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Piperidine and Piperazine Immobilized on Iron Oxide Nanoparticles as Magnetically Recyclable Heterogeneous Catalysts for One-Pot Synthesis of β-Phosphonomalonates

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Abstract

Piperidine and piperazine immobilized on silica-coated γ-Fe2O3 magnetic nanoparticles were synthesized as new supported bases via the reaction of chloro-functionalized γ-Fe2O3@SiO2 with piperidine and piperazine, respectively. The resulting bases were employed as magnetically recyclable heterogeneous catalysts for the efficient one-pot three-component synthesis of β-phosphonomalonates. The catalysts were easily separated from the reaction mixture by using a magnet and recycled for five times without significant loss of the catalytic activity.

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Acknowledgments

We are thankful to University of Birjand Research Council for their support on this work.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, University of Birjand, Birjand, Iran

    Sara Sobhani & Maryam Sadat Ghasemzadeh

  2. Department of Chemical Engineering, Faculty of Mining, Chemical and Material Engineering, Birjand University of Technology, Birjand, Iran

    Moones Honarmand

Authors
  1. Sara Sobhani
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  2. Maryam Sadat Ghasemzadeh
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  3. Moones Honarmand
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Corresponding author

Correspondence to Sara Sobhani.

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Sobhani, S., Ghasemzadeh, M.S. & Honarmand, M. Piperidine and Piperazine Immobilized on Iron Oxide Nanoparticles as Magnetically Recyclable Heterogeneous Catalysts for One-Pot Synthesis of β-Phosphonomalonates. Catal Lett 144, 1515–1523 (2014). https://doi.org/10.1007/s10562-014-1297-2

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  • DOI: https://doi.org/10.1007/s10562-014-1297-2

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