Skip to main content

Advertisement

Log in

Cellulose membranes via a top-down approach from loofah for oil/water separation

  • Original Article
  • Published:
Biomass Conversion and Biorefinery Aims and scope Submit manuscript

Abstract

Degradable materials have been used for the preparation of oil-water separation membranes, especially cellulose-based membranes. However, the extraction of cellulose nanofibers is time, energy, and chemically intensive and the source of cellulose is mainly wood, bamboo, cotton, and flax. Herein, we report a top-down approach for the scalable production of structurally asymmetric composite cellulose membranes from loofah. The tear strength of the membrane was 388.7% times of the PVDF membrane and the preparation cost was only 3.3% of the price of commercially available nitrocellulose membrane. A superhydrophobic renewable and degradable cellulose membrane with a surface water contact angle of 152.3°can be prepared by a one-step method using the cellulose membrane as a substrate and dodecyltriethoxysilane as a modifier. The superhydrophobic cellulose membrane could separate oil and water by continuous filtration with high efficiency (98.1%) and high flux (2349Lm-2h-1). Such a simple and low-cost method could promote the popularity of separation membranes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5
Fig. 6.
Fig. 7
Fig. 8
Fig. 9.

Similar content being viewed by others

Data availability

There is no dataset provided with this submission.

References

  1. Schrope M (2010) Deepwater Horizon: a scientist at the centre of the spill. Nature 466:680–684. https://doi.org/10.1038/466680a

    Article  Google Scholar 

  2. Jernelöv A (2010) How to defend against future oil spills. Nature 466:182–183. https://doi.org/10.1038/466182a

    Article  Google Scholar 

  3. Ge J, Zhao H, Zhu H et al (2016) Advanced sorbents for oil-spill cleanup: recent advances and future perspectives. Adv Mater 28:10459–10490. https://doi.org/10.1002/adma.201601812

    Article  Google Scholar 

  4. Deng Y, Peng C, Dai M et al (2020) Recent development of super-wettable materials and their applications in oil-water separation. Journal of Cleaner Production 266:121624. https://doi.org/10.1016/j.jclepro.2020.121624

    Article  Google Scholar 

  5. Rasouli S, Rezaei N, Hamedi H et al (2021) Superhydrophobic and superoleophilic membranes for oil-water separation application: a comprehensive review. Materials & Design 204:109599. https://doi.org/10.1016/j.matdes.2021.109599

    Article  Google Scholar 

  6. Ryerson TB, Camilli R, Kessler JD et al (2012) Chemical data quantify Deepwater Horizon hydrocarbon flow rate and environmental distribution. Proceedings of the National Academy of Sciences 109:20246–20253. https://doi.org/10.1073/pnas.1110564109

    Article  Google Scholar 

  7. McNutt MK, Chu S, Lubchenco J et al (2012) Applications of science and engineering to quantify and control the Deepwater Horizon oil spill. Proceedings of the National Academy of Sciences 109:20222–20228. https://doi.org/10.1073/pnas.1214389109

    Article  Google Scholar 

  8. Qiu L, Sun Y, Guo Z (2020) Designing novel superwetting surfaces for high-efficiency oil-water separation: design principles, opportunities, trends and challenges. Journal of Materials Chemistry A 8:16831–16853. https://doi.org/10.1039/d0ta02997a

    Article  Google Scholar 

  9. Jing L, Wang L, Wang N et al (2017) A robust Cu (OH)2 nanoneedles mesh with tunable wettability for nonaqueous multiphase liquid separation. Small 13:1600499. https://doi.org/10.1002/smll.201600499

    Article  Google Scholar 

  10. Gondal MA, Sadullah MS, Qahtan TF et al (2017) Fabrication and wettability study of WO3 coated photocatalytic membrane for oil-water separation: a comparative study with ZnO coated membrane. Sci Rep 7:1686. https://doi.org/10.1038/s41598-017-01959-y

    Article  Google Scholar 

  11. Hou L, Wang L, Wang N et al (2016) Separation of organic liquid mixture by flexible nanofibrous membranes with precisely tunable wettability. NPG Asia Mater 8:e334–e334. https://doi.org/10.1038/am.2016.179

    Article  Google Scholar 

  12. Kota AK, Kwon G, Choi W et al (2012) Hygro-responsive membranes for effective oil–water separation. Nature Communications 3:1025. https://doi.org/10.1038/ncomms2027

    Article  Google Scholar 

  13. Zhang C, Liang F, Zhang W et al (2020) Constructing mechanochemical durable and self-healing superhydrophobic surfaces. ACS Omega 5:986–994. https://doi.org/10.1021/acsomega.9b03912

    Article  Google Scholar 

  14. Ge M, Cao C, Huang J et al (2018) Rational design of materials interface at nanoscale towards intelligent oil–water separation. Nanoscale Horizons 3:235–260. https://doi.org/10.1039/C7NH00185A

    Article  Google Scholar 

  15. Zhang J, Seeger S (2011) Polyester materials with superwetting silicone nanofilaments for oil/water separation and selective oil absorption. Advanced Functional Materials 21:4699–4704. https://doi.org/10.1002/adfm.201101090

    Article  Google Scholar 

  16. Lin J, Lin F, Liu R et al (2020) Scalable fabrication of robust superhydrophobic membranes by one-step spray-coating for gravitational water-in-oil emulsion separation. Separation and Purification Technology 231:115898. https://doi.org/10.1016/j.seppur.2019.115898

