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Synthesis of imidazolidine derivatives and investigation of coordination to manganese(II) ion

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Abstract

The imidazolidine derivatives were prepared via [1 + 1] condensation of various aldehydes such as 2-Hydroxy benzaldehyde, 2-fluoro benzaldehyde, 2-chloro benzaldehyde, pyridine-2-carbaldehyde, pyrrole-2-carbaldehyde, thiophene-2-carbaldehyde, furan-2-carbaldehyde with N,N′-bis((pyridine-2-yl)methyl)ethane-1,2-diamine (L) in the solvent of acetonitrile and characterized by the appropriate spectroscopic methods (FT-IR, UV–Vis, molar conductivity, 1H and 13C NMR, EI-Mass, X-ray). By coordinating the imidazolidine ring to the metal ions, this ring can be stabilized or hydrolyzed and converted to initial materials. Therefore, in this research, to investigate the effect of imidazolidine ring pressure and the effect of different groups in neutralizing this pressure in coordination with manganese(II) ion, the Manganese(II) complexes of these compounds were synthesized and characterized by FT-IR, UV–Vis spectroscopy, molar conductivity, EI-Mass spectrometry, and X-ray crystallography. The spectroscopic data for the imidazolidine derivatives confirm their formation. The manganese(II) complex of these compounds showed that the imidazolidine ring was unstable due to coordinated and created pressure on the imidazolidine ring and the presence of different groups on the ring does not affect the stability.

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Acknowledgements

We are grateful to the Faculty of Chemistry of Yazd University and the Ministry of Science, Research and Technology of Iran, for their financial support.

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Authors and Affiliations

  1. Department of Chemistry, Yazd University, Yazd, Iran

    Ahmad Ali Dehghani-Firouzabadi & Zahra Samadifar

  2. Chemistry Department, ShahidBeheshti University, G. C., Evin, Tehran, 1983963113, Iran

    Behrouz Notash

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  1. Ahmad Ali Dehghani-Firouzabadi
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  2. Zahra Samadifar
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Corresponding author

Correspondence to Ahmad Ali Dehghani-Firouzabadi.

Appendix A

Appendix A

CCDC 1483053, 1559036, and 1483052 contain the supplementary crystallographic data for L2, L6, and [MnLCl2], respectively. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+ 44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.

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Dehghani-Firouzabadi, A.A., Samadifar, Z. & Notash, B. Synthesis of imidazolidine derivatives and investigation of coordination to manganese(II) ion. J IRAN CHEM SOC 21, 679–687 (2024). https://doi.org/10.1007/s13738-023-02950-3

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