Abstract
Due to a unique high efficiency in producing microfibers and nanofibers, centrifugal electrospinning that combines centrifugal spinning and electrospinning has attracted great interest in academic research and industrial manufacturing. This work is focused on the effects of various parameters of centrifugal electrospinning on the structure and properties of poly(vinyl pyrrolidone) fibers prepared by centrifugal electrospinning. The spinning parameters of interest included spinning voltage and rotation speed, and the characteristics of fibers included spinning productivity, jet trajectory, fiber morphology, fiber diameter, and fiber alignment. It was found that there was a competitive relationship between centrifugal force and electrostatic force during fiber formation. When only centrifugal force was applied, the obtained fibers mostly exhibited a circular distribution. When the electrostatic force began to increase, the fibers became increasingly uniform in morphology and showed a distribution in the vertical circumferential direction. The fiber alignment shows that the effects of these two factors on fiber alignment are competitive. The fiber yield shows that when the rotating speed is fixed at 1500 rpm, with the increase of voltage, the yield increases significantly and then increases slowly. The results suggest that centrifugal electrospinning can be favorable in the production of nanostructured fiber materials.
Graphical abstract
Similar content being viewed by others
References
Li Z, Mei S, Dong Y, She F, Kong L (2019) High efficiency fabrication of chitosan composite nanofibers with uniform morphology via centrifugal spinning. Polymers 11:1550
Kwak BE, Yoo HJ, Lee E, Kim DH (2021) Large-scale centrifugal multispinning production of polymer micro-and nanofibers for mask filter application with a potential of cospinning mixed multicomponent fibers. ACS Macro Lett 10:382–388
Ning X, Li Z (2021) Centrifugally spun SnSb nanoparticle/porous carbon fiber composite as high-performance lithium-ion battery anode. Mater Lett 287:129298
Saha S, Sadhukhan P, Roy Chowdhury S, Das S (2020) Rotary-Jet spin assisted fabrication of MnO2 microfiber for supercapacitor electrode application. Mater Lett 277:128342
Loordhuswamy A, Thinakaran S, Rangaswamy GD (2020) Centrifugal spun osteoconductive ultrafine fibrous mat as a scaffold for bone regeneration. J Drug Deliv Sci Technol 60:101978
Xue J, Wu T, Dai Y, Xia Y (2019) Electrospinning and electrospun nanofibers: methods, materials, and applications. Chem Rev 119:5298–5415
Liu Y, Li K, Mohideen MM, Ramakrishna S (2019) Melt electrospinning: a green method to produce superfine fibers. Academic, New York
Li K, Xu Y, Liu Y, Mohideen MM, He H, Ramakrishna S (2019) Dissipative particle dynamics simulations of centrifugal melt electrospinning. J Mater Sci 54:9958–9968
Kakiage M, Fukagawa D (2020) Preparation of ultrahigh-molecular-weight polyethylene fibers by combination of melt-spinning and melt-drawing. Mater Today Commun 23:100864
Im SH, Park SJ, Chung JJ, Jung Y, Kim SH (2019) Creation of polylactide vascular scaffolds with high compressive strength using a novel melt-tube drawing method. Polymer 166:130–137
Jafri NN, Jaafar J, Othman MH, Rahman MA, Aziz F, Yusof N, Salleh WN, Ismail AF (2021) Titanium dioxide hollow nanofibers for enhanced photocatalytic activities. Mater Today 46:2004–2011
Kumar A, Khanuja M (2021) Template-free graphitic carbon nitride nanosheets coated with polyaniline nanofibers as an electrode material for supercapacitor applications. Renew Energ 171:1246–1256
Kang J, Choi J, Yun SI (2021) Nonsolvent-induced phase separation of poly(3-hydroxybutyrate) and poly(hydroxybutyrate-co-hydroxyvalerate) blend as a facile platform to fabricate versatile nanofiber gels: Aero-, hydro-, and oleogels. Int J Biol Macromol 173:44–55
Cheng Q, Zhang Y, Zheng X, Sun W, Li B, Wang D, Li Z (2021) High specific surface crown ether modified chitosan nanofiber membrane by low-temperature phase separation for efficient selective adsorption of lithium. Sep Purif Technol 262:118312
