Skip to main content
Log in

Preternatural Hexagonal High-Entropy Alloys: A Review

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Recently, various topics on high-entropy alloys have been reported and great amounts of excellent properties have been investigated, including high strength, great corrosion resistance, great thermal stability, good fatigue and fracture properties, etc. Among all these research activities, high-entropy alloys tend to form face-centered-cubic (FCC) or body-centered-cubic (BCC) solid solutions due to their high-entropy stabilization effect, while the hexagonal structures are rarely reported. Up to now, the reported hexagonal high-entropy alloys are mainly composed of rare-earth elements and transitional elements. Their phase transformation and magnetic properties have also aroused wide concern. This study summarizes the above results and provides the forecast to the future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6, 299 (2004)

    CAS  Google Scholar 

  2. S.F. Zhao, Y. Shao, X. Liu, N. Chen, H.Y. Ding, K.F. Yao, Mater. Des. 87, 625 (2015)

    CAS  Google Scholar 

  3. H.Y. Ding, Y. Shao, P. Gong, J.F. Li, K.F. Yao, Mater. Lett. 125, 151 (2014)

    CAS  Google Scholar 

  4. M.A. Hemphill, T. Yuan, G.Y. Wang, J.W. Yeh, C.W. Tsai, A. Chuang, P.K. Liaw, Acta Mater. 60, 5723 (2012)

    CAS  Google Scholar 

  5. S. Jiang, H. Wang, Y. Wu, X. Liu, H. Chen, M. Yao, B. Gault, D. Ponge, D. Raabe, A. Hirata, M. Chen, Y. Wang, Z. Lu, Nature 544, 460 (2017)

    CAS  Google Scholar 

  6. I. Basu, V. Ocelik, J.T.M. De Hosson, Acta Mater. 150, 104 (2018)

    CAS  Google Scholar 

  7. D. Li, C. Li, T. Feng, Y. Zhang, G. Sha, J.J. Lewandowski, P.K. Liaw, Y. Zhang, Acta Mater. 123, 285 (2017)

    CAS  Google Scholar 

  8. J. Liu, X. Guo, Q. Lin, Z. He, X. An, L. Li, P.K. Liaw, X. Liao, L. Yu, J. Lin, L. Xie, J. Ren, Y. Zhang, Sci. China Mater. 62, 853 (2019)

    CAS  Google Scholar 

  9. Z. Zhang, M. Mao, J. Wang, B. Gludovatz, Z. Zhang, S.X. Mao, E.P. George, Q. Yu, R.O. Ritchie, Nat. Commun. 6, 10143 (2015)

    CAS  Google Scholar 

  10. Y. Zhang, S.G. Ma, J.W. Qiao, Metall. Mater. Trans. A 43, 2625 (2011)

    Google Scholar 

  11. O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P.K. Liaw, Intermetallics 18, 1758 (2010)

    CAS  Google Scholar 

  12. O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle, Intermetallics 19, 698 (2011)

    CAS  Google Scholar 

  13. W. Zhang, P. Liaw, Y. Zhang, Entropy 20, 951 (2018)

    CAS  Google Scholar 

  14. O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle, C.F. Woodward, J. Alloys Compd. 509, 6043 (2011)

    CAS  Google Scholar 

  15. Y.L. Chen, C.W. Tsai, C.C. Juan, M.H. Chuang, J.W. Yeh, T.S. Chin, S.K. Chen, J. Alloys Compd. 506, 210 (2010)

    CAS  Google Scholar 

  16. M. Gao, D. Alman, Entropy 15, 4504 (2013)

    CAS  Google Scholar 

  17. A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, W. Zhang, JOM 66, 1984 (2014)

    CAS  Google Scholar 

  18. M. Feuerbacher, M. Heidelmann, C. Thomas, Mater. Res. Lett. 3, 1 (2014)

    Google Scholar 

  19. Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen, P.K. Liaw, Adv. Eng Mater. 10, 534 (2008)

    CAS  Google Scholar 

  20. Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Prog. Mater. Sci. 61, 1 (2014)

