Abstract
The dynamic performances of various adsorbents in removing lead ion, Pb(II), from aqueous solution in an industrial-sized packed bed column were investigated through numerical simulation, by employing a linear driving force (LDF) approximation model in Aspen Adsorption simulation tool. The size of the real implemented packed bed column with dimensions of 0.9730 m height and 0.6096 m diameter, with a design flowrate of 631 mL/s and inlet concentration of 0.1 mg/L Pb(II) aqueous solution, was used to represent an industrial-sized packed bed column. Here, the dynamic performances of ten Langmuir-fitted adsorbents for removing Pb(II) from an aqueous solution were evaluated. Among the ten adsorbents, the apricot stone AC gave the highest dynamic adsorptive performance with the highest saturation time (203 days) and percentage removal (95.6%). This suggests a cheaper and environmental-friendly alternative of using biomass-activated adsorbent. Based on the simulation results of the ten adsorbents, a simple analysis method was formulated as a preliminary screening for comparing the adsorptive performance using information from the batch experiments related to separation factor and total adsorbent mass. The Langmuir separation factor, RL, can be used as a preliminary indicator to rank various adsorbents in removing Pb(II). In the case of available adsorbent density, the mtotal indicator is more reliable and gives a better indicator than RL. This present paper provides a preliminary screening in comparing various adsorbents’ performance operated in a packed bed column, especially the industrial-sized packed bed column.
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Kelishadi R (2012) Environmental pollution: health effects and operational implications for pollutants removal. J Environ Public Health 2012:341637
Mayur R (1979) Environmental problems of developing countries. Ann Am Acad Pol Soc Sci 444:89–101
Muralikrishna IV, Manickam V (2017) Environmental management: science and engineering for industry, 1st edn. Elsevier, Oxford, United Kingdom
Renu M, Agarwal K (2017) Singh, Heavy metal removal from wastewater using various adsorbents: a review. J Water Reuse Desalin 7:387–419
U.S. Department of Health and Human Services, Toxicological profile for lead, (2007).
Assi M, Hezmee M, Haron A, Sabri M, Rajion M (2016) The detrimental effects of lead on human and animal health. Vet World 9:660–671. https://doi.org/10.14202/vetworld.2016.660-671
Bahrun MHV, Kamin Z, Anisuzzaman SM, Bono A (2021) Assessment of adsorbent for removing lead (Pb) ion in an industrial-scaled packed bed column. J Eng Sci Technol 16:1213–1231
Ahmadi M, Teymouri P, Setodeh A, Mortazavi MS, Asgari A (2011) Adsorption of Pb(II) from aqueous solution onto Lewatit FO36 nano resin: equilibrium and kinetic studies. Environ Eng Manag J 10:1579–1587
Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92:407–418
Vardhan KH, Kumar PS, Panda RC (2019) A review on heavy metal pollution, toxicity and remedial measures: current trends and future perspectives. J Mol Liq 290:111197
Hanafy H, Sellaoui L, Thue PS, Lima EC, Dotto GL, Alharbi T, Belmabrouk H, Bonilla-Petriciolet A, Ben Lamine A (2019) Statistical physics modeling and interpretation of the adsorption of dye remazol black B on natural and carbonized biomasses. J.Mol Liq 299:112099
Hu A, Ren G, Che J, Guo Y, Ye J, Zhou S (2020) Phosphate recovery with granular acid-activated neutralized red mud: fixed-bed column performance and breakthrough curve modelling. J Environ Sci 90:78–86
Ye N, Cimetiere N, Heim V, Fauchon N, Feliers C, Wolbert D (2019) Upscaling fixed bed adsorption behaviors towards emerging micropollutants in treated natural waters with aging activated carbon: model development and validation. Water Res 148:30–40. https://doi.org/10.1016/j.watres.2018.10.029
