Abstract
The melt-annealing method was used to make invert glasses of cadmium sodium diborate. Cadmium oxide (CdO) makes up 40% of the glass components. Lead oxide (PbO) has been added to the glass network at the expense of CdO. The structural units of the glass exhibited the BO3, BO4, and B–O–B bridges. The Pb and Cd atoms modify the B–O–B linkage by replacing one of the boron atoms. The N4 ratio of the glass decreased from 0.712 to 0.393 when the PbO content increased from 0 to 40 mol%. The absorption edges of the glasses were shifted to higher photon wavelengths, from 366 nm to 404 nm, as the PbO ratio increased. The optical band gap, dispersion parameters, and Urbach energy were determined and discussed. The non-linear optical properties were deduced from the static refractive index, which rose from 54.188 × 10− 12 to 121.314 × 10− 12 esu, as the PbO content increased. Other physical parameters such as density, molar volume, ion concentrations and separation, molar refraction, and polarizability were explained to conclude the behavior and nature of the prepared glass by the term of metallization criterion (M).
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References
AbuShanab, W.S., Moustafa, E.B., Hammad, A.H., Ramadan, R.M., Wassel, A.R.: Enhancement the structural, optical and nonlinear optical properties of cadmium phosphate glasses by nickel ions. J. Mater. Sci. Mater. Electron. 30, 18058–18064 (2019). https://doi.org/10.1007/s10854-019-02158-3
Ahmed, E.M., Gaml, E.A.: Effect of Pb/B ion replacement in B2O3.PbO.Fe2O3.Na2O glasses: optical, magnetic, and fluorescence properties. Opt. Mater. (Amst). 116, 111075 (2021). https://doi.org/10.1016/J.OPTMAT.2021.111075
Askarinejad, A., Morsali, A.: Syntheses and characterization of CdCO3 and CdO nanoparticles by using a sonochemical method. Mater. Lett. 62, 478–482 (2008). https://doi.org/10.1016/J.MATLET.2007.05.082
Bhemarajam, J., Varkolu, M., Syam Prasad, P., Prasad, M.: Effect of Yb3 + ions on spectroscopic and optical properties of Bi2O3–B2O3–Li2O–PbO glass system. Results Opt. 14, 100582 (2024). https://doi.org/10.1016/J.RIO.2023.100582
Chandra Shekhar Reddy, M., Prabhakar Reddy, A., Krishnamurthy Goud, K., Appa Rao, B.: Physical and optical properties of PbO-Sb2O3-B2O3 glasses doped with Gd2O3. Mater. Today Proc. 3, 3970–3975 (2016). https://doi.org/10.1016/J.MATPR.2016.11.058
Davis, E.A., Mott, N.F.: Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors. Phil. Mag. 22, 0903–0922 (1970). https://doi.org/10.1080/14786437008221061
Dimitrov, V., Komatsu, T.: Electronic polarizability, optical basicity and non-linear optical properties of oxide glasses. J. Non Cryst. Solids. 249, 160–179 (1999). https://doi.org/10.1016/S0022-3093(99)00317-8
Dimitrov, V., Komatsu, T.: An interpretation of optical properties of oxides and oxide glasses in terms of the electronic ion polarizability and average single bond strength (review). J. Univ. Chem. Technol. Metall. 45, 219–250 (2010)
Dimitrov, V., Sakka, S.: Linear and nonlinear optical properties of simple oxides. II. J. Appl. Phys. 79, 1741–1745 (1996). https://doi.org/10.1063/1.360963
