Abstract
The present paper describes the basic causes of corrosion of naval/marine structures and the principles of cathodic protection. It also provides a review of available sacrificial anodes and impressed current cathodic protection (ICCP) anodes with their advantages and disadvantages for the protection of marine structures in particular ship’s hulls with emphasis on the advances made during the past several years. The most important advances in the area of cathodic protection of ships are the physical scale modelling and computer modelling for the last one and half decade. The merits and demerits of physical scale modelling and computer scale modelling are discussed in detail. Finally, the importance and need of a software package which can decide the optimum number of anodes and reference electrodes and their optimum position in the underwater portion of different marine structures and various classes of ship’s hull under all operating conditions is emphasised.
Similar content being viewed by others
References
Gurrappa I (2005) Cathodic protection of cooling water systems and selection of appropriate materials. J Mater Process Technol 166:256–267
Gurrappa I, Yashwanth IVS (2010) The significance of aluminium alloys for cathodic protection technology. In: Persson EL (ed) Aluminium alloys: preparation, properties and applications, Nova Science Publishers, New York, ISBN: 978-1-61122-311-8, pp 125–142
Gudze MT, Melchers RE (2008) Operational based corrosion analysis in naval ships. Corros Sci 50:3296–3307
Heyer A, D’Souza F, Leon Morales CF, Ferrari G, Mol JMC, De Wit JHW (2013) Ship ballast tanks a review from microbial corrosion and electrochemical point of view. Ocean Eng 70:188–200
Ashworth V (2010) Principles of cathodic protection. Shreir’s Corros 4:2747–2762
Tupper EC (2013) Introduction to naval architecture, 5th edn. pp 299–341
Hack HP (2010) Galvanic corrosion. Shreir’s Corros 2:828–856
Moan T, Uraga EA (2008) Reliability based assessment of deteriorating ship structures operating in multiple sea loading climates. Reliab Eng Syst Saf 93:433–446
Evitts RW (2012) Handbook of environmental degradation of materials, 2nd edn. pp 359–380
Barbalat M, Caron D, Lanarde L, Meyer M, Fontaine S, Castillon F, Vittonato JPh, Refait Ph (2013) Estimation of residual corrosion rates of steel under cathodic protection in soils via voltammetry. Corros Sci 73:222–229
Refait Ph, Jeannin M, Sabot R, Antony H, Pineau S (2013) Electrochemical formation and transformation of corrosion products on carbon steel under cathodic protection in seawater. Corros Sci 71:32–36
Evitts RW (2005) Handbook of environmental degradation of materials. William Andrews Publishing, New York, pp 229–241
Collazo A, Izquierdo M, Nóvoa XR, Pérez C (2007) Surface treatment of carbon steel substrates to prevent cathodic delamination. Electrochim Acta 52:7513–7518
Gurrappa I, Karnik JA (1994) The effect of tin activated aluminium alloy anodes of the addition of bismuth. Corros Prev Control 41:117–121
Gurrappa I (1993) The surface free energy and anode efficiency of aluminium alloys. Corros Prev Control 40:111–114
Kulkarni AG, Gurrappa I, Karnik JA (1991) Bismuth activated aluminium alloy anodes. Bull Electrochem 7:549–553
Kulkarni AG, Gurrappa I (1993) Effect of magnesium addition on the surface free energy and anode efficiency of indium activated aluminium alloys. Br Corros J 28:67–70
Gurrappa I, Karnik JA (1993) Effect of heat treatment on anode capacity of indium activated aluminium alloys. SAEST 28:118–122
Gurrappa I, Karnik JA (1996) Development of aluminium alloy anodes for cathodic protection of ships. Corros Prev Control 43:77–85
Schrieber CF, Reding JT (1967) Field testing a new aluminium anode: Al–Hg–Zn galvanic anode for seawater applications. Mater Prot 6:33–36
Keir DS, Pryor MJ, Sperry PR (1977) Galvanic corrosion characteristics of aluminium alloyed with group IV elements. J Electrochem Soc 114:777–782
Murai T, Miura C, Tamura Y (1977) On aluminium galvanic anodes. Bull. Bismuth Institute, Third Quarter, pp 17–20
U. S. Patent, 1968, No. 3.368958