Zheng J, Fan R, Wu H, Yao H, Yan Y, Liu J, Ran L, Sun Z, Yi L, Dang L, Gan P, Zheng P, Yang T, Zhang Y, Tang T, Wang Y (2019) Directed self-assembly of herbal small molecules into sustained release hydrogels for treating neural inflammation. Nat Commun 10:1604
Nguyen D, Huynh V, Pham N, Pham B, Serelis A, Davey T, Such C, Hawkett B (2019) SPION-decorated nanofibers by RAFT-mediated free radical emulsion polymerization-induced self assembly. Macromol Rapid Commun 40:e1800402
Rosman N, Wan Salleh WN, Jamalludin MR, Adam MR, Ismail NH, Jaafar J, Harun Z, Ismail AF (2021) Electrospinning parameters evaluation of PVDF-ZnO/Ag2CO3/Ag2O composite nanofiber affect on porosity by using response surface methodology. Mater Today 46:1824–1830
Beknalkar SA, Teli AM, Harale NS, Patil DS, Pawar SA, Shin JC, Patil PS (2021) Fabrication of high energy density supercapacitor device based on hollow iridium oxide nanofibers by single nozzle electrospinning. Appl Surf Sci 546:149102
Song T, Chen Z, He H, Liu Y, Ramakrishna S (2015) Orthogonal design study on factors affecting the diameter of perfluorinated sulfonic acid nanofibers during electrospinning. J Appl Polym Sci 132:41775
del Ángel-Sánchez K, Ulloa-Castillo NA, Segura-Cárdenas E, Martinez-Romero O, Elías-Zuñiga A (2019) Design, fabrication, and characterization of polycaprolactone (PCL)-TiO2-collagenase nanofiber mesh scaffolds by Forcespinning. MRS Commun 9:390–397
Zander NE (2015) Formation of melt and solution spun polycaprolactone fibers by centrifugal spinning. J Appl Polym Sci 132:41269
Mamidi N, Gutiérrez HML, Villela-Castrejón J, Isenhart L, Barrera EV, Elías-Zúñiga A (2017) Fabrication of gelatin-poly(epichlorohydrin-co-ethylene oxide) fiber scaffolds by Forcespinning® for tissue engineering and drug release. MRS Commun 7:913–921
Chang WM, Wang CC, Chen CY (2019) Fabrication of ultra-thin carbon nanofibers by centrifuged-electrospinning for application in high-rate supercapacitors. Electrochim Acta 296:268–275
Wang L, Wang B, Ahmad Z, Li JS, Chang MW (2019) Dual rotation centrifugal electrospinning: a novel approach to engineer multi-directional and layered fiber composite matrices. Drug Deliv Transl Res 9:204–214
Erickson A, Sun J, Levengood SKL, Zhang M (2019) Hyaluronic acid-coated aligned nanofibers for the promotion of glioblastoma migration. ACS Appl Bio Mater 2:1088–1097
Chen H, Li X, Li N, Yang B (2016) Electrostatic-assisted centrifugal spinning for continuous collection of submicron fibers. Text Res J 87:2349–2357
Valipouri A, Ravandi SAH, Pishevar AR (2013) A novel method for manufacturing nanofibers. Fibers Polym 14:941–949
Chang WM, Wang CC, Chen CY (2014) The combination of electrospinning and forcespinning: effects on a viscoelastic jet and a single nanofiber. Chem Eng J 244:540–551
Müller F, Jokisch S, Bargel H, Scheibel T (2020) Centrifugal electrospinning enables the production of meshes of ultrathin polymer fibers. ACS Appl Polym Mater 2:4360–4367
Lu W, Chen W, Lu W (2020) Fabrication of a wrinkled structure made of wearable polyacrylonitrile/polyurethane composite fibers with elastic sensing properties suitable for human movement detection. Polym Compos 41:3491–3500
Edmondson D, Cooper A, Jana S, Wood D, Zhang M (2012) Centrifugal electrospinning of highly aligned polymer nanofibers over a large area. J Mater Chem 22:18646–18652
Kancheva M, Toncheva A, Manolova N, Rashkov I (2014) Advanced centrifugal electrospinning setup. Mater Lett 136:150–152
Heidari I, Mosavi Mashhadi M, Faraji G (2013) A novel approach for preparation of aligned electrospun polyacrylonitrile nanofibers. Chem Phys Lett 590:231–234
Khamforoush M, Asgari T (2014) A modified electro-centrifugal spinning method to enhance the production rate of highly aligned nanofiber. NANO 10:1550016
Liao CC, Wang CC, Chen CY, Lai WJ (2011) Stretching-induced orientation of polyacrylonitrile nanofibers by an electrically rotating viscoelastic jet for improving the mechanical properties. Polymer 52:2263–2275
