Skip to main content
SpringerLink
Log in

Effects of Polyether and Polyester Polyols on the Hydrophobicity and Surface Properties of Polyurethane/Polysiloxane Elastomers

  • Article
  • Published:
Macromolecular Research Aims and scope Submit manuscript

Abstract

Polyurethane (PU) elastomer has been widely used in many fields. In this work, polyurethane/polysiloxane elastomers are synthesized by one-step polymerization using polyether and polyester polyols. The properties of polytetramethylene ether glycol (PTMG) and polycarbonate (PCDL) on polyurethane/polysiloxane elastomers are characterized by various test methods. The results show that PTMG is superior to PCDL in heat resistance and hydrophobicity to polyurethane/polysiloxane elastomers. The heat resistance index of PTMGPU is as high as 154 °C, and its contact angle has reached 115.2°. In addition, the surface of PTMGPU contains more silicone. This may be because the chain structure of PTMG is conducive to the migration of siloxane to the surface, and then a Si-O-Si protective layer is formed, thereby improving the heat resistance and hydrophobicity of the surface of PTMGPU. PCDLPU shows good mechanical properties, which may be related to the stronger chain structure of PCDL. This provides a theoretical basis for the future application of polyurethane/polysiloxane materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Kamaci, Eur. Polym. J., 123, 109444 (2020).

    Article  CAS  Google Scholar 

  2. Y. Zhang, W. Zhang, X. Wang, Q. Dong, X. Zeng, R. L. Quirino, Q. Lu, Q. Wang, and C. Zhang, Prog. Org. Coat., 142, 105588 (2020).

    Article  CAS  Google Scholar 

  3. J. Xiong, Z. Zheng, X. Qin, M. Li, H. Li, and X. Wang, Carbon, 44, 2701 (2006).

    Article  CAS  Google Scholar 

  4. S. H. Park, K. W. Oh, and S. H. Kim, Compos. Sci. Technol., 86, 82 (2013).

    Article  CAS  Google Scholar 

  5. X.-H. Yu, M. R. Nagarajan, T. G. Grasel, P. E. Gibson, and S. L. Cooper, J. Polym. Sci. Part A: Polym. Chem., 23 (1985).

  6. M. Alexandru, M. Cazacu, M. Cristea, A. Nistor, C. Grigoras, and B. C. Simionescu, J. Polym. Sci., Part A: Polym. Chem., 49, 1708 (2011).

    Article  CAS  Google Scholar 

  7. H. Daemi, M. Barikani, and M. Barmar, Carbohydr. Polym., 92, 490 (2013).

    Article  CAS  Google Scholar 

  8. L. T. J. Korley, B. D. Pate, E. L. Thomas, and P. T. Hammond, Polymer, 47, 3073 (2006).

    Article  CAS  Google Scholar 

  9. W. Zhang, X. Zou, X. Liu, Z. Liang, Z. Ge, and Y. Luo, Prog. Org. Coat., 139, 105407 (2020).

    Article  CAS  Google Scholar 

  10. S. Aslnejad, M. Nasiri, F. Abbasi, and H. Abdipour, Macromol. Res., 28, 733 (2020).

    Article  CAS  Google Scholar 

  11. H. Liu, Z. Wang, and C. Sun, Fibers Polym., 19, 580 (2018).

    Article  CAS  Google Scholar 

  12. Z. Ge and Y. Luo, Prog. Org. Coat., 76, 1522 (2013).

    Article  CAS  Google Scholar 

  13. M. V. Pergal, V. V. Antic, G. Tovilovic, J. Nestorov, D. Vasiljevic-Radovic, and J. Djonlagic, J. Biomater. Sci. Polym. Ed., 23, 1629 (2012).

