Abstract
Investigation of recycling and reutilizing capability of industrial wastes is essential to attend the vision of sustainable waste management. One such industrial waste is cupola slag, a by-product of grey cast iron. This slag mainly ends up in dump yards or landfills due to a lack of proper attention. This article aims to analyse available previous literature to understand every possible door for reutilizing cupola slag to attain the goal of sustainable waste management. Primary importance is given to the utilization of cupola slag in the building industry as partial or full substitution of fine and coarse natural aggregates as well as cement for making concrete. The reusability has been analysed by extensive investigations on microstructure, chemical and physical properties of cupola slag starting from its origin. Very few analyses of the utilization of cupola slag can be found in different sectors such as for making glass ceramics, synthesizing zeolite and phosphorus-based fertilizers, making ceramic foams, road construction and use as artificial pozzolan. The extensive analysis not only opened a huge opportunity to ensure reuse of industrial waste, i.e. cupola slag but also utilization can provide some added advantages of being eco-friendly. A sustainable future can be assured by more rigorous study and implementation of methods for the reuse of cupola slag.
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References
Aderibigbe DA, Ojobo AE (1982) Properties of cupola slag as a pozzolana and its effects on partial replacement of cement in a mortar. Conserv Recycl 5(4):203–208. https://doi.org/10.1016/0361-3658(82)90048-0
Afolayan JO, Alabi SA (2013) Investigation on the potentials of cupola furnace slag in concrete. Int J Integr Eng 5(2):59–62
Agarwal G et al (1991) Crystallization behavior of cupola slag glass-ceramics. J Non-Cryst Solids 130(2):187–197. https://doi.org/10.1016/0022-3093(91)90454-E
Agarwal G, Speyer RF (1991) Devitrification hardening of cupola slag glass with CaO and SiO2 additions. J Non-Cryst Solids 135(2–3):95–104. https://doi.org/10.1016/0022-3093(91)90409-Y
Agarwal G, Speyer RF (1992) Devitrifying cupola slag for use in abrasive products. Jom 44(3):32–37. https://doi.org/10.1007/BF03222790
Aitcin P-C (1986) Concrete structure, properties and materials. Can J Civ Eng. https://doi.org/10.1139/l86-075
Akeke G et al (2013) Structural properties of rice husk ash concrete. Int J Adv Eng Sci Appl Math 3(2):8269
Alabi SA, Mahachi J (2020) Behaviour of ground cupola furnace slag blended concrete at elevated temperature. J Mater Eng Struct 7:35–46
Amran YHM et al (2020) Clean production and properties of geopolymer concrete; a review. J Clean Prod. https://doi.org/10.1016/j.jclepro.2019.119679
Anuwattana R et al (2008) Conventional and microwave hydrothermal synthesis of zeolite ZSM-5 from the cupola slag. Microporous Mesoporous Mater 111(1–3):260–266. https://doi.org/10.1016/j.micromeso.2007.07.039
Anuwattana R, Khummongkol P (2009) Conventional hydrothermal synthesis of Na-A zeolite from cupola slag and aluminum sludge. J Hazard Mater 166(1):227–232. https://doi.org/10.1016/j.jhazmat.2008.11.020
Arum C, Mark GO (2014) Partial replacement of Portland cement by granulated cupola slag–sustainable option for concrete of low permeability. Civ Environ Res 6(3):17–26
Balaraman R, Elangoval NS (2018) Behaviour of cuplola slag in concrete as partial replacement with combination of fine and coarse aggregate. Taga J, 1041–1045
Balaraman R, Ligoria SA (2015) Utilization of cupola slag in concrete as fine and coarse aggregate. Int J Civ Eng Technol (IJCIET) 6(8):6–14
Barbara GK, Ann GK (2006) Fly ash characterization by SEM-EDS. Fuel 85(17–18):2537–2544
Baricova D, Pribulova A, Futas P (2018) Recycling possibilities of the slag from cupola furnace. Int Multidiscip Sci GeoConf Surv Geol Mining Ecol Manag, SGEM 18(4.2):137–144. https://doi.org/10.5593/sgem2018/4.2/S18.018
