Skip to main content
Log in

Characteristics and anti-toxicity analysis of Fe–Cu13x catalytic oxidation of NO at low temperature and its application in industry

  • Original article
  • Published:
International Journal of System Assurance Engineering and Management Aims and scope Submit manuscript

Abstract

The Fe–Cu13x molecular sieve catalyst was synthesized by ion exchange method. The product is having various applications, mainly within the food industry, agriculture industry, and also within the pharmaceutical industry. The denitration characteristics and anti-toxicity of Fe–Cu13x catalyst were investigated. Combined with a variety of characterization methods, it was found that the denitration performance of the catalyst was superior, and the denitration rate was more than 99%. In the subsequent anti toxicity test, Fe Cu catalyst showed good sulfur resistance. The NOx conversion rate of the catalyst remained above 90% after 3 h of sulphur resistance, while the no and removal efficiency decreased to 60% after 4 h of sulfur resistance. After the sulfur supply was stopped, the conversion rate did not increase and showed a gradual deactivation state. When the temperature increased to 400 °C, the catalyst could still maintain more than 95% NOx removal rate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Source: INI 2019

Fig. 2

Source: Erisman et al. 2011

Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Barreau M, Tarot ML, Duprez D, Courtois X, Can F (2018) Remarkable enhancement of the selective catalytic reduction of NO at low temperature by collaborative effect of ethanol and NH3 over silver supported catalyst. Appl Catal B Environ S0926337317307518

  • Chakraborty C, Gupta B, Ghosh SK, Das DK, Chakraborty C (2016) Telemedicine supported chronic wound tissue prediction using classification approaches. J Med Syst 40(3). https://doi.org/10.1007/s10916-015-0424-y

  • Chen X, Chen M, He G, Wang F, He H (2018) Specific role of potassium in promoting ag/al 2 o 3 for catalytic oxidation of formaldehyde at low temperature. J Phys Chem C 122(48)

  • Chen X, Chen M, He G, Wang F, He H (2018) Specific role of potassium in promoting Ag/Al2O3 for catalytic oxidation of formaldehyde at low temperature. J Phys Chem C 122(48)

  • Deng J, Chen S, Yao N, Wang Q, Li J, Wei Z (2020) Integrating H2 generation with sewage disposal by an efficient anti-poisoning bifunctional electrocatalyst. Appl Catal B Environ 277:119175

  • Gao X, Du X, Liu D, Gao H, Wang P, Yang J (2020) Core-shell gold-nickel nanostructures as highly selective and stable nonenzymatic glucose sensor for fermentation process. Sci Rep 10(1):1–10

    Article  Google Scholar 

  • Georgescu C, Solea LC, Deleanu L (2019) Additivation of vegetal oils for improving tribological characteristics. In: IOP conference series: materials science and engineering (vol 514, no 1, p 012012). IOP Publishing

  • Guo R, Wang J, An S, Zhang J, Zhou G, Guo L (2020) Effect of cerium oxide prepared under different hydrothermal time on electrocatalytic performance of Pt-based anode catalysts. J Rare Earths 38(4):384–394

    Article  Google Scholar 

  • Gupta A, Chakraborty C, Gupta B (2019) Medical information processing using smartphone under IoT framework. In: Energy conservation for IoT devices (pp 283–308). Springer Singapore. https://doi.org/10.1007/978-981-13-7399-2_12

  • Herawati H, Oktanella Y, Anisa AK (2021) Molecular docking analysis of curcuminoids from curcuma longa extract on inos as an immunomodulator candidate in broilers. Adv Anim Vet Sci 9(4):519–524

    Article  Google Scholar 

  • Kaewbuddee C, Kidkhunthod P, Chanlek N, Khunphonoi R, Wantala K (2019) Chemical surface analysis on post-thermal treatment of the k-oms-2 catalysts and catalytic oxidation efficiency at low temperature. Sains Malaysiana 48(7):1447–1457

    Article  Google Scholar 

  • Lei Z, Hao S, Zhang L, Yang J, Yusu W (2020) MnOx-CuOx cordierite catalyst for selective catalytic oxidation of the NO at low temperature. Environ Sci Pollut Res 27(19):23695–23706

    Article  Google Scholar 

  • Liu Y, Li Z, Xu S, Xie Y, Ye Y, Zou X, Lin S (2019) Synthesis of Pt-Ni (trace)/GNs composite and its bi-functional electrocatalytic properties for MOR and ORR. J Colloid Interface Sci 554:640–649

    Article  Google Scholar 

  • Manne R, Kantheti S (2020) COVID-19 and its impact on air pollution. Int J Res Appl Sci Eng Technol (IJRASET) 08(11):344–346

  • Muthu Rama Krishnan M, Banerjee S, Chakraborty C, Chakraborty C, Ray AK (2010) Statistical analysis of mammographic features and its classification using support vector machine. Expert Syst Appl 37(1):470–478. https://doi.org/10.1016/j.eswa.2009.05.045

    Article  Google Scholar 

  • Pei A, Ruan L, Liu B, Chen W, Lin S, Chen B, Liu Y, Zhu LH, Chen BH (2020) Ultra-low Au decorated PtNi alloy nanoparticles on carbon for high-efficiency electro-oxidation of methanol and formic acid. Int J Hydrogen Energy 45(43):22893–22905

