Skip to main content

Advertisement

Log in

Changes in the hydrochemistry of a karstic lake in Yucatan, Mexico

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

The Yucatan Peninsula is a karstic region with groundwater-dependent ecosystems and geological features such as karstic lakes. The objective of this research was to calculate the volume of water stored in this section of the aquifer and to describe the changes in the hydrochemistry of the lake Punta Laguna as a representative of karstic lakes in the Yucatan Peninsula. A bathymetry and calculation of the volume of water stored in the lake resulted in 5,198,505 m3 with a maximum depth measured of 26.6 m Physicochemical measurements were completed in surface and three vertical profiles to estimate the mass of nutrients and ions and to describe the current hydrochemistry. The lake is an oligotrophic one of mixed-typed water (chloride-calcium/magnesium), saturated or supersaturated with calcite, dolomite and aragonite due to limestone dissolution. No evidence obtain regarding the saline intrusion. The conclusion that we can derive from the data is that Punta Laguna is a tropical karstic lake in good condition with low anthropogenic influence, evolving hydrochemically speaking. The changes over a 20-year period suggest that there has been reverse ion exchange, evaporation and sulfate reduction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Reproduced from Giménez-Forcada (2010)

Similar content being viewed by others

References

  • Alfarrah N, Walraevens K (2018) Groundwater overexploitation and seawater intrusion in coastal areas of arid and semi-arid regions. Water 10(2):143

    Google Scholar 

  • Aguilar Y, Bautista F, Mendoza ME, Frausto O, Ihl T (2016) Density of karst depressions in Yucatán state, Mexico. J Cave Karst Stud 78:51

    Google Scholar 

  • Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. Bakelma Publishers, Great Britain

    Google Scholar 

  • Askri B, Ahmed AT, Al-Shanfari RA, Bouhlila R, Al-Farisi KBK (2016) Isotopic and geochemical identifications of groundwater salinisation processes in Salalah coastal plain, Sultanate of Oman. Geochemistry 76:243–255

    Google Scholar 

  • Bauer-Gottwein P, Gondwe BR, Charvet G, Marín LE, Rebolledo-Vieyra M, Merediz-Alonso G (2011) The Yucatán Peninsula karst aquifer, Mexico. Hydrogeol J 19:507–524

    Google Scholar 

  • Baup F, Frappart F, Maubant J (2014) Combining high-resolution satellite images and altimetry to estimate the volume of small lakes. Hydrol Earth Syst Sci 18:2007–2020

    Google Scholar 

  • Bottrell S, Webber N, Gunn J, Worthington S (2000) The geochemistry of sulphur in a mixed allogenic–autogenic karst catchment, Castleton, Derbyshire, UK. Earth Surf Proc Land 25:155–165

    Google Scholar 

  • Bower CE, Holm-Hansen T (1980) A salicylate–hypochlorite method for determining ammonia in seawater. Can J Fish Aquat Sci 37:794–798

    Google Scholar 

  • Cao X, Wu P, Zhou S, Sun J, Han Z (2018) Tracing the origin and geochemical processes of dissolved sulphate in a karst-dominated wetland catchment using stable isotope indicators. J Hydrol 562:210–222

    Google Scholar 

  • Cervantes-Martínez A, Elías-Gutiéerrez M, Suárez-Morales E (2002) Limnological and morphometrical data of eight karstic systemscenotes' of the Yucatan Peninsula, Mexico, during the dry season (February–May, 2001). Hydrobiologia 482:167–177

    Google Scholar 

  • Cervantes-Martínez A, Mezeta-Barrera M, Gutiérrez-Aguirre MA (2009) Limnología básica del lago cárstico turístico Cenote Azul en Quintana Roo, México. Hidrobiológica 19:177–180

    Google Scholar 

  • Charlton M (1980) Hypolimnion oxygen consumption in lakes: discussion of productivity and morphometry effects. Can J Fish Aquat Sci 37:1531–1539

    Google Scholar 

  • Curtis JH, Hodell DA, Brenner M (1996) Climate variability on the Yucatan Peninsula (Mexico) during the past 3500 years, and implications for Maya cultural evolution. Quatern Res 46:37–47

    Google Scholar 

  • Custodio E, Llamas MR (2001) Hidrología subterránea, 2nd edn. Omega, Barcelona

    Google Scholar 

  • DOF Diario Oficial de la Federación (2002) Decreto por el que se declara área natural protegida, con la categoría de Área de Protección de Flora Y Fauna, la región conocida como Otoch Ma’ax Yetel Kooh, localizada en los municipios de Valladolid, en el Estado de Yucatán y Solidaridad, en el Estado de Quintana Roo. Diario Oficial de la Federación. México, D.F (Junio 5)

  • DOF Diario Oficial de la Federación (2009) Programa de Manejo del Área de Protección de Flora y Fauna Otoch Ma’ax Yetel Kooh, localizada en los municipios de Valladolid, en el Estado de Yucatán y Solidaridad, en el Estado de Quintana Roo. Diario Oficial de la Federación. México, D.F (Octubre 27)

