Skip to main content
SpringerLink
Log in

Synthesis, spectroscopic, thermochemical properties of lanthanide complexes with 3,4-Diethoxybenzoic acid and 1,10-phenanthroline

  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

Three novel lanthanide complexes [Ln(3,4-DEOBA)3phen]2[Ln=Eu(1), Tb(2), Dy(3); 3,4-DEOBA=3,4- diethoxybenzoate; phen=1,10-phenanthroline] were synthesized and characterized by elemental analysis, molar conductance, X-ray diffraction and infrared spectrometry. The luminescence spectra of complexes 1 and 2 show the characteristic emission of Eu3+ ion(5 D 0→7 F 0—3) and Tb3+ ion(5 D 4→7 F 6—3). The thermal decomposition mechanism of the title complexes and the analysis of the evolved gases were investigated by thermogravimetry/differential scanning calorimetry-Fourier transform infrared(TG/DSC-FTIR) technology. The results indicate the complexes are thermally stable. In the thermal decomposition of the complexes, phen molecules lost firstly, and then 3,4-DEOBA ligand decomposed into H2O, CO2 and other gaseous molecules. Besides, several gaseous organic fragments were also detected. The heat capacities of complexes 1―3 were measured by DSC in a temperature range of 263.15―340.15 K. Based on the fitted polynomial and thermodynamic equations, the smoothed heat capacities and thermodynamic functions of the three complexes were calculated. The study on biological activity showed that the complexes exhibited good antibacterial activity against Candida albicans, Staphylococcus aureus and Escherichia coli.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bag P., Chakraborty A., Rouzières M., Clérac R., Butcher R. J., Chandrasekhar V., Cryst. Growth. Des., 2014, 14(9), 4583

    Article  CAS  Google Scholar 

  2. Hou X. Y., Wang X., Gao L. J., Fu F., Wang J. J., Cao J., Z. Anorg. Allg. Chem., 2014, 640(10), 2072

    Article  CAS  Google Scholar 

  3. Zhan C. H., Wang F., Kang Y., Zhang J., Inorg. Chem., 2012, 51(1), 523

    Article  CAS  Google Scholar 

  4. Rzaczynska Z., Kula A., Sienkiewicz-Gromiuk J., Szybiak A., J. Therm. Anal. Calorim., 2010, 103(1), 275

    Article  Google Scholar 

  5. You L. X., Li Z. G., Ding F., Wang S. J., Ren B. Y., Sun Y. G., Inorg. Chem. Commun., 2014, 46, 340

    Article  CAS  Google Scholar 

  6. Ma X., Li X., Cha Y. E., Jin L. P., Cryst. Growth Des., 2012, 12(11), 5227

    Article  CAS  Google Scholar 

  7. Zhang S., Yang Y., Xia Z. Q., Liu X. Y., Yang Q., Wei Q., Xie G., Chen S. P., Gao S. L., Inorg. Chem., 2014, 53(20), 10952

    Article  CAS  Google Scholar 

  8. Refat M. S., Al-Maydama H. M., Al-Azab F. M., Amin R. R., Jamil Y. M., Spectrochim. Acta A, 2014, 128, 427

    Article  CAS  Google Scholar 

  9. Kalyani N. T., Atram R. G., Dhoble S. J., Luminescence, 2014, 29(6), 674

    Article  CAS  Google Scholar 

  10. Tang S. F., Lorbeer C., Wang X., Ghosh P., Mudring A. V., Inorg. Chem., 2014, 53(17), 9027

    Article  CAS  Google Scholar 

  11. Sheng K., Li H. T., Jin Z., Li Y., J. Mater. Sci-Mater. El., 2014, 25(10), 4562

    Article  CAS  Google Scholar 

  12. Stanley J. M., Chan C. K., Yang X., Jones R. A., Holliday B. J., Polyhedron, 2010, 29(12), 2511

    Article  CAS  Google Scholar 

  13. Marques L. F., Cantaruti A. A. B., Correa C. C., Lahoud M. G., da Silva R. R., Ribeiro S. J. L., Machado F. C., J. Photoch. Photobio. A, 2013, 252, 69

    Article  CAS  Google Scholar 

  14. Marques L. F., dos Santos M. V., Ribeiro S. J. L., Castellano E. E., Machado F. C., Polyhedron, 2012, 38(1), 149

    Article  CAS  Google Scholar 

  15. Zhou J. M., Shi W., Xu N., Cheng P., Inorg. Chem., 2013, 52(14), 8082

    Article  CAS  Google Scholar 

  16. Hu M., Wang Q. L., Xu G. F., Deng G. R., Yang G. M., Yu M., Zhang Y. H., Inorg. Chim. Acta, 2007, 360(5), 1684

    Article  CAS  Google Scholar 

  17. Melnikov P., Arkhangelsky I. V., Nascimento V. A., Silva A. F., Zanoni Consolo L. Z., J. Therm. Anal. Calorim., 2014, 118(3), 1537