    Article  Google Scholar 

  • Peng K, Bhuvanendran N, Ravichandran S, Zhang W, Ma Q, Xing L, Xu Q, Khotseng L, Su H (2020) Carbon supported PtPdCr ternary alloy nanoparticles with enhanced electrocatalytic activity and durability for methanol oxidation reaction. Int J Hydrogen Energy 45(43):22752–22760

    Article  Google Scholar 

  • Rajesh D, Mahendiran C, Suresh C, Pandurangan A, Maiyalagan T (2019) Hydrothermal synthesis of three dimensional reduced graphene oxide-multiwalled carbon nanotube hybrids anchored with palladium-cerium oxide nanoparticles for alcohol oxidation reaction. Int J Hydrogen Energy 44(10):4962–4973

    Article  Google Scholar 

  • Rezaee-Khorasany A, Razavi BM, Taghiabadi E, Yazdi AT, Hosseinzadeh H (2019) Effect of saffron (stigma of Crocus sativus L.) aqueous extract on ethanol toxicity in rats: A biochemical, histopathological and molecular study. J Ethnopharmacol 237:286–299

    Article  Google Scholar 

  • Shao W, Ebaid R, El-Sheekh M, Abomohra A, Eladel H (2019) Pharmaceutical applications and consequent environmental impacts of Spirulina (Arthrospira): an overview. Grasas Aceites 70(1):292

    Article  Google Scholar 

  • Tao W, Xinyu Z, Jun L, Hanzi L, Yonghong G, Baomin S (2018) Plasma-assisted catalytic conversion of no over cu-fe catalysts supported on zsm-5 and carbon nanotubes at low temperature. Fuel Process Technol 178:53–61

    Article  Google Scholar 

  • Velásquez F, Espitia J, Mendieta O, Escobar S, Rodríguez J (2019) Non-centrifugal cane sugar processing: A review on recent advances and the influence of process variables on qualities attributes of final products. J Food Eng 255:32–40

    Article  Google Scholar 

  • Wang H, Qu Z, Xie H, Maeda N, Miao L, Wang Z (2016) Insight into the mesoporous FexCe1−xO2−δ catalysts for selective catalytic reduction of NO with NH3: regulable structure and activity. J Catal 338:56–67

    Article  Google Scholar 

  • Wang W, Guo R, Pan W, Hu G (2018) Low temperature catalytic oxidation of no over different-shaped ceo 2. J Rare Earths S1002072117301424

  • Wang Q, Wang X, Wang L, Hu Y, Ning P, Ma Y et al (2019a) Catalytic oxidation and hydrolysis of hcn over laxcuy/tio2 catalysts at low temperatures. Microporous Mesoporous Mater 282:260–268

    Article  Google Scholar 

  • Wang Q, Xu H, Huang W, Pan Z, Zhou H (2019) Metal organic frameworks-assisted fabrication of CuO/Cu2O for enhanced selective catalytic reduction of NOx by NH3 at low temperatures. J Hazardous Mater 364(FEB.15):499–508

  • Wang SQ, Li JM, Liu WB (2020a) Effect of F, V and Mn co-doping on the catalytic performance of TiO2-pillared bentonite in the photocatalytic denitration. J Fuel Chem Technol 48(9):1131–1139

    Article  Google Scholar 

  • Wang D, Xia Y, Lv H, Miao L, Bi L, Liu W (2020b) PrBaCo2-xTaxO5+ δ based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance. Int J Hydrogen Energy 45(55):31017–31026

    Article  Google Scholar 

  • Wu Z, Zeng Y, Song F, Zhang S, Zhong Q (2019) Active sites assembly effect on CeO2–WO3–TiO2 catalysts for selective catalytic reduction of NO with NH3. Mol Catal 479:110549

  • Xiong S, Peng Y, Wang D, Huang N, Zhang Q, Yang S, Chen J, Li J (2020) The role of the Cu dopant on a Mn3O4 spinel SCR catalyst: improvement of low-temperature activity and sulfur resistance. Chem Eng J 387:124090

  • Yao Z, Qu D, Guo Y, Yang Y, Huang H (2019) Fabrication and characteristics of mn@ cu 3 (btc) 2 for low-temperature catalytic reduction of no x with nh 3. Adv Mater Sci Eng 2019:1–9

    Google Scholar 

  • Zhang W, Rhodes JS, Garg A, Takemoto JY, Qi X, Harihar S, Zhou A (2020) Label-free discrimination and quantitative analysis of oxidative stress induced cytotoxicity and potential protection of antioxidants using Raman micro-spectroscopy and machine learning. Anal Chim Acta 1128:221–230

    Article  Google Scholar 

  • Zhu J, Zhang W, Qi Q, Zhang H, Zhang Y, Sun D, Liang P (2019) Catalytic oxidation of toluene, ethyl acetate and chlorobenzene over Ag/MnO2-cordierite molded catalyst. Sci Rep 9(1):1–10

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Deepika Koundal.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest and all ethical issues including human or animal participation has been done. No such consent is applicable.

Funding

This research work is self-funded.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hu, C., Amurishana, Wu, S. et al. Characteristics and anti-toxicity analysis of Fe–Cu13x catalytic oxidation of NO at low temperature and its application in industry. Int J Syst Assur Eng Manag 13 (Suppl 1), 166–174 (2022). https://doi.org/10.1007/s13198-021-01332-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13198-021-01332-3

Keywords

Navigation