    Article  CAS  Google Scholar 

  14. R. Gallego, J. F. Arteaga, C. Valencia, and J. M. Franco, Chem. Eng. Sci., 134, 260 (2015).

    Article  CAS  Google Scholar 

  15. N. Amirshaqaqi, M. Salami-Kalajahi, and M. Mahdavian, Iran. Polym. J., 23, 699 (2014).

    Article  CAS  Google Scholar 

  16. W. Panwiriyarat, V. Tanrattanakul, J.-F. Pilard, P. Pasetto, and C. Khaokong, J. Appl. Polym. Sci., 130, 453 (2013).

    Article  CAS  Google Scholar 

  17. J. T. Garrett, R. Xu, J. Cho, and J. Runt, Polymer, 44, 2711 (2003).

    Article  CAS  Google Scholar 

  18. C.-A. Xu, Z. Qu, Z. Tan, B. Nan, H. Meng, K. Wu, J. Shi, M. Lu, and L. Liang, Polym. Test., 86, 106485 (2020).

    Article  CAS  Google Scholar 

  19. X. Yang, Y. Guo, X. Luo, N. Zheng, T. Ma, J. Tan, C. Li, Q. Zhang, and J. Gu, Compos. Sci. Technol., 164, 59 (2018).

    Article  CAS  Google Scholar 

  20. N. Ren, Y. Song, C. Tao, B. Cong, Q. Cheng, Y. Huang, G. Xu, and J. Bao, J. Solid State Electrochem., 22, 1109 (2018).

    Article  CAS  Google Scholar 

  21. A. Bahadur, A. Saeed, S. Iqbal, M. Shoaib, M. S. ur Rahman, M. I. Bashir, M. Asghar, M. A. Ali, and T. Mahmood, React. Fund. Polym, 119, 57 (2017).

    Article  CAS  Google Scholar 

  22. M. P. Drupitha, G. B. Nando, and K. Naskar, Eur. Polym. J., 105, 194 (2018).

    Article  CAS  Google Scholar 

  23. P. Król, Ł. Uram, B. Król, K. Pielichowska, and M. Walczak, Mater. Sci. Eng. C: Mater. Biol. Appl., 93, 483 (2018).

    Article  Google Scholar 

  24. Z. Liu, J. Zhang, L. Tang, Y. Zhou, Y. Lin, R. Wang, J. Kong, Y. Tang, and J. Gu, Compos. Part B: Eng., 178, 107466 (2019).

    Article  CAS  Google Scholar 

  25. S. Li, Z. Liu, L. Hou, Y. Chen, and T. Xu, Prog. Org. Coat., 141, 105545 (2020).

    Article  CAS  Google Scholar 

  26. Y. Xia and R. C. Larock, Polymer, 51, 2508 (2010).

    Article  CAS  Google Scholar 

  27. S. A. Kulkami, S. B. Ogale, and K. P. Vijayamohanan, J. Colloid Interface Sci., 318, 372 (2008).

    Article  Google Scholar 

  28. J. Kang, D. Son, G.-J. N. Wang, Y. Liu, J. Lopez, Y. N. Kim, J. Y. Oh, T. Katsumata, J. Mun, Y. Lee, L. Jin, J. B-H Tok, and Z. Bao, Adv. Mater., 30, e1706846 (2018).

    Article  Google Scholar 

  29. J. Bao, G. Shi, C. Tao, C. Wang, C. Zhu, L. Cheng, G. Qian, and C. Chen, J. Power Sources, 389, 84 (2018).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, 510650, P. R. China

    Chang-An Xu, Mangeng Lu, Kun Wu & Jun Shi

  2. University of Chinese Academy of Sciences, Beijing, 100049, P. R. China

    Chang-An Xu, Mangeng Lu, Kun Wu & Jun Shi

  3. Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou, 510650, P. R. China

    Chang-An Xu, Mangeng Lu, Kun Wu & Jun Shi

  4. CAS Engineering Laboratory for Special Fine Chemicals, Guangzhou, 510650, P. R. China

    Chang-An Xu, Mangeng Lu, Kun Wu & Jun Shi

  5. CASH GCC Research Institute of New Materials Co., Ltd, Nanxiong, 512400, P. R. China

    Mangeng Lu

Authors
  1. Chang-An Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mangeng Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kun Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jun Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mangeng Lu.

Additional information

Publisher’s Note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Acknowledgment: We sincerely acknowledged the financial supports from Key Technologies Research and Development Program, China (2017YFD0601003).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, CA., Lu, M., Wu, K. et al. Effects of Polyether and Polyester Polyols on the Hydrophobicity and Surface Properties of Polyurethane/Polysiloxane Elastomers. Macromol. Res. 28, 1032–1039 (2020). https://doi.org/10.1007/s13233-020-8138-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13233-020-8138-5

Keywords

Search

Navigation