    Article  CAS  Google Scholar 

  18. Ni Y., Tao J., Jin J., Lu C., Xu Z., Xu F., Chen J., Kang Z., J. Alloy Compd., 2014, 612, 349

    Article  CAS  Google Scholar 

  19. Colman T. A. D., Gomes D. J. C., Caires F. J., Filho O. T., da Silva R. D. C., Ionashiro M., Thermochim. Acta, 2014, 591, 111

    Article  CAS  Google Scholar 

  20. Liu J., Ren N., Zhang J., Zhang C., Song H., Sci. China Chem., 2014, 57(11), 1520

    Article  CAS  Google Scholar 

  21. He Q. Z., Yang J., Min H., Li H. X., Mater. Lett., 2006, 60(3), 317

    Article  CAS  Google Scholar 

  22. Essawy A. A., Afifi M. A., Moustafa H., El-Medani S. M., Spectrochim. Acta A, 2014, 131, 388

    Article  CAS  Google Scholar 

  23. Refat M. S., Al-Azab F. M., Al-Maydama H. M. A., Amin R. R., Jamil Y. M. S., J. Mol. Struc., 2014, 1059, 208

    Article  CAS  Google Scholar 

  24. Geary W. J., Coordin. Chem. Rev., 1971, 7(1), 81

    Article  CAS  Google Scholar 

  25. Wang J. F., Meng F. T., Xu S. L., Liu X., Zhang J. J., Thermochim. Acta, 2011, 521(1/2), 2

    Article  CAS  Google Scholar 

  26. Feng R., Jiang F. L., Wu M. Y., Chen L., Yan C. F., Hong M. C., Cryst. Growth Des., 2010, 10(5), 2306

    Article  CAS  Google Scholar 

  27. Gou R., Wang Y., Yang R., Lan Y., Chem. Res. Chinese Universities, 2014, 30(2), 190

    Article  CAS  Google Scholar 

  28. Shi J. Y., Li J., Duan Y., Hu L., Yang X., Wang Z. Y., Liu Y. W., Wang C. X., J. Therm. Anal. Calorim., 2008, 93(2), 403

    Article  Google Scholar 

  29. Qi X. X., Ren N., Xu S. L., Zhang J. J., Zong G. C., Gao J., Geng L. N., Wang S. P., Shi S. K., RSC Adv., 2015, 5, 1926

    Google Scholar 

  30. Tang K., Liu H. M., Ren N., Zhang J. J., Wu K. Z., J. Chem. Thermodyn., 2012, 47, 428

    Article  CAS  Google Scholar 

  31. Zhang L. J., Di Y. Y., Dou J. M., Phase Transit., 2012, 85(9), 809

    Article  CAS  Google Scholar 

  32. Gao Z. F., Di M. Z., Di Y. Y., Chem. J. Chinese Universities, 2013, 34(5), 1208

    Google Scholar 

  33. Nadia E. A. El-Gamel Zayed M. A., Spectrochim. Acta A, 2011, 82(1), 414

    Article  Google Scholar 

  34. Zhao Y. F., Chu H. B., Bai F., Gao D. Q., Zhang H. X., Zhou Y. S., Wei X. Y., Shan M. N., Li H. Y., Zhao Y. L., J. Organomet. Chem., 2012, 716, 167

    Article  CAS  Google Scholar 

  35. Lekha L., Raja K. K., Rajagopal G., Easwaramoorthy D., J. Mol. Struc., 2014, 1056/1057, 307

    Article  Google Scholar 

  36. Chandra S., Agrawal S., Spectrochim. Acta A, 2014, 124, 564

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Testing and Analysis Center, Hebei Normal University, Shijiazhuang, 050024, P. R. China

    Xiaoxia Qi & Jianjun Zhang

  2. College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050024, P. R. China

    Xiaoxia Qi & Jianjun Zhang

  3. College of Chemical Engineering & Material, Handan College, Handan, 056005, P. R. China

    Ning Ren & Dahai Zhang

Authors
  1. Xiaoxia Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ning Ren
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dahai Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jianjun Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Ning Ren or Jianjun Zhang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21073053, 21473049) and the Natural Science Foundation of Hebei Province, China(No.B2012205022).

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Qi, X., Ren, N., Zhang, D. et al. Synthesis, spectroscopic, thermochemical properties of lanthanide complexes with 3,4-Diethoxybenzoic acid and 1,10-phenanthroline. Chem. Res. Chin. Univ. 31, 1039–1045 (2015). https://doi.org/10.1007/s40242-015-5052-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-015-5052-z

Keywords

Search

Navigation