Doweidar, H., Megahed, A., Gohar, I.A.: Mixed ionic-electronic conduction in sodium borate glasses with low V2O5 content. J. Phys. D Appl. Phys. 19, 1939–1946 (1986). https://doi.org/10.1088/0022-3727/19/10/018
El Batal, F.H., El Kheshen, A.A., Azooz, M.A., Abo-Naf, S.M.: Gamma ray interaction with lithium diborate glasses containing transition metals ions. Opt. Mater. (Amst). 30, 881–891 (2008). https://doi.org/10.1016/j.optmat.2007.03.010
El Batal, H.A., El Batal, F.H., Azooz, M.A., Marzouk, M.A., El Kheshen, A.A., Ghoneim, N.A., El Din, E., Abdelghany, F.M.: Comparative shielding behavior of binary PbO-B2O3 and Bi2O3-B2O3 glasses with high heavy metal oxide contents towards gamma irradiation revealed by collective optical, FTIR and ESR measurements. J. Non Cryst. Solids. 572, 121090 (2021). https://doi.org/10.1016/J.JNONCRYSOL.2021.121090
El-Batal, H.A., El-Mandouh, Z.S., Zayed, H.A., Marzouk, S.Y., El-Komy, G.M., Hosny, A.: Optical and infrared properties of lithium diborate glasses doped with copper oxide: Effect of gamma irradiation. Indian J. Pure Appl. Phys. 50, (2012)
Elbatal, H.A., Abdelghany, A.M., Ali, I.S.: Optical and FTIR studies of CuO-doped lead borate glasses and effect of gamma irradiation. J. Non Cryst. Solids. 358, 820–825 (2012a). https://doi.org/10.1016/J.JNONCRYSOL.2011.12.069
Elbatal, H.A., Abdelghany, A.M., Elbatal, F.H., Ezzeldin, F.M.: Gamma rays interactions with WO3-doped lead borate glasses. Mater. Chem. Phys. 134, 542–548 (2012b). https://doi.org/10.1016/J.MATCHEMPHYS.2012.03.032
Fox, M.: Optical Proeprties of Solids. Oxford University Press, Oxford (2001)
Hammad, A.H., Marzouk, M.A., ElBatal, H.A.: The effects of Bi2O3 on optical, FTIR and thermal properties of SrO-B2O3 glasses. Silicon. 8 (2016). https://doi.org/10.1007/s12633-015-9283-x
Hammad, A.H., Moustafa, E.B., Wassel, A.R.: Emphasis of some physical and dynamical properties of inverted barium phosphate base glass. J. Mater. Res. Technol. 15, 4813–4825 (2021). https://doi.org/10.1016/J.JMRT.2021.10.113
Hammad, A.H., Abdel-wahab, M.S., Vattamkandathil, S.: An investigation into the morphology and crystallization process of lithium borate glass containing vanadium oxide. J. Mater. Res. Technol. 16, 1713–1731 (2022a). https://doi.org/10.1016/J.JMRT.2021.12.131
Hammad, A.H., Moustafa, E.B., Abdel-wahab, M.S., AbuShanab, W.S., Wassel, A.R.: Investigate the structure, mechanical, and optical properties of a novel cadmium phosphate glass containing vanadium oxide. Optik (Stuttg). 261, 169214 (b). (2022b). https://doi.org/10.1016/J.IJLEO.2022.169214
Heiman, D., Hellwarth, R.W., Hamilton, D.S.: Raman scattering and nonlinear refractive index measurements of optical glasses. J. Non Cryst. Solids. 34, 63–79 (1979). https://doi.org/10.1016/0022-3093(79)90007-3
Julien, C., Massot, M., Balkanski, W., Krol, A., Nazarewicz, W.: Infrared studies of the structure of borate glasses. Mater. Sci. Engineering: B. 3, 307–312 (1989). https://doi.org/10.1016/0921-5107(89)90026-3
Kamitsos, E.I.: Infrared studies of borate glasses. Phys. Chem. Glasses. 44, 79–87 (2003)
Kamitsos, E.I., Patsis, A.P., Karakassides, M.A., Chryssikos, G.D.: Infrared reflectance spectra of lithium borate glasses. J. Non Cryst. Solids. 126, 52–67 (1990). https://doi.org/10.1016/0022-3093(90)91023-K
