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Preparation and Properties of Halogen-Free Flame Retardant and High Refractive Index Optical Resin via Click Chemistry

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Abstract

Halogen-free flame retardant tri(acryloyloxyethyl) phosphate (TAEP) optical resin was prepared using hydroxy ethyl acrylate (HEA) and phosphorus oxychloride and the chemical structure was characterized by Fourier transform infrared spectrometer and proton nuclear magnetic resonance spectrometer. Optical resins mixed by pentaerythritol tetrathioglycolic and TAEP with different S and P contents were obtained via click chemistry curing. The curing performance, thermal stability and flame retardant performance of the optical resins were analyzed by differential scanning calorimeter, thermogravimetric analyzer, and vertical burning tester, respectively. Additionally, the burned residual morphology of samples was investigated by scanning electronic microscopy, and the refractive indices of the optical resins were measured by an Abbe refractometer. The results revealed that increasing S content could improve the refractive indices of the resins; whereas, the flame retardant performances decreased. The optical resins with S content of 2% and P contents of 7.37% had refractive indices of 1.4935 and UL 94 V-0 flame retard level, respectively. The optical resins had good thermal stability and the 5% decomposition temperature reached up to 200.1 °C.

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Authors and Affiliations

  1. Polymer and Fine Chemicals Technology Development Center, Shenzhen Polytechnic, Shenzhen, P. R. China

    Chaoyun Luo & Feng Lin

  2. The Key Laboratory of Polymer Processing Engineering, Ministry of Education, South China University of Technology, Guangzhou, P. R. China

    Chaoyun Luo & Jianqing Zhao

  3. College of Materials Science and Engineering, Guangdong Research Center for Interfacial Engineering of Functional Materials, Shenzhen University, Shenzhen, P. R. China

    Jiandong Zuo

  4. College of Materials Science and Engineering, South China University of Technology, Guangzhou, P. R. China

    Fuquan Wang, Yanchao Yuan & Jianqing Zhao

Authors
  1. Chaoyun Luo
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  2. Jiandong Zuo
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  3. Fuquan Wang
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  4. Yanchao Yuan
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  5. Feng Lin
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  6. Jianqing Zhao
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Corresponding author

Correspondence to Jiandong Zuo.

Additional information

Acknowledgments: This work was supported by the National Natural Science Foundation of China (Grant Nos. U1201243, 51273221, and 51173047); the Opening Project of The Key Laboratory of Polymer Processing Engineering, Ministry of Education, China (KFKT-201404); and the Shenzhen Science and Technology Foundation Research Grant (JCYJ 20150327145230372).

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Luo, C., Zuo, J., Wang, F. et al. Preparation and Properties of Halogen-Free Flame Retardant and High Refractive Index Optical Resin via Click Chemistry. Macromol. Res. 26, 346–352 (2018). https://doi.org/10.1007/s13233-018-6045-8

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  • DOI: https://doi.org/10.1007/s13233-018-6045-8

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