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Corrosion Inhibition by Indazole Derivatives in 1 M HCl Medium: Experimental and Computational Studies

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Abstract

In this work, we studied the inhibitory effect of two indazole derived compounds named 2-methyl-6-nitro-2Hindazole (6NI2) and 1-ethyl-6-nitro-3a,7a-dihydro-1H-indazole (6NE1) on the corrosion of C38 steel in 1 M HCl solution, using electrochemical impedance spectroscopy, potentiodynamic polarization, and mass loss measurements in different concentrations and temperatures (298 K, 308 K, 318 K, and 328 K). The results showed that the efficiency of our compounds increases with the increase of inhibitor concentration in the solution to reach maximum values of 94.73% and 96.49% at 10–3 M of 6NE1 and 6NI2, respectively. The increase in temperature negatively influences the inhibition efficiency of both compounds down to 79.04% and 80.10% at 10−3 M of 6NE1 and 6NI2, respectively, at 382 K. Thermodynamic and kinetic parameters controlling the adsorption process are calculated and discussed. The polarization curves show that both 6NE1 and 6NI2 act as mixed-type inhibitors. The adsorption mode of 6NE1 and 6NI2 obeys the Langmuir adsorption isotherm. In addition, the Nyquist curves showed that the increase of the inhibitor concentration results in the increase of the charge transfer resistance and the decrease of the double layer capacity. The surface of the C38 steel was investigated using SEM and EDS technics. DFT calculations and Molecular dynamics simulations have approved the correlation of the inhibition efficiency with the experimental study of our inhibitors.

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Data Availability

All data generated or analyzed during this study are included in this published article. Any further datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

The authors are grateful for the research assistance from Electrochemistry and Mustapha Hilali (who passed away before the publication is complete) from the Applied Chemistry-Physics and Environment Team, Faculty of Sciences, Ibn Zohr University, B.P. 8106 City Dakhla, Agadir, Morocco.

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There were no research Grants for this work from any funding agencies.

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Authors and Affiliations

  1. Molecular Modeling and Spectroscopy Research Team, Faculty of Science, Chouaïb Doukkali University, PB 20, 24000, El Jadida, Morocco

    Amine El Maraghi & Habib El Alaoui El Abdallaoui

  2. Analytical Chemistry and Environmental Sciences Unit, Water and Environment Laboratory, Faculty of Sciences, Chouaib Doukkali University, PB 20, 24000, El Jadida, Morocco

    Amine El Maraghi & Hocine Garmes

  3. Extraction, Spectroscopy and Valorization Team, Organic Synthesis, Extraction, and Valorization Laboratory, Sciences Faculty of Ain Chock, Hassan II University, Casablanca, Morocco

    Said Byadi

Authors
  1. Amine El Maraghi
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  2. Habib El Alaoui El Abdallaoui
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  3. Hocine Garmes
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  4. Said Byadi
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Contributions

AE: Electrochemical experiments, wrote the main manuscript, prepared figures, and tables, HE: Supervision and correction of the manuscript. HG: supervision and correction of the manuscript. SB: DFT, and Molecular Dynamic, correction.

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Correspondence to Amine El Maraghi or Said Byadi.

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El Maraghi, A., El Alaoui El Abdallaoui, H., Garmes, H. et al. Corrosion Inhibition by Indazole Derivatives in 1 M HCl Medium: Experimental and Computational Studies. J Bio Tribo Corros 9, 15 (2023). https://doi.org/10.1007/s40735-022-00731-8

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  • DOI: https://doi.org/10.1007/s40735-022-00731-8

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