    Article  Google Scholar 

  17. Li L, Xu Z, Sun W et al (2020) Bio-inspired membrane with adaptable wettability for smart oil/water separation. Journal of Membrane Science 598:117661. https://doi.org/10.1016/j.memsci.2019.117661

    Article  Google Scholar 

  18. Zhang W, Shi Z, Zhang F et al (2013) Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux. Advanced Materials 25:2071–2076. https://doi.org/10.1002/adma.201204520

    Article  Google Scholar 

  19. Lu KJ, Zhao D, Chen Y et al (2020) Rheologically controlled design of nature-inspired superhydrophobic and self-cleaning membranes for clean water production. npj Clean. Water 3:1–10. https://doi.org/10.1038/s41545-020-0078-2

    Article  Google Scholar 

  20. Peng Y, Zhu W, Shen S et al (2017) Strain-induced surface micro/nanosphere structure: a new technique to design mechanically robust superhydrophobic surfaces with rose petal-like morphology. Advanced Materials Interfaces 4:1700497. https://doi.org/10.1002/admi.201700497

    Article  Google Scholar 

  21. Wang D, Sun Q, Hokkanen MJ et al (2020) Design of robust superhydrophobic surfaces. Nature 582:55–59. https://doi.org/10.1038/s41586-020-2331-8

    Article  Google Scholar 

  22. Leslie HA, van Velzen MJM, Brandsma SH et al (2022) Discovery and quantification of plastic particle pollution in human blood. Environment International 163:107199. https://doi.org/10.1016/j.envint.2022.107199

    Article  Google Scholar 

  23. Hussain SM, Braydich-Stolle LK, Schrand AM et al (2009) Toxicity evaluation for safe use of nanomaterials: recent achievements and technical challenges. Advanced Materials 21:1549–1559. https://doi.org/10.1002/adma.200801395

    Article  Google Scholar 

  24. Hu R, Yang J, Li S et al (2020) Fabrication of special wettability functionalized Mg (OH)(2)@cotton fabric for oil/water mixtures and emulsions separation. Cellulose 27:7739–7749. https://doi.org/10.1007/s10570-020-03315-2

    Article  Google Scholar 

  25. Wang X, Xu S, Tan Y et al (2016) Synthesis and characterization of a porous and hydrophobic cellulose-based composite for efficient and fast oil–water separation. Carbohydrate Polymers 140:188–194. https://doi.org/10.1016/j.carbpol.2015.12.028

    Article  Google Scholar 

  26. Peng Q, Cheng J, Lu S, Li Y (2020) Electrospun hyperbranched polylactic acid–modified cellulose nanocrystals/polylactic acid for shape memory membranes with high mechanical properties. Polymers for Advanced Technologies 31:15–24. https://doi.org/10.1002/pat.4743

    Article  Google Scholar 

  27. Wang D-C, Yang X, Yu H-Y et al (2020) Smart nonwoven fabric with reversibly dual-stimuli responsive wettability for intelligent oil-water separation and pollutants removal. Journal of Hazardous Materials 383:121123. https://doi.org/10.1016/j.jhazmat.2019.121123

    Article  Google Scholar 

  28. Gao S, Dong X, Huang J et al (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation. Chemical Engineering Journal 333:621–629. https://doi.org/10.1016/j.cej.2017.10.006

    Article  Google Scholar 

  29. Li Z, Chen C, Xie H et al (2021) Sustainable high-strength macrofibres extracted from natural bamboo. Nat Sustain. 5:235–244. https://doi.org/10.1038/s41893-021-00831-2

    Article  Google Scholar 

  30. Xing T, Dong C, Wang X et al (2022) Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures. Front Chem Sci Eng 16:1377–1386. https://doi.org/10.1007/s11705-022-2157-z

    Article  Google Scholar 

  31. Popescu CM, Popescu MC, Vasile C (2011) Structural analysis of photodegraded lime wood by means of FT-IR and 2D IR correlation spectroscopy. International Journal of Biological Macromolecules 48:667–675. https://doi.org/10.1016/j.ijbiomac.2011.02.009

    Article  Google Scholar 

  32. Liu C, Wang S, Shi J, Wang C (2011) Fabrication of superhydrophobic wood surfaces via a solution-immersion process. Applied Surface Science 258:761–765. https://doi.org/10.1016/j.apsusc.2011.08.077

    Article  Google Scholar 

  33. Arkles B, Larson GL (2013) Silicon compounds: silanes & silicones, 3rd edn. Gelest, Inc., Morrisville, PA

    Google Scholar 

  34. Labbé N, Rials TG, Kelley SS et al (2005) FT-IR imaging and pyrolysis-molecular beam mass spectrometry: new tools to investigate wood tissues. Wood Sci Technol 39:61–76. https://doi.org/10.1007/s00226-004-0274-0

    Article  Google Scholar 

Download references

Funding

The authors profusely thank the Natural Science Foundation of China [grant number 51776070], and the State Grid Science and Technology Program [SGGNSW00YWJS2100024].

Author information

Authors and Affiliations

Authors

Contributions

Changqing Dong and Xiaoying Hu contributed to conceptualization and methodology. Tong Xing contributed to the investigation, data analysis, and writing the original draft and all other authors contribute to the review, editing, and preparation of the final draft. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Changqing Dong.

Ethics declarations

Ethical approval

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xing, T., Dong, C., Hu, X. et al. Cellulose membranes via a top-down approach from loofah for oil/water separation. Biomass Conv. Bioref. (2023). https://doi.org/10.1007/s13399-023-03766-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s13399-023-03766-0

Keywords

Navigation