Beckett PHT (1989) The use of extractants in studies on trace metals in soils, sewage sludges, and sludge-treated soils. In: Stewart BA (ed) Advances in soil science, vol 9. Springer, New York. https://doi.org/10.1007/978-1-4612-3532-3_3
Beeley P (2001) Foundry technology. Elsevier Ltd
Bellmann F, Stark J (2009) Activation of blast furnace slag by a new method. Cem Concr Res 39(8):644–650. https://doi.org/10.1016/j.cemconres.2009.05.012
Berns H, Theisen W (2008) ‘Ferrous materials: Steel and cast iron’, Ferrous Materials: steel and cast iron. Springer, Berlin, pp 1–418. https://doi.org/10.1007/978-3-540-71848-2
Bilim C et al (2009) Predicting the compressive strength of ground granulated blast furnace slag concrete using artificial neural network. Adv Eng Softw 40(5):334–340. https://doi.org/10.1016/j.advengsoft.2008.05.005
Cabeza R et al (2011) Effectiveness of recycled P products as P fertilizers, as evaluated in pot experiments. Nutr Cycl Agroecosyst 91(2):173–184. https://doi.org/10.1007/s10705-011-9454-0
Cramer SM, Bakke P (1994) Potential use of cupola slag as road construction material. American Foundrymen’s Society, 113–122
Decroocq D (1984) Catalytic cracking of heavy petroleum fractions. Editions Technip, Paris
Deng A, Hung YT, Wang LK (2016) Management, minimization, and recycling of metal casting wastes. In: Waste treatment in the metal manufacturing, forming, coating, and finishing industries. CRC Press, 151–195
Deo B et al (2013) Control of slag formation, foaming, slopping, and chaos in BOF. Trans Indian Inst Met 66(5–6):543–554. https://doi.org/10.1007/s12666-013-0306-2
Donatello S, Tyrer M, Cheeseman CR (2010) Comparison of test methods to assess pozzolanic activity. Cement Concr Compos 32(2):121–127. https://doi.org/10.1016/j.cemconcomp.2009.10.008
Eggleston HK (1970) The successful utilization of iron and steel slags. In: Second mineral waste utilization symposium. Illinois: IIT Research Institute, Chicago, pp 15–22
Leng F, Feng N, Lu X (2000) An experimental study on the properties of resistance to diffusion of chloride ions of fly ash and blast furnace slag concrete. Cem Concr Res 30(6):989–992. https://doi.org/10.1016/S0008-8846(00)00250-7
Fernández-Jiménez A, Palomo A (2005) Composition and microstructure of alkali activated fly ash binder: effect of the activator. Cem Concr Res 35(10):1984–1992. https://doi.org/10.1016/j.cemconres.2005.03.003
Fredericci C, Zanotto ED, Ziemath EC (2000) Crystallization mechanism and properties of a blast furnace slag glass. J Non-Cryst Solids 273(1–3):64–75. https://doi.org/10.1016/S0022-3093(00)00145-9
Frondistou-Yannas S (1977) Waste concrete as aggregate for new concrete. J Am Concr Inst 74(8):373–376. https://doi.org/10.14359/11019
Ganesan K, Rajagopal K, Thangavel K (2008) Rice husk ash blended cement: assessment of optimal level of replacement for strength and permeability properties of concrete. Constr Build Mater 22(8):1675–1683. https://doi.org/10.1016/j.conbuildmat.2007.06.011
Gartner E, Hirao H (2015) A review of alternative approaches to the reduction of CO2 emissions associated with the manufacture of the binder phase in concrete. Cem Concr Res 78:126–142. https://doi.org/10.1016/j.cemconres.2015.04.012
Goodarzi F (2006) Characteristics and composition of fly ash from Canadian coal-fired power plants. Fuel 85(10–11):1418–1427. https://doi.org/10.1016/j.fuel.2005.11.022
Halicka A, Ogrodnik P, Zegardlo B (2013) Using ceramic sanitary ware waste as concrete aggregate. Constr Build Mater 48:295–305. https://doi.org/10.1016/j.conbuildmat.2013.06.063
Hammel EC, Ighodaro OLR, Okoli OI (2014) Processing and properties of advanced porous ceramics: An application based review. Ceram Int 40(10):15351–15370. https://doi.org/10.1016/j.ceramint.2014.06.095
Hansson CM (1989) Cast iron technology. Mater Sci Eng: A. https://doi.org/10.1016/0921-5093(89)90868-x