  • Drever JI (1988) The geochemistry of natural waters, 2nd edn. Prentice Hall, New Jersey

    Google Scholar 

  • Escobar J, Curtis JH, Brenner M, Hodell DA, Holmes JA (2010) Isotope measurements of single ostracod valves and gastropod shells for climate reconstruction: evaluation of within-sample variability and determination of optimum sample size. J Paleolimnol 43:921–938

    Google Scholar 

  • Fratesi B (2013) Hydrology and geochemistry of the freshwater lens in coastal karst. In: Lace M, Mylroie J (eds) Coastal karst landforms, vol 5. Coastal Research Library, Springer, Dordrecht. pp 59–75

    Google Scholar 

  • García-Frapolli E, Ayala-Orozco B, Bonilla-Moheno M, Espadas-Manrique C, Ramos-Fernández G (2007) Biodiversity conservation, traditional agriculture and ecotourism: Land cover/land use change projections for a natural protected area in the northeastern Yucatan Peninsula, Mexico. Landscape Urban Plan 83:137–153

    Google Scholar 

  • Giménez-Forcada E (2010) Dynamic of sea water interface using hydrochemical facies evolution diagram. Groundwater 48:212–216

    Google Scholar 

  • Gutiérrez R (2008) Compilation and production of a karst map of Mexico. American Geophysical Union, Fall Meeting 2008, abstract #H21D-0854

  • Hartmann A, Goldscheider N, Wagener T, Lange J, Weiler M (2014) Karst water resources in a changing world: Review of hydrological modeling approaches. Rev Geophys 52:218–242

    Google Scholar 

  • Hodell DA, Brenner M, Curtis JH (2007) Climate and cultural history of the northeastern Yucatan Peninsula, Quintana Roo, Mexico. Clim Change 83:215–240

    Google Scholar 

  • Hollister J, Milstead WB (2010) Using GIS to estimate lake volume from limited data. Lake Reserv Manag 26:194–199

    Google Scholar 

  • INEGI—Instituto Nacional de Estadística y Geografía (2002) Estudio Hidrológico del Estado de Yucatán https://internet.contenidos.inegi.org.mx/contenidos/productos/prod_serv/contenidos/espanol/bvinegi/productos/historicos/2104/702825224165/702825224165.pdf. Accessed 15 February 2018

  • INEGI—Instituto Nacional de Estadística y Geografía. (2017). ‘Anuario estadístico y geográfico de Yucatán 2017’. https://www.datatur.sectur.gob.mx/ITxEF_Docs/YUC_ANUARIO_PDF.pdf. Accessed 22 March 2018

  • Kambesis PN, Coke JG (2013) Overview of the controls on eogenetic cave and karst development in Quintana Roo, Mexico. In: Lace M, Mylroie J (eds) Coastal karst landforms. Coastal research library, vol 5. Springer, Dordrecht, pp 347–373

    Google Scholar 

  • Kasper-Zubillaga JJ, Arellano-Torres E, Armstrong-Altrin JS, Sial AN (2017) A study of carbonate beach sands from the Yucatan Peninsula, Mexico: a case study. Carbonates Evaporites 32(1):1–12

    Google Scholar 

  • Kelley K, Mylroie JE, Mylroie JR, Moore C, Moore P, Collins L, Ersek L, Lascu I, Roth M, Passion R (2006b) Eolianites and karst development in the Mayan Riviera, Mexico. In: Proceedings of the 12th symposium on the geology of the bahamas and other carbonate regions, Gerace Research Center, Bahamas, pp 88–99

  • Kresic N (2013) Water in karst: management, vulnerability and restoration. McGraw-Hill, New York, USA

    Google Scholar 

  • Ma R, Wang Y, Sun Z, Zheng C, Ma T, Prommer H (2011) Geochemical evolution of groundwater in carbonate aquifers in Taiyuan, northern China. Appl Geochem 26:884–897

    Google Scholar 

  • Massmann G, Tichomirowa M, Merz C, Pekdeger A (2003) Sulfide oxidation and sulfate reduction in a shallow groundwater system (Oderbruch Aquifer, Germany). J Hydrol 278:231–243

    Google Scholar 

  • NOM-127-SSA1-1994 (1994) Norma Oficial Mexicana, Salud ambiental, agua para uso y consumo humano—límites permisibles de calidad y tratamientos a que debe someterse el agua para su potabilización

  • OECD-Organisation for Economic Co-Operation and Development (1982) Eutrophication of waters. Monitoring, Assessment and Control, Paris

    Google Scholar 

  • Pérez L, Bugja R, Lorenschat J, Brenner M, Curtis J, Hoelzmann P, Islebe G, Scharf B, Schwalb A (2011) Aquatic ecosystems of the Yucatan peninsula (Mexico), Belize, and Guatemala. Hydrobiologia 661:407–433