Paixão RM, Reck IM, Gomes RG, Bergamasco R, Vieira MF, Vieira AMS (2018) Water decontamination containing nitrate using biosorption with Moringa oleifera in dynamic mode. Environ Sci Pollut Res 25:21544–21554
Kamin Z, Bono A, Bahrun MHV (2021) Applicability of linear driving force (LDF) mass transfer model for heavy metal biosorption in packed bed column. Mater Today Proc 42:186–190. https://doi.org/10.1016/j.matpr.2020.11.343
Bahrun MHV, Battak N, Tan W-H, Bono A (2022) Process simulation of steam stripping of bleached palm oil deodorization for removing free fatty acids using DWSIM. J Phys Conf Ser 2314:012016. https://doi.org/10.1088/1742-6596/2314/1/012016
Danish M, Ansari KB, Danish M, Khan NA, Aftab RA, Zaidi S, Khan MS, Al Mesfer MK, Qyyum MA, Nizami AS (2022) Developing convective–dispersive transport model to characterize fixed-bed adsorption of lead (II) over activated tea waste biosorbent. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-021-02130-4
AspenTech A (2001) reference guide. Aspen Technology Inc, United Kingdom
Marin P, Borba CE, Módenes AN, Espinoza-Quiñones FR, De Oliveira SPD, Kroumov AD (2014) Determination of the mass transfer limiting step of dye adsorption onto commercial adsorbent by using mathematical models. Environ Technol (United Kingdom) 35:2356–2364. https://doi.org/10.1080/09593330.2014.904445
Glueckauf E (1955) Theory of chromatography. Part 10: formulae for diffusion into spheres and their application to chromatography. Trans Faraday Soc 51:1540–1551. https://doi.org/10.1039/TF9555101540
Knox J, Ebner PAD, Levan MD, Coker RF, Ritter JA (2016) Limitations of breakthrough curve analysis in fixed-bed adsorption. Ind Eng Chem Res 55:4734–4748
Tan W-H, Bahrun MHV, Surugau N, Bono A (2020) Evaluation of adsorption dynamic retention of copper ion in porous agricultural soil, Trans. Sci Technol 7:90–100
Ohashi H, Sugawara T, Kikuchi K, Konno H (1981) Correlation of liquid-side mass transfer coefficient for single particles and fixed beds. J Chem Eng Japan 14:433–438
Sperlich A, Schimmelpfennig S, Baumgarten B, Genz A, Amy G, Worch E, Jekel M (2008) Predicting anion breakthrough in granular ferric hydroxide (GFH) adsorption filters. Water Res 42:2073–2082. https://doi.org/10.1016/j.watres.2007.12.019
Wakao N, Funazkri T (1978) Effect of fluid dispersion coefficients on particle-to-fluid mass transfer coefficients in packed beds: correlation of sherwood numbers. Chem Eng Sci 33:1375–1384
Bono A (1989) Sorptive separation of simple water soluble organics, University of Surrey.
Lakshmikandhan K, Ramadevi A (2019) Removal of lead in water using activated carbon prepared from Acacia catechu. Water SA 45:374–382
Mouni L, Merabet D, Bouzaza A, Belkhiri L (2011) Adsorption of Pb(II) from aqueous solutions using activated carbon developed from apricot stone. Desalination 276:148–153
Yi ZJ, Yao J, Kuang YF, Chen HL, Wang F, Yuan ZM (2015) Removal of Pb(II) by adsorption onto Chinese walnut shell activated carbon. Water Sci Technol 72:983–989
Goel J, Kadirvelu K, Rajagopal C, Kumar V (2005) Removal of lead (II) by adsorption using treated granular activated carbon: batch and column studies. J Hazard Mater 125:211–220
Asuquo E, Martin A, Nzerem P, Siperstein F, Fan X (2017) Adsorption of Cd(II) and Pb(II) ions from aqueous solutions using mesoporous activated carbon adsorbent: equilibrium, kinetics and characterisation studies. J Environ Chem Eng 5:679–698
Danish M, Hashim R, Rafatullah M, Sulaiman O, Govind AA (2011) Adsorption of Pb(II) ions from aqueous solutions by date bead carbon activated with ZnCl2. clean - soil, air, water 39:392–399
