Skip to main content

Advertisement

Log in

Annealed peanut shell biochar as potential reinforcement for aloe vera fiber-epoxy biocomposite: mechanical, thermal conductivity, and dielectric properties

  • Original Article
  • Published:
Biomass Conversion and Biorefinery Aims and scope Submit manuscript

Abstract

The mechanical, thermal conductivity, and dielectric behavior of peanut shell biochar toughened aloe vera fiber–reinforced epoxy resin composites were studied in this present study. The main aim of this research was to study the effect of adding graphitized biochar into the epoxy resin along with aloe vera fiber in load-bearing, thermal, and electrical conductivity properties. To prepare the annealed biochar, peanut shell wastes were first pyrolyzed at 400 °C and subsequently annealed at the temperature range between 1000 and 1050 °C with [Fe(NO3)3] catalyst for about 3 h. The composites were prepared using hand layup method and post cured at elevated temperature. The mechanical, thermal conductivity, and dielectric properties of the composites were analyzed to identify the effectiveness of reinforcements. It is noted that the RAB2 was found to have a highest tensile and flexural strength of 160 and 212 MPa. However, a maximum dosage up to 5vol% in the resin reduced the resin’s load-bearing capacity. It is further noted that the composite material’s thermal conductivity has been enhanced by the addition of biochar. RAB3’s thermal conductivity was found to be the highest at 0.54w/mK. Similarly, the dielectric constant and loss of composite were improved after the addition of biochar particle. The composite designation RAB3 had a maximum constant of 7.2 and a loss of 0.8. These epoxy-based composites with better mechanical, thermal, and dielectric properties could be utilized to make food processing containers and medical device processing equipments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Prakash VR Arun, Viswanthan R (2019) Fabrication and characterization of echinoidea spike particles and kenaf natural fibre-reinforced Azadirachta-Indica blended epoxy multi-hybrid bio composite. Compos A Appl Sci Manuf 118:317–326

    Article  Google Scholar 

  2. Ben Samuel J, Jaisingh SJ, Sivakumar K, Mayakannan AV, Arunprakash VR (2021) Visco-elastic, thermal, antimicrobial and dielectric behaviour of areca fibre-reinforced nano-silica and neem oil-toughened epoxy resin bio composite. Silicon 13(6):1703–1712

    Article  Google Scholar 

  3. Manikandan G, Jaiganesh V, Malarvannan RR, Arun Prakash VR (2021) Mechanical and delamination studies on siliconized chitosan and morinda-citrifolia natural fiber-reinforced epoxy composite in drilling. Polym Compos 42(1):181–190

    Article  Google Scholar 

  4. Tesfaye T, Sithole B, Ramjugernath D (2017) Valorisation of chicken feathers: a review on recycling and recovery route—current status and future prospects. Clean Technol Environ Policy 19(10):2363–2378

    Article  Google Scholar 

  5. Chaitanya S, Singh I (2016) Novel aloe vera fiber reinforced biodegradable composites—development and characterization. J Reinf Plast Compos 35(19):1411–1423

    Article  Google Scholar 

  6. Komal UK, Lila MK, Singh I (2020) PLA/banana fiber based sustainable biocomposites: a manufacturing perspective. Compos Part B Eng 180:107535

    Article  Google Scholar 

  7. Sailesh Ashwin, Arunkumar R, Saravanan S (2018) Mechanical properties and wear properties of Kenaf–aloe vera–jute fiber reinforced natural fiber composites. Materials Today: Proceedings 5(2):7184–7190

    Google Scholar 

  8. Sivasaravanan S, Sangeetha M, Prakash S, Dinesh Reddy T, Prabhudev Rahul D (2019) Experimental investigation of composite material laminated with Aloe vera fiber in different composite resin. Materials Today: Proceedings 16:832–837

    Google Scholar 

  9. Das C, Tamrakar S, Kiziltas A, Xie X (2021) Incorporation of biochar to improve mechanical, thermal and electrical properties of polymer composites. Polymers 13(16):2663

    Article  Google Scholar 

  10. Zhang Q, Cai H, Yi W, Lei H, Liu H, Wang W, Ruan R (2020) Biocomposites from organic solid wastes derived biochars: a review. Materials 13(18):3923

    Article  Google Scholar 

  11. Picard M, Thakur S, Misra M, Mielewski DF, Mohanty AK (2020) Biocarbon from peanut hulls and their green composites with biobased poly (trimethylene terephthalate) (PTT). Sci Rep 10(1):1–14

    Article  Google Scholar 

  12. Rajadurai A (2016) Thermo-mechanical characterization of siliconized E-glass fiber/hematite particles reinforced epoxy resin hybrid composite. Appl Surf Sci 384:99–106

    Article  Google Scholar 

  13. Kumar M, Xiong X, Wan Z, Sun Y, Tsang DCW, Gupta J, Gao B, Cao X, Tang J, Sik Ok Y (2020) Ball milling as a mechanochemical technology for fabrication of novel biochar nanomaterials. Bioresour Technol 312:123613

    Article  Google Scholar 

  14. Thompson E, Danks AE, Bourgeois L, Schnepp Z (2015) Iron-catalyzed graphitization of biomass. Green Chem 17(1):551–556