Kaur, A., Khan, S., Kumar, D., Bhatia, V., Rao, S.M., Kaur, N., Singh, K., Kumar, A., Singh, S.P.: Effect of MnO on structural, optical and thermoluminescence properties of lithium borosilicate glasses. J. Lumin. 219, 116872 (2020). https://doi.org/10.1016/J.JLUMIN.2019.116872
Krogh-Moe, J.: The structure of vitreous and liquid boron oxide. J. Non Cryst. Solids. 1, 269–284 (1969). https://doi.org/10.1016/0022-3093(69)90025-8
Kumar, B.V., Sankarappa, T., Kumar, M.P., Kumar, S.: Electronic transport properties of mixed transition metal ions doped borophosphate glasses. J. Non Cryst. Solids. 355, 229–234 (2009). https://doi.org/10.1016/J.JNONCRYSOL.2008.11.018
Lin, H., Liu, B., Zhou, L., Yang, H., He, J., Zhang, T., Liu, H., Jiang, X., Li, C., Li, S., Liu, L., Zeng, F., Su, Z.: Enhancements of magneto-optical properties of GeO2-PbO-B2O3–SiO2–P2O5 glass doped Tb3 + ion. Mater. Chem. Phys. 282, 125963 (2022). https://doi.org/10.1016/J.MATCHEMPHYS.2022.125963
Lorentz H.A.: Ueber die Beziehung Zwischen Der Fortpflanzungsgeschwindigkeit Des Lichtes Und Der Körperdichte. Ann. Phys. 245, 641–665 (1880). https://doi.org/10.1002/ANDP.18802450406
Lorenz, L.: Ueber die Refractionsconstante. Ann. Phys. 247, 70–103 (1880). https://doi.org/10.1002/ANDP.18802470905
Mandal, A.K., Balaji, S., Sen, R.: Microwave and conventional preparation of zinc borate glass: Eu3 + ion as luminescent probe. J. Alloys Compd. 615, 283–289 (2014). https://doi.org/10.1016/J.JALLCOM.2014.06.206
Marzouk, S.Y., Hammad, A.H., Elsaghier, H.M., Abbas, W., Zidan, N.A.: The correlation between the structural, optical, and electrical properties in mixed alkali fluoroborate glasses containing vanadium ions. J. Non Cryst. Solids. 476, 30–35 (2017). https://doi.org/10.1016/j.jnoncrysol.2017.08.031
Mott, N., Davis, E.: Electronic Processes in Non-Crystalline Materials. Oxford University Press, Oxford (1979)
Novatski, A., Steimacher, A., Medina, A.N., Bento, A.C., Baesso, M.L., Andrade, L.H.C., Lima, S.M., Guyot, Y., Boulon, G.: Relations among nonbridging oxygen, optical properties, optical basicity, and color center formation in CaO-MgO aluminosilicate glasses. J. Appl. Phys. 104, 094910 (2008). https://doi.org/10.1063/1.3010306
Pal Singh, G., Kaur, P., Kaur, S., Singh, D.P.: Role of WO3 in structural and optical properties of WO3–Al2O3–PbO–B2O3 glasses. Phys. B Condens. Matter. 406, 4652–4656 (2011). https://doi.org/10.1016/J.PHYSB.2011.09.052
Prasad, R.N.A., Venkata Siva, B., Neeraja, K., Krishna Mohan, N., Rojas, J.I.: Influence of modifier oxides on spectroscopic features of Nd2O3 doped PbO-Ro2O3–WO3–B2O3 glasses (with Ro2O3 = Sb2O3, Al2O3, and Bi2O3). J. Lumin. 223, 117171 (2020). https://doi.org/10.1016/J.JLUMIN.2020.117171
Rajesh, N., Kannan, J.C., Leonardi, S.G., Neri, G., Krishnakumar, T.: Investigation of CdO nanostructures synthesized by microwave assisted irradiation technique for NO2 gas detection. J. Alloys Compd. 607, 54–60 (2014). https://doi.org/10.1016/J.JALLCOM.2014.04.035
Rao, P.N., Raghavaiah, B., Rao, D.K., Veeraiah, N.: Studies on dielectric properties of LiF-Sb2O3-B2O3:CuO glass system. Mater. Chem. Phys. 91, 381–390 (2005). https://doi.org/10.1016/j.matchemphys.2004.11.044