Hybská H et al (2017) Ecotoxicity of concretes with granulated slag from gray iron pilot production as filler. Mater 10(5):505. https://doi.org/10.3390/ma10050505
Jaturapitakkul C, Roongreung B (2003) Cementing material from calcium carbide residue-rice husk ash. J Mater Civ Eng 15(5):470–475. https://doi.org/10.1061/(asce)0899-1561(2003)15:5(470)
Kirca Ö (2018) Ancient binding materials, mortars and concrete technology: History and durability aspects. In: Modena C, Lourenço PB, Roca P (Eds) Structural analysis of historical cnstructions, pp 87–95
Kucey RMN (1987) Increased phosphorus uptake by wheat and field beans inoculated with a Phosphorus-Solubilizing Penicillium bilaji strain and with Vesicular-Arbuscular Mycorrhizal fungi. Appl Environ Microbiol 53(12):2699–2703. https://doi.org/10.1128/aem.53.12.2699-2703.1987
Kukier U et al (2003) Composition and element solubility of magnetic and non-magnetic fly ash fractions. Environ Pollut 123(2):255–266. https://doi.org/10.1016/S0269-7491(02)00376-7
Ladomerský J et al (2016) One-year properties of concrete with partial substitution of natural aggregate by cupola foundry slag. J Clean Prod 131:739–746. https://doi.org/10.1016/j.jclepro.2016.04.101
Lara-Sánchez JF et al (2016) Development of ceramic foams using cast iron slag as a raw material. Adv Ceram Sci Eng 5:11. https://doi.org/10.14355/acse.2016.05.002
Li G (2004) Properties of high-volume fly ash concrete incorporating nano-SiO 2. Cem Concr Res 34(6):1043–1049. https://doi.org/10.1016/j.cemconres.2003.11.013
Li G, Zhao X (2003) Properties of concrete incorporating fly ash and ground granulated blast-furnace slag. Cement Concr Compos 25(3):293–299. https://doi.org/10.1016/S0958-9465(02)00058-6
Limbachiya M, Meddah MS, Ouchagour Y (2012) Use of recycled concrete aggregate in fly-ash concrete. Constr Build Mater 27(1):439–449. https://doi.org/10.1016/j.conbuildmat.2011.07.023
Malhotra VM (1986) Superplasticized fly ash concrete for structural applications. Concr Int 8(12):28–31
Malhotra VM, Mehta PK (2002) High-Performance, high-volume fy ash concrete. Concr Int 24(7):30–34
Madandoust R et al (2011) Mechanical properties and durability assessment of rice husk ash concrete. Biosys Eng 110(2):144–152. https://doi.org/10.1016/j.biosystemseng.2011.07.009
Manning MP, Weldon BD (2020) Experimental, analytical, and practical investigations of nonproprietary ultra-high performance concrete developed using local materials.
Medina C et al (2012a) Gas permeability in concrete containing recycled ceramic sanitary ware aggregate. Constr Build Mater 37:597–605. https://doi.org/10.1016/j.conbuildmat.2012.08.023
Medina C, Sánchez De Rojas MI, Frías M (2012b) Reuse of sanitary ceramic wastes as coarse aggregate in eco-efficient concretes. Cement Concr Compos 34(1):48–54. https://doi.org/10.1016/j.cemconcomp.2011.08.015
Mehta PK (2008) High-performance, high-volume fly ash concrete for sustainable development. In: International workshop on sustainable development and concrete technology 31(4), pp 3–14
Mistry VK, Varia DJ (2020) Green concrete by replacing coarse aggregate with cupola slag for environmental protection. Smart Innov, Syst Technol 161:223–237. https://doi.org/10.1007/978-981-32-9578-0_20
Murdock LJ, Brook KM (1979) Concrete materials and practice. Arnold (Edward) Publishers, London, England
Naik TR, Moriconi G (2005) Environmental-friendly durable concrete made with recycled materials for sustainable concrete construction. In: International symposium on sustainable development of cement and concrete
Nataraja MC, Das L (2010) Concrete mix proportioning as per is 10262:2009-comparison with is 10262:1982 and ACI 211.1-91. Indian Concr J 84(9):64–70
Ndlovu S, Simate GS, Matinde E (2017) Waste production and utilization in the metal extraction industry. Waste Prod Util Metal Extr Ind. https://doi.org/10.1201/9781315153896
Neville AM (1995) Properties of concrete, Vol 4. Longman, London.