    Google Scholar 

  21. A. Takeuchi, A. Inoue, Mater. Trans. 46, 2817 (2005)

    CAS  Google Scholar 

  22. X. Yang, Y. Zhang, Mater. Chem. Phys. 132, 233 (2012)

    CAS  Google Scholar 

  23. S. Guo, C. Ng, J. Lu, C.T. Liu, J. Appl. Phys. 109, 103505 (2011)

    Google Scholar 

  24. Y.F. Ye, Q. Wang, J. Lu, C.T. Liu, Y. Yang, Mater. Today 19, 349 (2016)

    CAS  Google Scholar 

  25. Y.F. Ye, Q. Wang, J. Lu, C.T. Liu, Y. Yang, Scr. Mater. 104, 53 (2015)

    CAS  Google Scholar 

  26. Y.F. Ye, Q. Wang, Y.L. Zhao, Q.F. He, J. Lu, Y. Yang, J. Alloys Compd. 681, 167 (2016)

    CAS  Google Scholar 

  27. Y.F. Ye, C.T. Liu, Y. Yang, Acta Mater. 94, 152 (2015)

    CAS  Google Scholar 

  28. Y.F. Ye, X.D. Liu, S. Wang, C.T. Liu, Y. Yang, Intermetallics 78, 30 (2016)

    CAS  Google Scholar 

  29. M.C. Gao, B. Zhang, S.M. Guo, J.W. Qiao, J.A. Hawk, Metall. Mater. Trans. A 47, 3322 (2015)

    Google Scholar 

  30. J. Lužnik, P. Koželj, S. Vrtnik, A. Jelen, Z. Jagličić, A. Meden, M. Feuerbacher, J. Dolinšek, Phys. Rev. B 92, 224201 (2015)

    Google Scholar 

  31. Y.J. Zhao, J.W. Qiao, S.G. Ma, M.C. Gao, H.J. Yang, M.W. Chen, Y. Zhang, Mater. Des. 96, 10 (2016)

    CAS  Google Scholar 

  32. K.V. Yusenko, S. Riva, P.A. Carvalho, M.V. Yusenko, S. Arnaboldi, A.S. Sukhikh, M. Hanfland, S.A. Gromilov, Scr. Mater. 138, 22 (2017)

    CAS  Google Scholar 

  33. A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, Intermetallics 69, 103 (2016)

    CAS  Google Scholar 

  34. F. Zhang, Y. Wu, H. Lou, Z. Zeng, V.B. Prakapenka, E. Greenberg, Y. Ren, J. Yan, J.S. Okasinski, X. Liu, Y. Liu, Q. Zeng, Z. Lu, Nat. Commun. 8, 15687 (2017)

    CAS  Google Scholar 

  35. C.L. Tracy, S. Park, D.R. Rittman, S.J. Zinkle, H. Bei, M. Lang, R.C. Ewing, W.L. Mao, Nat. Commun. 8, 15634 (2017)

    CAS  Google Scholar 

  36. J. Moon, Y. Qi, E. Tabachnikova, Y. Estrin, W.M. Choi, S.H. Joo, B.J. Lee, A. Podolskiy, M. Tikhonovsky, H.S. Kim, Mater. Lett. 202, 86 (2017)

    CAS  Google Scholar 

  37. K.M. Youssef, A.J. Zaddach, C. Niu, D.L. Irving, C.C. Koch, Mater. Res. Lett. 3, 95 (2014)

    Google Scholar 

  38. Z. Li, C.C. Tasan, K.G. Pradeep, D. Raabe, Acta Mater. 131, 323 (2017)

    CAS  Google Scholar 

  39. C.H. Tsau, Y.H. Chang, Entropy 15, 5012 (2013)

    CAS  Google Scholar 

  40. C.H. Tsau, Mater. Sci. Eng. A 501, 81 (2009)

    Google Scholar 

  41. T.T. Shun, C.H. Hung, C.F. Lee, J. Alloys Compd. 495, 55 (2010)

    CAS  Google Scholar 

  42. T.T. Shun, C.H. Hung, C.F. Lee, J. Alloys Compd. 493, 105 (2010)

    CAS  Google Scholar 

  43. J.W. Qiao, M.L. Bao, Y.J. Zhao, H.J. Yang, Y.C. Wu, Y. Zhang, J.A. Hawk, M.C. Gao, J. Appl. Phys. 124, 195101 (2018)

    Google Scholar 

  44. T. Zuo, M.C. Gao, L. Ouyang, X. Yang, Y. Cheng, R. Feng, S. Chen, P.K. Liaw, J.A. Hawk, Y. Zhang, Acta Mater. 130, 10 (2017)