Liao CC, Wang CC, Chen CY (2011) Stretching-induced crystallinity and orientation of polylactic acid nanofibers with improved mechanical properties using an electrically charged rotating viscoelastic jet. Polymer 52:4303–4318
Liao CC, Wang CC, Shih KC, Chen CY (2011) Electrospinning fabrication of partially crystalline bisphenol A polycarbonate nanofibers: effects on conformation, crystallinity, and mechanical properties. Eur Polym J 47:911–924
Liao CC, Hou SS, Wang CC, Chen CY (2010) Electrospinning fabrication of partially crystalline bisphenol A polycarbonate nanofibers: the effects of molecular motion and conformation in solutions. Polymer 51:2887–2896
Dabirian F, Ravandi SAH, Pishevar AR (2013) The effects of operating parameters on the fabrication of polyacrylonitrile nanofibers in electro-centrifuge spinning. Fibers Polym 14:1497–1504
Dabirian F, Hosseini Ravandi AS, Pishevar RA (2010) Investigation of parameters affecting PAN nanofiber production using electrical and centrifugal forces as a novel method. Current Nanosci 6:545–552
Dabirian F, Hosseini Ravandi AS, Pishevar RA, Abuzade RA (2011) A comparative study of jet formation and nanofiber alignment in electrospinning and electrocentrifugal spinning systems. J Electrostat 69:540–546
Valipouri A, Hosseini Ravandi SA, Pishevar A (2014) Optimization of the parameters involved in fabrication of solid state polymerized polyamide (SSP PA66) nanofibers via an enhanced electro-centrifuge spinning. J Ind Text 45:368–386
Wu S, Peng H, Li X, Streubel PN, Liu Y, Duan B (2017) Effect of scaffold morphology and cell co-culture on tenogenic differentiation of HADMSC on centrifugal melt electrospun poly (L-lactic acid) fibrous meshes. Biofabrication 9:044106
Hashemi AR, Pishevar AR, Valipouri A, Părău EI (2018) Numerical and experimental study on the steady cone-jet mode of electro-centrifugal spinning. Phys Fluids 30:017103
Peng H, Liu Y, Ramakrishna S (2017) Recent development of centrifugal electrospinning. J Appl Polym Sci 134:44578
Cao K, Liu Y, Olkhov AA, Siracusa V, Iordanskii AL (2018) PLLA-PHB fiber membranes obtained by solvent-free electrospinning for short-time drug delivery. Drug Deliv Transl Res 8:291–302
Gómez-Tejedor JA, Overberghe NV, Rico P, Ribelles JLG (2011) Assessment of the parameters influencing the fiber characteristics of electrospun poly(ethyl methacrylate) membranes. Eur Polym J 47:119–129
Ayres CE, Jha BS, Meredith H, Bowman JR, Bowlin GL, Henderson SC, Simpson DG (2008) Measuring fiber alignment in electrospun scaffolds: a user’s guide to the 2D fast Fourier transform approach. J Biomater Sci Polym Ed 19:603–621
Ayres C, Bowlin GL, Henderson SC, Taylor L, Shultz J, Alexander J, Telemeco TA, Simpson DG (2006) Modulation of anisotropy in electrospun tissue-engineering scaffolds: analysis of fiber alignment by the fast Fourier transform. Biomaterials 27:5524–5534
Shi K, Giapis KP (2018) Scalable fabrication of supercapacitors by nozzle-free electrospinning. ACS Appl Energ Mater 1:296–300
Xu H, Chen H, Li X, Liu C, Yang B (2014) A comparative study of jet formation in nozzle- and nozzle-less centrifugal spinning systems. J Polym Sci Part B 52:1547–1559
Lord Rayleigh FRS (1882) On the equilibrium of liquid conducting masses charged with electricity. Lond Edinb Dublin Philos Mag J Sci 14:184
Acknowledgements
The authors would like to thank Professor Xiaozhen Yang of the Institute of Chemistry, Chinese Academy of Science, for his valuable discussions. This study was financially supported by the National Natural Science Foundation of China (21374008).
Author information
Authors and Affiliations
Contributions
The manuscript was written through the contributions of all authors. All authors have approved the final version of the manuscript.
Corresponding author
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Chen, J., Hu, H., Song, T. et al. Competitive effects of centrifugal force and electric field force on centrifugal electrospinning. Iran Polym J 31, 1147–1159 (2022). https://doi.org/10.1007/s13726-022-01073-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13726-022-01073-5