Sakano T, Toda K, Hanada M (1966) Tests on the effect of indium for high performance aluminium anodes. Mater Prot 5:45–50
Bessone JB (1986), Association Brasileira de Corrosao (ABRACO) Seminario National de Corrosao (Rio de Janeiro, Brazil ABBRACO) 163
Reboul MC, Gimenez PH, Rameau JJ (1984) A proposed activation mechanism for Al anodes. Corrosion 40:366–371
Breslin CB, Carroll WM (1993) The activation of aluminium by indium ions in chloride, bromide and iodide solutions. Corros Sci 34:327–341
Carroll WM, Breslin CB (1992) Activation of aluminium in halide solutions containing activator ions. Corros Sci 33:1161–1177
Reboul MC, Delatte MC (1980) Activation mechanism for sacrificial Al–Zn–Hg anodes. Mater Perform 19:35–41
Tamada A, Tamura Y (1993) The electrochemical characteristics of aluminium galvanic anodes in an arctic seawater. Corros Sci 34:261–277
Lin JC, Shih HC (1987) Improvement of the current efficiency of an Al–Zn–In anodes by heat treatment. J Electrochem Soc 134:817–823
Sheir LL (1984) Corrosion of metals and alloys. Chap 11.17
Shreir LL (1977) Platinum provides protection for steel structures. Platin Met Rev 22:110–121
Gurrappa I (2001) Smart Approaches in Designing Effective Cathodic Protection Systems. In: Proceedings of all India convention on cathodic protection engineering, Mumbai, India, pp E 1–40
Gurrappa I, Yashwanth IVS, GogiaAK (2012) The selection materials for marine applications. In: Volkov Konstantin (ed) Gas turbines ISBN: 979-953-307-816-7, INTEC Publishers, Chicago, pp 51–70
Gurrappa I, Yashwanth IVS (2013) The role of corrosion and its importance in industries and society. In: Proceedings of fifth ISEC triennial international conference on advances and recent trends in electrochemistry, Hyderabad, pp 137–151
Bryan WT (1970) Use of high silicon chromium iron anodes for deep groundbeds. Mater Perform 9:25–30
Jakobs JA (1981) A comparison of anodes for impressed current systems. Mater Perform 20:17–23
Kokinney YM, Cangi J (1976) Proceedings NACE Conference, Houston, p 84
Kroon DH, Schreiber CF (1984) Proceedings NACE Conference, Houston, p 44
Berkeley KGC (1984) Proceedings NACE Conference, Houston, p 48
Paul NJ, Said SM, Gobaisi DM (1985) A new dimensionally stable anode for cathodic protection for impressed systems. Corros Main 8:109–113
Dreyman EW (1972) Precious metal anodes-state of the art. Mater Prot Perform 11:17–20
Warne MA, Heyfield PCS (1976) Platinised titanium anodes for use in cathodic protection. Mater Perform 15:39–42
NACE Publication 56-1 (1956). Corrosion 12: 47t
Warne MA (1979) Precious metal anodes-options for cathodic protection. Mater Perform 18:32–38
Tatum JF (1979) Platinized anodes in carbonaceous backfills-a new dimension. Mater Perform 18:30–33
Baboian R (1979) New developments in platinum type anodes. Mater Perform 18:9–15
Linder B (1979) Magnetite anodes for impressed current cathodic protection. Mater Perform 18:17–19
Jakobs JA, Hewes FW (1979) Caproco Corporation Prevention Ltd., Edmonton, Report F/4003/79
Jakogs JA, Hewes FW (1984) International congress on metallic corrosion, Toranto, 4: 78
Tudor S, Miller WL, Ticker A, Preiser HS (1958) Electrochemical deterioration of graphite and high silicon iron anodes in sodium chloride electrolytes. Corrosion 14:53–59
Brady GD (1971) Graphite anodes for impressed current cathodic protection: a practical approach. Mater Prot Perform 10:20–22
Babosian R (1977) Performance of Pt anodes in impressed current cathodic protection. Mater Perform 16:20–25
Kumar A, Armstrong MD (1988) Cathodic protection using ceramic coated anodes. Mater Perform 27:19–23
Kessler RJ, Powers RG (1989) Conductive rubber as an impressed anode—cathodic protection of steel-reinforced concrete. Mater Perform 28:24–27
Gurrappa I, Karnik JA (1995) Physical scale modelling for cathodic protection of ships. Corros Prev Control 42:43–47
Gurrappa I (1994) Physical and computer modelling for ship’s impressed current cathodic protection (ICCP) systems. Corros Prev Control 41:40–45
Morgan J (1987) Cathodic protection, 2nd edn. National Association of Corrosion Engineers, Houston