    CAS  Google Scholar 

  45. T. Zuo, M. Zhang, P.K. Liaw, Y. Zhang, Intermetallics 100, 1 (2018)

    CAS  Google Scholar 

  46. R. Li, H. Hao, Y. Zhao, Y. Zhang, Metals 7, 76 (2017)

    Google Scholar 

  47. Y. Li, W. Zhang, T. Qi, J. Alloys Compd. 693, 25 (2017)

    CAS  Google Scholar 

  48. Y. Zhang, M. Zhang, D. Li, T. Zuo, K. Zhou, M. Gao, B. Sun, T. Shen, Metals 9, 382 (2019)

    CAS  Google Scholar 

  49. Y. Yuan, Y. Wu, X. Tong, H. Zhang, H. Wang, X.J. Liu, L. Ma, H.L. Suo, Z.P. Lu, Acta Mater. 125, 481 (2017)

    CAS  Google Scholar 

  50. S.M. Na, P.K. Lambert, H. Kim, J. Paglione, N.J. Jones, AIP Adv. 9, 035010 (2019)

    Google Scholar 

  51. K. Sarlar, A. Tekgül, I. Kucuk, Curr. Appl. Phys. 20, 18 (2020)

    Google Scholar 

  52. K. Wu, C. Liu, Q. Li, J. Huo, M. Li, C. Chang, Y. Sun, J. Magn. Magn. Mater. 489, 165404 (2019)

    CAS  Google Scholar 

  53. W. Sheng, J.Q. Wang, G. Wang, J. Huo, X. Wang, R.W. Li, Intermetallics 96, 79 (2018)

    CAS  Google Scholar 

  54. J. Huo, L. Huo, H. Men, X. Wang, A. Inoue, J. Wang, C. Chang, R.W. Li, Intermetallics 58, 31 (2015)

    CAS  Google Scholar 

  55. L. Xue, L. Shao, Q. Luo, B. Shen, J. Alloy. Compd. 790, 633 (2019)

    CAS  Google Scholar 

  56. A. Takeuchi, T. Wada, H. Kato, Mater. Trans. 60, 1666 (2019)

    CAS  Google Scholar 

  57. A. Takeuchi, T. Wada, H. Kato, Mater. Trans. 60, 2267 (2019)

    CAS  Google Scholar 

  58. Y.D. Wu, Y.H. Cai, T. Wang, J.J. Si, J. Zhu, Y.D. Wang, X.D. Hui, Mater. Lett. 130, 277 (2014)

    CAS  Google Scholar 

  59. H.W. Yao, J.W. Qiao, J.A. Hawk, H.F. Zhou, M.W. Chen, M.C. Gao, J. Alloy. Compd. 696, 1139 (2017)

    CAS  Google Scholar 

  60. M. Yoo, S. Agnew, J. Morris, K. Ho, Mater. Sci. Eng. A 319, 87 (2001)

    Google Scholar 

  61. Z. Wu, R. Ahmad, B. Yin, S. Sandlöbes, W. Curtin, Science 359, 447 (2018)

    CAS  Google Scholar 

  62. X.N. Mu, H.N. Cai, H.M. Zhang, Q.B. Fan, Z.H. Zhang, Y. Wu, Y.X. Ge, D.D. Wang, Mater. Des. 140, 431 (2018)

    CAS  Google Scholar 

  63. S. Agnew, M. Yoo, C. Tome, Acta Mater. 49, 4277 (2001)

    CAS  Google Scholar 

  64. J.S. Park, Y.W. Chang, Adv. Mater. Res. 26, 95 (2007)

    Google Scholar 

  65. H.R. Ogden, D.J. Maykuth, W.L. Finlay, R.I. Jaffee, JOM 3, 1150 (1951)

    Google Scholar 

  66. Y. Bu, Z. Li, J. Liu, H. Wang, D. Raabe, W. Yang, Phys. Rev. Lett. 122, 075502 (2019)

    CAS  Google Scholar 

  67. L. Rogal, P. Bobrowski, F. Kormann, S. Divinski, F. Stein, B. Grabowski, Sci. Rep. 7, 2209 (2017)

    Google Scholar 

  68. S. Vrtnik, J. Lužnik, P. Koželj, A. Jelen, J. Luzar, Z. Jagličić, A. Meden, M. Feuerbacher, J. Dolinšek, J. Alloy. Compd. 742, 877 (2018)

    CAS  Google Scholar 

  69. Y. Ikeda, B. Grabowski, F. Koermann, Mater. Charact. 147, 464 (2019)

    CAS  Google Scholar 

  70. F.X. Zhang, S. Zhao, K. Jin, H. Xue, G. Velisa, H. Bei, R. Huang, J.Y.P. Ko, D.C. Pagan, J.C. Neuefeind, W.J. Weber, Y. Zhang, Phys. Rev. Lett. 118, 205501 (2017)

    CAS  Google Scholar 

  71. F. Tian, H. Zhao, Y. Wang, N. Chen, Scr. Mater. 166, 164 (2019)

    CAS  Google Scholar 

  72. C.W. Chu, W.L. McMillan, H.L. Luo, Phys. Rev. B 3, 3757 (1971)

    Google Scholar 

Download references

Acknowledgements

Yong Zhang would like to thank the financial support from the National Natural Science Foundation of China (No 51671020) and the Fundamental Research Funds for the Central Universities (No. FRF-MP-19-013).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yong Zhang.

Additional information

Available online at http://link.springer.com/journal/40195.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, RX., Qiao, JW., Liaw, P.K. et al. Preternatural Hexagonal High-Entropy Alloys: A Review. Acta Metall. Sin. (Engl. Lett.) 33, 1033–1045 (2020). https://doi.org/10.1007/s40195-020-01045-9

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-020-01045-9

Keywords

Navigation