Okumara H, Ouchi M (1999) Self-compacting concrete development, present use and future. In: 1st international RILEM symposium on self-compacting concrete, pp 3–14
Osborn EF et al (1954) Optimum composition of blast furnace slag as deduced from liquidus data for the quaternary system CaO-MgO-Al2O3-SiO2. Jom 6(1):33–45. https://doi.org/10.1007/bf03397977
Osborne GJ (1999) Durability of Portland blast-furnace slag cement concrete. Cement Concr Compos 21(1):11–21. https://doi.org/10.1016/S0958-9465(98)00032-8
Pal SC, Mukherjee A, Pathak SR (2003) Investigation of hydraulic activity of ground granulated blast furnace slag in concrete. Cem Concr Res 33(9):1481–1486. https://doi.org/10.1016/S0008-8846(03)00062-0
Panda R, Sahoo TK (2021) Effect of replacement of GGBS and fly ash with cement in concrete. Lect Notes Civ Eng 75:811–818. https://doi.org/10.1007/978-981-15-4577-1_68
Pavlenko SI, Malyshkin VI (1999) Fine grained cementless concrete containing slag from foundry. In: Exploiting wastes in concrete, pp 101–108. https://doi.org/10.1680/ewic.28210.0009
Pierce Y, Kanaka SKB, Niteen B (2021) Experimental studies on concrete using the partial replacement of cement by glass powder and fine aggregate as manufactured sand. In: Das BB, Nanukuttan SV, Patnaik AK, Panandikar NS (eds) Recent trends in civil engineering. Lecture notes in civil engineering, vol 105. Springer, Singapore. https://doi.org/10.1007/978-981-15-8293-6_45
Pitarch AM et al (2019) Effect of tiles, bricks and ceramic sanitary-ware recycled aggregates on structural concrete properties. Waste Biomass Valoriz 10(6):1779–1793. https://doi.org/10.1007/s12649-017-0154-0
Pribulova A et al (2019) Cupola Furnace Slag: Its Origin, Properties and Utilization. Int J Metalcast 13(3):627–640. https://doi.org/10.1007/s40962-019-00314-3
Raheem AA, Kareem MA (2017) Chemical composition and physical characteristics of rice husk ash blended cement. Int J Eng Res Afr 32:25–35. https://doi.org/10.4028/www.scientific.net/JERA.32.25
Ramachandran VS, Feldman RF(1996) Concrete science. In: Concrete admixtures handbook. William Andrew Publishing, pp 1-66. https://doi.org/10.1016/B978-081551373-5.50005-2
Ramasamy V (2012) Compressive strength and durability properties of Rice Husk Ash concrete. KSCE J Civ Eng 16(1):93–102. https://doi.org/10.1007/s12205-012-0779-2
Rao A, Jha KN, Misra S (2007) Use of aggregates from recycled construction and demolition waste in concrete. Resour Conserv Recycl 50(1):71–81. https://doi.org/10.1016/j.resconrec.2006.05.010
Rashad AM (2013) A comprehensive overview about the influence of different additives on the properties of alkali-activated slag - A guide for Civil Engineer. Constr Build Mater 47:29–55. https://doi.org/10.1016/j.conbuildmat.2013.04.011
Ren S et al (2012) Influence of B2O3 on viscosity of high Ti-bearing blast furnace slag. ISIJ Int 52(6):984–991. https://doi.org/10.2355/isijinternational.52.984
Richardson IG, Groves GW (1992) Microstructure and microanalysis of hardened cement pastes involving ground granulated blast-furnace slag. J Mater Sci 27(22):6204–6212. https://doi.org/10.1007/BF01133772
Richardson IG, Li S (2018) Composition and structure of an 18-year-old 5M KOH-activated ground granulated blast-furnace slag paste. Constr Build Mater 168:404–411. https://doi.org/10.1016/j.conbuildmat.2018.02.034
Rodríguez-Mendoza YE, Fuentes AF, Escalante-García JI (2012) Cementitious blends of portland cement with calcium sulphate, fly ash and cupola slag. Mater Res Soc Symp Proc 1488:9–15. https://doi.org/10.1557/opl.2012.1541
Rodríguez De Sensale G (2006) Strength development of concrete with rice-husk ash. Cement Concr Compos 28(2):158–160. https://doi.org/10.1016/j.cemconcomp.2005.09.005
Römer W, Steingrobe B (2018) Fertilizer effect of phosphorus recycling products. Sustain (switzerland) 10(4):1166. https://doi.org/10.3390/su10041166
Sahdeo SK et al (2021) Reclaimed asphalt pavement as a substitution to natural coarse aggregate for the production of sustainable pervious concrete pavement mixes. J Mater Civ Eng 33(2):04020469. https://doi.org/10.1061/(asce)mt.1943-5533.0003555