Benedict RL (ed) (1987) Classic papers and reviews on anode resistance fundamentals and applications. National Association Corrosion Engineers, Houston
Hack HP, Guanti RJ (1989) Effect of high flow on calcareous deposits and cathodic protection current density. Mater Perform 28:29–40
Tighe-Ford DJ, McGrath JN, Hodgkiss L (1985) Design improvements for a ship’s impressed current cathodic protection system using dimension and conductivity scaling (DACS). Corros Prev Control 32:89–91
Tighe-Ford DJ, Ramaswamy S (1988) The use of stylised physical scale models for studying the impressed current cathodic protection of ships. Corros Prev Control 35:122–127
McGrath JN, Tighe-Ford DJ, Hodgkiss L (1985) Scale modelling of a ship’s impressed current cathodic protection system. Corros Prev Control 32:36–38
Tighe-Ford DJ, Botten RA, Hughes RD (1990) Study of design criteria for ship impressed current cathodic protection by stylised modelling. Corros Prev Control 38:5–11
Tighe-Ford DJ, McGrath JN, Wareham MP (1998) Evaluation of warship impressed current cathodic protection systems. Trans I Mar E 100:185–191
McGrath JN, Tighe-Ford DJ, Hodgkiss L (1990) Scale modeling of impressed current cathodic protection systems for ships. J Naval Eng 29:314–322
Tighe-Ford DJ, Khambhaita P (1991) Effect of paint damage and under-way conditions upon ship ICCP current demands. Corros Prev Control 38:85–89
Tighe-Ford DJ, Khambhaita P, Walton CP (1993) Effect of propeller material and condition on the impressed current cathodic protection of ships. Corros Prev Control 40:79–83
Thomas ED, Parks AR (1989) CORROSION/89, Paper No: 274, Houston, Texas
Parks AR, Thomas ED, Lucas KE (1991) Physical scale modelling verification with shipboard trials. Mater Perform 30:26–29
Warne MA (1982) Proceedings 1st international conference on cathodic protection theory and practice. Institution of Corrosion Science and Technology, Leighton Buzzard
Gartland PO (1983) Proceedings seminar on offshore Corrosion, norse petroleum forening, Stavanger, Norway, 18–19 Jan 1983
Gurrappa I (2009) Smart designs for ships impressed current cathodic protection systems—a report, pp 1–47
Haroun M, Erbar R, Heidersbach R (1986) Use of computers in corrosion control and monitoring. Mater Perform 25:23–27
Sander KF (1982) Proceedings 1st international conference on cathodic protection theory and practice. Institution of Corrosion Science and Technology, Leighton Buzzard
Doig P, Flewitt PEJ (1979) A finite difference numerical analysis of galvanic corrosion for semi-infinite linear coplanar electrodes. J Electrochem Soc 126:2057–2063
Munn RS (1986) Microcomputer corrosion analysis for structures in inhomogeneous electrolytes. Mater Perform 25:33–42
Strommen R, Rodland A (1981) Computerised techniques applied in design of offshore cathodic protection systems. Mater Perform 20:15–20
Haroun M, Erbar R, Heidersbach R (1988), Corrosion 88, paper no. 98. National Association of Corrosion Engineers, Houston
Forrest AW, Bicicchi RT (1981) Cathodic protection of bronze propellers for copper–nickel–surface ships. Corrosion 37:349–357
Munn RS (1982) A mathematical model for a galvanic anode cathodic protection system. Mater Perform 21:29–35
Munn RS (1983) Corrosion 83, paper no. 212. National Association of Corrosion Engineers, Houston
Kasper RG, April MG (1982) Corrosion 82, paper no. 82. National Association of Corrosion Engineers, Houston
Helle HPE, Beek BHM, Ligtelijn JT (1981) Numerical distribution of potential distributions and current densities in multi-electrode systems. Corrosion 37:522–529
DeCarlo EA (1983) Computer-aided cathodic protection design technique for complex offshore strictures. Mater Perform 22:38–44
Santana Diaz E, Adey R (2005) Optimising the location of anodes in cathodic protection systems to smooth potential distribution. Adv Eng Softw 36:591–598
Wu J, Xing S, Liang C, Lu L, Yan Y (2011) The influence of electrode position and output current on the corrosion related electro-magnetic field of ship. Adv Eng Softw 42:902–909