Shekinah P, Kadirvelu K, Kanmani P, Senthilkumar P, Subburam V (2002) Adsorption of lead (II) from aqueous solution by activated carbon prepared from Eichhornia. J Chem Technol Biotechnol 77:458–464
Krishnan KA, Sheela A, Anirudhan TS (2003) Kinetic and equilibrium modeling of liquid-phase adsorption of lead and lead chelates on activated carbons. J Chem Technol Biotechnol 78:642–653
Yadav SK, Singh DK, Sinha S (2013) Adsorption study of lead(II) onto xanthated date palm trunk: kinetics, isotherm and mechanism. Desalin Water Treat 51:6798–6807
Pandey PK, Sharma SK, Sambi SS (2015) Removal of lead(II) from waste water on zeolite-NaX. J Environ Chem Eng 3:2604–2610
Govindarao VMH, Froment GF (1986) Voidage profiles in packed beds of spheres. Chem Eng Sci 41:533–539. https://doi.org/10.1016/0009-2509(86)87035-X
R. Chhabra, M.G. Basavaraj, eds., Flow of fluids through granular beds and packed columns, in: Coulson Richardson’s Chem. Eng. Vol. 2A Part. Syst. Part. Technol., 6th ed., Butterworth-Heinemann, 2019: pp. 335–386. https://doi.org/10.1016/b978-0-08-049064-9.50015-1.
Benyahia F, O’Neill KE (2005) Enhanced voidage correlations for packed beds of various particle shapes and sizes. Part Sci Technol 23:169–177. https://doi.org/10.1080/02726350590922242
Wang L, Chen A, Fields K (2000) Arsenic removal from drinking water by ion exchange and activated alumina plants, Cincinnati, Ohio.
Bhardwaj V, Kumar P, Singhal G (2014) Toxicity of heavy metals pollutants in textile mills effluents. Int J Sci Eng Res 5:664–666
Juela D, Vera M, Cruzat C, Alvarez X, Vanegas E (2021) Mathematical modeling and numerical simulation of sulfamethoxazole adsorption onto sugarcane bagasse in a fixed-bed column. Chemosphere 280:130687. https://doi.org/10.1016/j.chemosphere.2021.130687
Danish M, Ansari KB, Aftab RA, Danish M, Zaidi S, Trinh QT (2021) gPROMS-driven modeling and simulation of fixed bed adsorption of heavy metals on a biosorbent: benchmarking and case study. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-021-13207-y
Arim AL, Neves K, Quina MJ, Gando-Ferreira LM (2018) Experimental and mathematical modelling of Cr(III) sorption in fixed-bed column using modified pine bark. J Clean Prod 183:272–281. https://doi.org/10.1016/j.jclepro.2018.02.094
de Freitas GR, Vieira MGA, da Silva MGC (2018) Batch and fixed bed biosorption of copper by acidified algae waste biomass. Ind Eng Chem Res 57:11767–11777
Sotelo JL, Ovejero G, Rodríguez A, Álvarez S, García J (2012) Removal of atenolol and isoproturon in aqueous solutions by adsorption in a fixed-bed column. Ind Eng Chem Res 51:5045–5055
Weber TW, Chakravorti RK (1974) Pore and solid diffusion models for fixed-bed adsorbers. AIChE J 20:228–238
Adeolu AT, Okareh OT, Dada AO (2016) Adsorption of chromium ion from industrial effluent using activated carbon derived from plantain (Musa paradisiaca) wastes. Am J Environ Prot 4:7–20
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Mohd Hardyianto Vai Bahrun: Conceptualization, formal analysis, investigation, writing-original draft preparation. Awang Bono: Supervision, conceptualization, formal analysis, review, and editing. Muhammad Abbas Ahmad Zaini: Supervision, review, and editing. Norasikin Othman: Supervision, review, and editing. Agus Saptoro: Supervision, review, and editing.
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Bahrun, M.H.V., Bono, A., Zaini, M.A.A. et al. Dynamic performances of adsorbents in an industrial-sized packed bed column for lead ion removal. Biomass Conv. Bioref. 14, 11229–11242 (2024). https://doi.org/10.1007/s13399-022-03379-z
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DOI: https://doi.org/10.1007/s13399-022-03379-z