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Electrical Characterization of Sodium Cadmium Borate Glasses Doped With TiO2

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Abstract

A glass series sodium cadmium borate glasses doped with titanium has been formed using melt quench technique within the composition 20Na2O-(20−x)CdO–60B2O3–xTiO2 (0 ≤ x ≤ 5 mol%). The composition was prepared to study the effect of dopant (TiO2) on physical, optical and electrical properties of the glass series under study. The results of physical parameter i.e. density and molar volume show some structural changes at higher concentration of TiO2 doping. Some theoretical physical parameters (\({\Lambda }_{th},\) Mcriterion, n, Rm, αm, N and R) were calculated and displayed in Tables 2 and 3. The dc conductivity of the glasses is found temperature dependent and is due to thermally activated weak polaron hopping. The conductivity value ranges in between 2.45 × 10–6 and 3.47 × 10–6 Scm−1 at 523 K temperature that indicates the semiconducting behaviour of these glasses.

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Acknowledgements

Authors are grateful to the Armament Research Board, Defence Research and Development Organisation (DRDO), New Delhi for providing the financial support to carry out the study through Grant-In-Aid scheme of ARMREB, Project No.: ARMREB/MAA/2018/205.

Funding

This work was supported by Armament Research Board, DRDO, New Delhi. Project No. ARMREB/MAA/2018/205. Dr. Sonam Raheja is the PI of DRDO funded research project.

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  1. Department of Physics, School of Engineering and Technology, Apeejay Stya University, Sohna – Palwal Road, Gurugram, India

    Sonam Raheja, Ravinder Singh & Moin Uddin

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  1. Sonam Raheja
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Correspondence to Sonam Raheja.

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Raheja, S., Singh, R. & Uddin, M. Electrical Characterization of Sodium Cadmium Borate Glasses Doped With TiO2. J. Inst. Eng. India Ser. D 103, 497–503 (2022). https://doi.org/10.1007/s40033-022-00350-0

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