Abrahamsson R, Kay SM, Stoica P (2007) Estimation of the parameters of a bilinear model with applications to submarine detection and system identification. Digit Signal Process 17:756–773
Montoya R, Aperador W, Bastidas DM (2009) Influence of conductivity on cathodic protection of reinforced alkali-activated slag mortar using the finite element method. Corros Sci 51:2857–2862
Trethewey KR, Roberge PR (1994) Lifetime prediction in engineering systems: the influence of people. Mater Design 15:275–285
Fu JW, Chow JSK (1982) Cathodic protection designs using an integral numerical equation method. Mater Perform 21:9–12
Bardal E, Johnson R, Gartland PO (1984) Prediction of galvanic corrosion rates and distribution by means of calculation and experimental models. Corrosion 40:628–632
Cherry BW, Foo M, Siauw TH (1986) Boundary element analysis method of the potential field association with a corroding electrode. Corrosion 42:654–661
Strommen R, Keim W, Finnegan J, Mehdizadeh P (1987) Advances in offshore cathodic protection modelling using the boundary element method. Mater Perform 26:23–28
Zamani NG, Chaung J, Mand J, Porter F (1987) BEM simulation of cathodic protection systems employed in infinite electrolytes. Int J Numer Methods Eng 24:605–620
Chaung JM, Zamani NG, Hsiung CC (1987) Some computational aspects of BEM simulation of cathodic protection systems. Appl Math Model 11:371–379
Gartland PO, Johnson R (1985) Corrosion 85, Paper No. 319. National Association of Corrosion Engineers, Houston
Zamani NG, Chung JM (1987) Optimal control of current in a cathodic protection system: a numerical investigation. Optim Control Appl Methods 8:339–350
Lacerda LAD, Silva JMD, Lázaris J (2007) Dual boundary element formulation for half-space cathodic protection analysis. Eng Anal Bound Elem 31:559–567
Wrobel LC, Miltiadou P (2004) Genetic algorithms for inverse cathodic protection systems. Eng Anal Bound Elem 28:267–271
Santiago JAF, Telles JCF (1999) A solution technique for cathodic protection with dynamic boundary conditions by the boundary element method. Adv Eng Softw 30:663–671
Aoki S, Amaya K (1997) Optimization of cathodic protection system by BEM. Eng Anal Bound Elem 19:147–153
DeGiorgi VG, Wimmer SA (2005) Gemoetric details and modeling accuracy requirements for shipboard impressed current cathodic protection modeling. Eng Anal Bound Elem 29:15–28
DeGiorgi VG (2002) Evaluation of perfect paint assumptions in modeling of cathodic protection systems. Eng Anal Bound Elem 26:435–445
DeGiorgi VG, Thomas ED, Lucas KE (1998) Scale effects and verification of modelling of ship cathodic protection systems. Eng Anal Bound Elem 22:41–49
Brebbia CA, Walker S (1979) Boundary element techniques in engineering. Newnes-Butterworths, London
Strommen RD, Osvoll H, Keim W (1986) Corrosion 86, Paper No. 297. National Association Corrosion Engineers, Houston
Danson D, Brebbia CA, Adey RA (1982) The BEASY system. Adv Eng Softw 4:68–74
Danson DJ, Warne MA (1983) Corrosion 83, Paper No. 211. National Association of Corrosion Engineers, Houston
Telles JCF, Mansur WJ, Marinho MG (1989) Corrosion 89, Paper No. 276. National Association of Corrosion Engineers, Houston
Chauchot P, Bigourdan B, Lemmoine L (1989) Corrosion 89, Paper No. 401. National Association of Corrosion Engineers, Houston
Martinez S, Stern I (2000) A mathematical model for internal cathodic protection of cylindrical structures by wire anodes. J Appl Electrochem 30:1053–1060
Zamani NG, Porter JF, Mufti AA (1986) A survey of computational efforts in the field of corrosion engineering. Int J Numer Methods Eng 23:1295–1311
Jia JX, Song G, Atrens A, St. John D, Baynham J, Chandler G (2004) Evaluation of the BEASY program using linear and piecewise linear approaches for the boundary conditions. Mater Corros 55:845–852
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gurrappa, I., Yashwanth, I.V.S. & Mounika, I. Cathodic Protection Technology for Protection of Naval Structures Against Corrosion. Proc. Natl. Acad. Sci., India, Sect. A Phys. Sci. 85, 1–18 (2015). https://doi.org/10.1007/s40010-014-0182-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40010-014-0182-0