Shehata MH, Thomas MDA, Bleszynski RF (1999) The effects of fly ash composition on the chemistry of pore solution in hydrated cement pastes. Cem Concr Res 29(12):1915–1920. https://doi.org/10.1016/S0008-8846(99)00190-8
Shi C, Krivenko PV, Roy D (2006) Alkali-activated cements and concretes. Alkali-Activ Cem Concr. https://doi.org/10.4324/9780203390672
Shimoda K et al (2008) Total understanding of the local structures of an amorphous slag: Perspective from multi-nuclear (29Si, 27Al, 17O, 25Mg, and 43Ca) solid-state NMR. J Non-Cryst Solids 354(10–11):1036–1043. https://doi.org/10.1016/j.jnoncrysol.2007.08.010
Siddique R et al (2016) Properties of bacterial rice husk ash concrete. Constr Build Mater 121:112–119. https://doi.org/10.1016/j.conbuildmat.2016.05.146
Siddique S et al (2019) Sustainable utilisation of ceramic waste in concrete: exposure to adverse conditions. J Clean Prod 210:246–255. https://doi.org/10.1016/j.jclepro.2018.10.231
Silvestre BS, Ţîrcă DM (2019) Innovations for sustainable development: moving toward a sustainable future. J Clean Prod 208:325–332. https://doi.org/10.1016/j.jclepro.2018.09.244
Soiński MS, Kordas P, Skurka K (2016) Trends in the production of castings in the World and in Poland in the XXI century. Arch Foundry Eng 16(2):5–10. https://doi.org/10.1515/afe-2016-0017
Sosa I et al. (2020) Durability in marine environment of high-performance concrete with electric arc furnace slags and cupola slag admixture. In: XV international conference on durability of building materials and components, Barcelona
Sosa I et al (2020b) High performance self-compacting concrete with electric arc furnace slag aggregate and cupola slag powder. Appl Sci (switzerland) 10(3):773. https://doi.org/10.3390/app10030773
Stroup WW, Stroup RD, Fallin JH (2003) Cupola slag cement mixture and methods of making and using the same, United States Patent no. US6521039B2
Suhendro B (2014) Toward green concrete for better sustainable environment. Procedia Eng 95:305–320. https://doi.org/10.1016/j.proeng.2014.12.190
The Foundry Informatics Centre (2020) Profile of indian foundry industry. Available at: foundryinfo-india.org/profile_of_indian.aspx.
Topcu IB, Guncan NF (1995) Using waste concrete as aggregate. Cem Concr Res 25(7):1385–1390
Twigg MV, Richardson JT (2002) Theory and applications of ceramic foam catalysts. Chem Eng Res Des 80(2):183–189. https://doi.org/10.1016/S0263-8762(02)72166-7
Vega-Zamanillo Á et al (2017) Analysis of the use of cupola furnace slags, green sand and reclaimed asphalt pavement in asphalt concrete mixtures for low intensity traffic. Revista De La Construction 16(2):229–237. https://doi.org/10.7764/RDLC.16.2.229
Walker R, Pavía S (2011) Physical properties and reactivity of pozzolans, and their influence on the properties of lime-pozzolan pastes. Mater Struct/materiaux Et Constr 44(6):1139–1150. https://doi.org/10.1617/s11527-010-9689-2
Yilmaz B, Müller U (2009) Catalytic applications of zeolites in chemical industry. Top Catal 52(6–7):888–895. https://doi.org/10.1007/s11244-009-9226-0
Zhou H et al (2020) Phosphorus pollution control using waste-based adsorbents: Material synthesis, modification, and sustainability. Crit Rev Environ Sci Technol. https://doi.org/10.1080/10643389.2020.1866414
Acknowledgements
The authors wholeheartedly acknowledge the Department of Science & Technology and Biotechnology, Government of West Bengal (Memo No.: 1698(Sanc.)/ST/P/S&T/6G-3/2019 dated 06.02.2020) sponsored project “Reuse of cupola slag–an attempt for sustainable development”, of Jadavpur University for providing financial support for the research work.
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Chakravarty, S., Haldar, P., Nandi, T. et al. Cupola slag reutilization for sustainable waste management: review and economic analysis. Int. J. Environ. Sci. Technol. 20, 1169–1184 (2023). https://doi.org/10.1007/s13762-021-03574-x
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DOI: https://doi.org/10.1007/s13762-021-03574-x