    Article  Google Scholar 

  15. Neeli ST, Ramsurn H (2018) Synthesis and formation mechanism of iron nanoparticles in graphitized carbon matrices using biochar from biomass model compounds as a support. Carbon 134:480–490

    Article  Google Scholar 

  16. Barnakov Ch N, Khokhlova GP, Popova AN, Sozinov SA, Ismagilov ZR (2015) XRD characterization of the structure of graphites and carbon materials obtained by the low-temperature graphitization of coal tar pitch. Eurasian Chemico-Technological Journal 17(2):87–93

    Article  Google Scholar 

  17. Yan Q, Li J, Zhang X, Hassan EB, Wang C, Zhang J, Cai Z (2018) Catalytic graphitization of kraft lignin to graphene-based structures with four different transitional metals. J Nanoparticle Res 20(9):1–20

    Article  Google Scholar 

  18. Thambiliyagodage CJ, Ulrich S, Araujo PT, Bakker MG (2018) Catalytic graphitization in nanocast carbon monoliths by iron, cobalt and nickel nanoparticles. Carbon 134:452–463

    Article  Google Scholar 

  19. Jayabalakrishnan D, Prabhu P, Iqbal MS, Mugendiran V, Ravi S, Prakash AVR (2021) Mechanical, dielectric, and hydrophobicity behavior of coconut shell biochar toughened Caryota urens natural fiber reinforced epoxy composite. Polym Compos

  20. Jayabalakrishnan D, Saravanan K, Ravi S, Prabhu P, Maridurai T, Prakash VR (2021) Fabrication and characterization of acrylonitrile butadiene rubber and stitched E-glass fibre tailored Nano-silica epoxy resin composite. SILICON 13(8):2509–2517

    Article  Google Scholar 

  21. Prabhahar MJ, Jaisingh J, Prakash AVR (2020) Role of Magnetite (Fe3O4)-Titania (TiO2) hybrid particle on mechanical, thermal and microwave attenuation behaviour of flexible natural rubber composite in X and Ku band frequencies. Mater Res Express 7(1):016106

    Article  Google Scholar 

  22. Tahar M, Prakash VR, Gaoui B, Sebaey TA (2021) Microwave shielding performance of TiO2/Co/GF containing high structure carbon fiber alternate laminate composite. J Mater Sci Mater Electron. 1–16

  23. Rajadurai A (2016) Radio frequency shielding behaviour of silane treated Fe2O3/E-glass fibre reinforced epoxy hybrid composite. Appl Phys A 122(10):1–9

    Google Scholar 

  24. Rajadurai A (2017) Inter laminar shear strength behavior of acid, base and silane treated E-glass fibre epoxy resin composites on drilling process. Defence Technol 13(1):40–46

    Article  MathSciNet  Google Scholar 

  25. Silva H, Ferreira JAM, Costa JDM, Capela C (2013) A study of mixed mode interlaminar fracture on nanoclay enhanced epoxy/glass fiber composites. Ciencia & Tecnologia dos Materiais 25(2):92–97

    Article  Google Scholar 

  26. Burger N, Laachachi A, Ferriol M, Lutz M, Toniazzo V, Ruch D (2016) Review of thermal conductivity in composites: mechanisms, parameters and theory. Prog Polym Sci 61:1–28

    Article  Google Scholar 

  27. Pietrak K, Wiśniewski TS (2015) A review of models for effective thermal conductivity of composite materials. J Power Technol 95(1)

  28. Arun Prakash VR, Rajadurai A (2016) Mechanical, thermal and dielectric characterization of iron oxide particles dispersed glass fiber epoxy resin hybrid composite. Digest J Nanomater Biostruct 11(2):373–80

    Google Scholar 

  29. Merizgui T, Gaoui B, Sebaey TA, Arun Prakash VR (2021) Electromagnetic shielding behavior of epoxy multi-hybrid composites comprises of E-glass fiber, Ag nanoparticle, and Ni nanosheet: a novel approach. Polym Compos 42(5):2484–2491

    Article  Google Scholar 

  30. Antony Vincent V, Kailasanathan C, Ramesh G, Maridurai T, Arun Prakash VR (2021) Fabrication and characterization of hybrid natural fibre-reinforced sandwich composite radar wave absorbing structure for stealth radomes. Trans Electr Electron Mater 22(6):794–802

    Article  Google Scholar 

  31. AmuthaJeevakumari SA, Mothilal T, Ramesh G, Arun Prakash VR (2021) Mechanically toughened EMI shielding natural rubber composite in microwave frequency bands. Plast Rubber Compos 50(5):241–248

    Article  Google Scholar 

  32. Saeed A, Madkhli AY, Al-Dossari M, Abolaban F (2022) Electrical and dielectric properties of composites composed of natural quartz with aluminum. Silicon. 1–15

Download references

Author information

Authors and Affiliations

Authors

Contributions

All authors have equally contributed.

Corresponding author

Correspondence to N. Balaji.

Ethics declarations

Conflict of interest

The authors declare no competing interests.

Additional information

Publisher's note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Balaji, N., Natrayan, L., Kaliappan, S. et al. Annealed peanut shell biochar as potential reinforcement for aloe vera fiber-epoxy biocomposite: mechanical, thermal conductivity, and dielectric properties. Biomass Conv. Bioref. 14, 4155–4163 (2024). https://doi.org/10.1007/s13399-022-02650-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13399-022-02650-7

Keywords

Navigation