protection Act, Washington DC
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Acharya, P.K., Patro, S.K. Evaluation of Functional, Microstructural, Environmental Impact, and Economic Performance of Concrete Utilizing Ferrochrome Ash and Slag. J. Sustain. Metall. 8, 1573–1589 (2022). https://doi.org/10.1007/s40831-022-00587-9
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DOI: https://doi.org/10.1007/s40831-022-00587-9