Shelby, J.E.: Introduction to Glass Science and Technology. The Royal Society of Chemistry, Cambridge, UK (2005)
Shelby, J.E., Baker, L.D.: Alkali fluoroborate glasses. Phys. Chem. Glasses. 39, 23–28 (1998)
Sindhu, S., Sanghi, S., Agarwal, A., Sonam, Seth, V.P., Kishore, N.: The role of V2O5 in the modification of structural, optical and electrical properties of vanadium barium borate glasses. Phys. B Condens. Matter. 365, 65–75 (2005). https://doi.org/10.1016/J.PHYSB.2005.04.037
Singh, K.J., Singh, N., Kaundal, R.S., Singh, K.: Gamma-ray shielding and structural properties of PbO–SiO2 glasses. Nucl. Instrum. Methods Phys. Res. B. 266, 944–948 (2008). https://doi.org/10.1016/J.NIMB.2008.02.004
Singh, G.P., Kaur, S., Kaur, P., Singh, D.P.: Modification in structural and optical properties of ZnO, CeO2 doped Al2O3–PbO–B2O3 glasses. Phys. B Condens. Matter. 407, 1250–1255 (2012). https://doi.org/10.1016/J.PHYSB.2012.01.114
Talib, Z.A., Daud, W.M., Tarmizi, E.Z.M., Sidek, H.A.A., Yunus, W.M.M.: Optical absorption spectrum of Cu2O–CaO–P2O5 glasses. J. Phys. Chem. Solids. 69, 1969–1973 (2008). https://doi.org/10.1016/J.JPCS.2008.02.005
Ticha, H., Tichy, L.: Remark on the correlation between the refractive index and the optical band gap in some crystalline solids. Mater. Chem. Phys. 293, 126949 (2023). https://doi.org/10.1016/J.MATCHEMPHYS.2022.126949
Wang, C.C.: Empirical relation between the Linear and the third-order nonlinear optical susceptibilities. Phys. Rev. B. 2, 2045–2048 (1970). https://doi.org/10.1103/PhysRevB.2.2045
Weber, M.J., Milam, D., Smith, W.L.: Nonlinear refractive index of glasses and crystals. Opt. Eng. 17, 463–469 (1978). https://doi.org/10.1117/12.7972266
Wemple, S.H., DiDomenico, M.: Behavior of the electronic dielectric constant in covalent and ionic materials. Phys. Rev. B. 3, 1338–1351 (1971). https://doi.org/10.1103/PhysRevB.3.1338
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This research work was funded by Institutional Fund Projects under grant no. (IFPIP: 1689-135-1443). The authors gratefully acknowledge technical and financial support provided by the Ministry of Education and King Abdulaziz University, DSR, Jeddah, Saudi Arabia.
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Mohammed M. Damoom (M.M.D): Conceptualization, Visualization, Writing-original draft, Methodology, and resources. Abdulsalam M. Alhawsawi (A.M.A): Data curation, formal analysis, Methodology. Essam Banoqitah (E.B): Data curation, formal analysis, Methodology. Essam B. Moustafa (E.B.M): Visualization, Data curation, formal analysis, and Writing-original draft. O.E. Sallam (O.E.S): Data curation, formal analysis, Methodology and Writing-original draft. Ahmed H. Hammad (A. H. H): Writing-Review, Editing, Visualization, and Supervision.
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Damoom, M.M., Alhawsawi, A.M., Banoqitah, E. et al. Studying the optical and non-linear optical characteristics of lead ions in structured cadmium sodium diborate glass. Opt Quant Electron 56, 976 (2024). https://doi.org/10.1007/s11082-024-06909-3
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DOI: https://doi.org/10.1007/s11082-024-06909-3