Abstract
ITO substrates were treated with organic solvent cleaning(OSC), SC1 treatment[V(NH4OH):V(H2O2): V(H2O)=1:1:5], O2 plasma and UV ozone, respectively. Combined investigations of atom force microscopy(AFM), water contact angle measurements, ultraviolet photoemission spectroscopy(UPS) and X-ray photoemission spectroscopy(XPS) demonstrated that UV ozone treatment could give rise to the smoothest surface, the most hydrophilic property and the highest work function(WF) of ITO due to the removal of hydrophobic C―O impurity from the ITO surface and the enrichments of more oxygen on the ITO surface. When PEDOT:PSS film[(poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate)] was deposited on the ITO substrates treated with UV ozone, it showed a lower root-mean- square roughness in AFM images, a higher transmission in UV-Vis transmission spectra and a higher WF in UPS spectra than the PEDOT:PSS films deposited on the ITO substrates treated by other three methods. As a result, the power conversion efficiency of polymer solar cells(PSCs) based on PTB7:PC71BM as an active layer and ITO treated by UV ozone as an anode can reach 8.48% because of the simultaneously improved short circuit current, open circuit voltage and fill factor compared to the PSCs with ITO treated with other three methods.
Similar content being viewed by others
References
Yu G., Gao J., Hummelen J. C., Wudl F., Heeger A. J., Science, 1995, 270(5243), 1789
Thompson B. C., Fréchet J. M. J., Angew. Chem. Int. Ed., 2008, 47(1), 58
Qin R. P., Song G. L., Jiang Y. R., Bo Z. S., Chem. J. Chinese Universities, 2012, 33(4), 828
Li G., Zhu R., Yang Y., Nat. Photon., 2012, 6(3), 153
Liu B., Xu F., Zhang, X. H., Yan D. D., Lu D., Chem. Res. Chinese Universities, 2015, 31(5), 809
Qi Z. Q., Chen X. K., Fan C. Z., Chai W. P., J. Mater. Process. Tech., 2009, 209, 973
Chen Z. X., Li W. C., Li R., Zhang Y. F., Xu G. Q., Cheng H. S., Langmuir, 2013, 29(45), 13836
Qin G., Fan L., Watanabe A., J. Mater. Process. Tech., 2016, 227, 16
Donley C., Dunphy D., Paine D., Carter C., Nebesny K., Lee P., Alloway D., Armstrong N. R., Langmuir, 2002, 18(2), 450
Kugler T., Johansson A., Dalsegg I., Gelius U., Salaneck W. R., Synthetic Met., 1997, 91(1-3), 143
Kim K., Ihm K., Kim B., ACTA Phys. Pol. A, 2015, 127(4), 1176
Kim J. S., Cacialli F., Granström M., Friend R. H., Johansson N., Salaneck W. R., Daik R., Feast W. J., Synthetic Met., 1999, 101(1-3), 111
Kim J. S., Granström M., Friend R. H., Johansson N., Salaneck W. R., Daik R., Feast W. J., Cacialli F., J. Appl. Phys., 1998, 84(12), 6859
Sugiyama K., Ishii H., Ouchi Y., J. Appl. Phys., 2000, 87(1), 295
Praveen T., Shiju K., Predeep P., Microelectron. Eng., 2015, 131, 8
Milliron D. J., Hill I. G., Shen C., Kahn A., Schwartz J., J. Appl. Phys., 2000, 87(1), 572
Lu D., Wu Y., Guo J., Lu G., Wang Y., Shen J., Mater. Sci. Eng. B, 2003, 97(2), 141
So S. K., Choi W. K., Cheng C. H., Leung L. M., Kwong C. F., Appl. Phys. A, 1999, 68(4), 447
Ke J. C., Wang Y. H., Chen K. L., Huang C. J., J. Colloid Interf. Sci., 2016, 465, 311
Kim S. Y., Lee J. L., Kim K. B., Tak Y. H., J. Appl. Phys., 2004, 95(5), 2560
Su Z. S., Wang L. D., Li Y. T., Zhao H. F., Chu B., Li W. L., Nanoscale Res. Lett., 2012, 7(2), 465
Tang F. C., Chang J., Chou W. Y., Cheng H. L., Chen J. S., She H. S., Phys. Status Solidi A, 2012, 209(2), 369
Wagenpfahl A., Rauh D., Binder M., Deibel C., Dyakonov V., Phys. Rev. B, 2010, 82(11), 115306
Ouyang X. H., Peng R. X., Ai L., Zhang X. Y., Ge Z. Y., Nat. Photon., 2015, 9(8), 520
Liu S. J., Zhang K., Lu J. M., Zhang J., Yip H. L., Huang F., Cao Y., J. Am. Chem. Soc., 2013, 135(41), 15326
Duan C. H., Zhang K., Guan X., Zhong C. M., Xie H. M., Huang F., Chen J. W., Peng J. B., Cao Y., Chem. Sci., 2013, 4(3), 1298
Kim J. K., Park I., Kim W. J., Wang D. H., Choi D. G., Choi Y. S., Park J. H., ChemSusChem, 2014, 7(7), 1957
Zhou H., Zhang Y., Mai C. K., Collins S. D., Nguyen T. Q., Bazan G. C., Heeger A. J., Adv. Mater., 2014, 26(5), 780
Wang F., Xu Q., Tan Z. A., Li L., Li S., Hou X., Sun G., Tu X., Hou J., Li Y., J. Mater. Chem. A, 2014, 2(5), 1318
Xu Q., Wang F., Tan Z. A., Li L., Li S., Hou X., Sun G., Tu X., Hou J., Li Y., ACS Appl. Mater. Interfaces, 2013, 5(21), 10658
Dang M. T., Lefebvre J., Wuest J. D., ACS Sustainable Chem. Eng., 2015, 3(12), 3373
Dang M. T., Brunner P. L. M., Wuest J. D., ACS Sustainable Chem. Eng., 2014, 2(12), 2715
Wang F. Z., Sun G., Li Cong, Liu J. Y., Hu S. Q., Zheng H., Tan Z. A., Li Y. F., ACS Appl. Mater. Interfaces, 2014, 6(12), 9458
Author information
Authors and Affiliations
Corresponding author
Additional information
Supported by the National Basic Research Program of China(No.2014CB643505) and the National Natural Science Foundation of China(No.51273077).
Rights and permissions
About this article
Cite this article
Chen, Y., Sun, Y., Yu, C. et al. Anode engineering of highly efficient polymer solar cells using treated ITO. Chem. Res. Chin. Univ. 32, 689–694 (2016). https://doi.org/10.1007/s40242-016-6176-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-016-6176-5