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Short-Term Oxidation Response of Nb–15Re–15Si–20Cr–15Ti Alloy

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Abstract

The Nb–15Re–15Si–20Cr–15Ti alloy was subjected to 24 h of air exposure in a temperature range from 700 to 1,400 °C. The Re addition to the Nb–Si–Cr–Ti alloy has been found to control pesting at lower temperatures, and spalling at higher temperatures. Formation of Cr2Re3 phase is believed to help in the lowering the oxidation kinetics, thus reducing pesting and spalling. Addition of titanium improves the oxidation resistance by forming intermetallics such as (Nb,Ti)5Si3, NbCr2, and Cr2Re3. The weight gain/loss per unit area as a function of temperature is used to determine the oxidation resistance. Oxidation characterization was carried out using XRD and backscattered imaging, EDS, and x-ray mapping modes on the SEM.

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References

  1. J.H. Schneibel, Beyond nickel-base superalloys (Metals and Ceramic Division, Oak Ridge National Laboratory, Oak Ridge, 2005)

    Google Scholar 

  2. B.P. Bewlay, H.A. Lipsitt, M.R. Jackson, W.J. Reeder, J.A. Sutliff, Solidification processing of high temperature intermetallic eutectic-based alloys. Mater. Sci. Eng. A 192/193, 534–543 (1995)

    Article  Google Scholar 

  3. K.S. Chan, Cyclic oxidation response of the multiphase niobium-based alloys. Metall. Mater. Trans. A 35A, 589 (2004)

    Article  Google Scholar 

  4. C. Liu, P. Tortorelli, J. Horton, C. Carmichael, Effects of alloy additions on the microstructure and properties of Cr–Cr2Nb alloys. Mater. Sci. Eng. A 214, 23–32 (1996)

    Article  Google Scholar 

  5. J.C. Carlen, Elyria, Ohio “Molybdenum–Rhenium Alloy” United States patent, Patent No. 5437744, 1 Aug 1995

  6. K.S. Chan, Cyclic-oxidation resistance of niobium-base in situ composites: modeling and experimentation. Oxid. Met. 61, 165–194 (2004)

    Article  Google Scholar 

  7. S.K. Varma, R.M. Dasary, Short term oxidation of Nb–15Re–15Si–10Cr–20Mo. J. Mater. Res. Technol. 3(1), 25–34 (2014)

    Article  Google Scholar 

  8. J. Geng, P. Tsakiropoulos, A study of the microstructures and oxidation resistance of Nb–Si–Cr–Al–Mo in situ composites alloyed with Ti, Hf and Sn. Intermetallics 15, 382–395 (2007)

    Article  Google Scholar 

  9. B. Bewlay, M. Jackson, H. Lipsitt, The balance of mechanical and environmental properties of a multi-element niobium–niobium silicide-based in situ composite. Metall. Trans. A 27A, 3801–3808 (1996)

    Article  Google Scholar 

  10. K.S. Chan, Cyclic oxidation response of multiphase niobium-based alloys. Metall. Trans. 35, 589–597 (2004)

    Article  Google Scholar 

  11. S.K. Varma, C. Parga, K. Amato, J. Hernandez, Microstructures and high temperature oxidation resistance of alloys from Nb–Cr–Si system. J. Mater. Sci. 45(14), 3931–3937 (2010)

    Article  Google Scholar 

Download references

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Correspondence to Ruth M. Dasary-Sierra.

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Dasary-Sierra, R.M., Varma, S.K. Short-Term Oxidation Response of Nb–15Re–15Si–20Cr–15Ti Alloy. Metallogr. Microstruct. Anal. 3, 224–232 (2014). https://doi.org/10.1007/s13632-014-0139-3

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  • DOI: https://doi.org/10.1007/s13632-014-0139-3

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