    Google Scholar 

  • Perry E, Velazquez-Oliman G, Marin L (2002) The hydrogeochemistry of the karst aquifer system of the northern Yucatan Peninsula, Mexico. Int Geol Rev 44:191–221

    Google Scholar 

  • Pinacho-Guendulain B, Ramos-Fernández G (2017) Influence of fruit availability on the fission–fusion dynamics of spider monkeys (Ateles geoffroyi). Int J Primatol 38:466–484

    Google Scholar 

  • Polk JS, Brinkmann R (2013) Climatic influences on coastal cave and karst development in Florida. In: Lace M, Mylroie J (eds) Coastal karst landforms, vol 5. Coastal Research Library, Springer, Dordrecht, pp 317–345

    Google Scholar 

  • Sironić A, Barešić J, Horvatinčić N, Brozinčević A, Vurnek M, Kapelj S (2017) Changes in the geochemical parameters of karst lakes over the past three decades—the case of Plitvice Lakes, Croatia. Appl Geochem 78:12–22

    Google Scholar 

  • Strickland JD, Parsons TR (1972) A practical handbook of seawater analysis, 2nd edn. Fisheries Research Board of Canada, Bulletin 167, Ottawa, Canada

    Google Scholar 

  • Taminskas J, Marcinkevicius V (2002) Karst geoindicators of environmental change: the case of Lithuania. Environ Geol 42:757–766

    Google Scholar 

  • Torrescano-Valle N, Folan WJ (2015) Physical settings, environmental history with an outlook on global change. In: Islebe G, Calmé S, León-Cortés J, Schmook B (eds) Biodiversity and conservation of the Yucatán Peninsula. Springer, Cham

    Google Scholar 

  • Turekian KK (1968) Oceans. Prentice Hall, New Jersey

    Google Scholar 

  • USEPA—United States Environmental Protection Agency (1978) Method 365.3: Phosphorous, All Forms (Colorimetric, Ascorbic Acid, Two Reagent). https://www.epa.gov/sites/production/files/2015-08/documents/method_365-3_1978.pdf. Accessed 20 October 2017

  • Valero-Garcés B, Morellón M, Moreno A, Corella JP, Martín-Puertas C, Barreiro F, Pérez A, Giralt S, Mata-Campo MP (2014) Lacustrine carbonates of Iberian Karst Lakes: sources, processes and depositional environments. Sed Geol 299:1–29

    Google Scholar 

  • Villasuso MJ, Ramos RM (2000) A conceptual model of the aquifer of the Yucatan Peninsula. Research Report-International Institute for Applied Systems Analysis IIASA RR:120–139

  • Whitmore TJ, Brenner M, Curtis JH, Dahlin BH, Leyden BW (1996) Holocene climatic and human influences on lakes of the Yucatan Peninsula, Mexico: an interdisciplinary, palaeolimnological approach. Holocene 6:273–287

    Google Scholar 

  • Williamson CE, Brentrup JA, Zhang J, Renwick WH, Hargreaves BR, Knoll LB, Overholt EP, Rose KC (2014) Lakes as sensors in the landscape: optical metrics as scalable sentinel responses to climate change. Limnol Oceanogr 59:840–850

    Google Scholar 

  • Yamanaka M, Nakano T, Tase N (2007) Sulfate reduction and sulfide oxidation in anoxic confined aquifers in the northeastern Osaka Basin, Japan. J Hydrol 335:55–67

    Google Scholar 

  • Zhang Y, Wu Z, Liu M, He J, Shi K, Zhou Y, Wang M, Liu X (2015) Dissolved oxygen stratification and response to thermal structure and long-term climate change in a large and deep subtropical reservoir (Lake Qiandaohu, China). Water Res 75:249–258

    Google Scholar 

Download references

Acknowledgements

This study was carried out with support from CONACYT (National Research and Technology Council of Mexico), Catedras CONACYT Project 2944—Modelación del ciclo el agua en la Peninsula de Yucatan [Water cycle modelling in the Yucatan Peninsula]. Thanks to the staff in the Protected Area Otoch Ma’ax Yetel Kooh Jazmín Montero, Andrés Cen Ma and Elena García (CONANP) and providers of tourist services of the Najil Tucha cooperative. Research was carried out with funds from the agreement of the National Protected Areas Commission CONANP/PROCODES/6687/2017 (Mexico). We are grateful to Cinthya D. Grimaldo, for her help with laboratory analyses. Cecilia Hernández and Victor Carrillo shared unpublished information on chlorophyll. Álvaro Hernández and Alejandro Carmona for their help in fieldwork.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Eduardo Cejudo.

Ethics declarations

Conflict of interest

The authors declare no conflicts of interest

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 206 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cejudo, E., Acosta-González, G., Ortega-Camacho, D. et al. Changes in the hydrochemistry of a karstic lake in Yucatan, Mexico. Environ Earth Sci 79, 98 (2020). https://doi.org/10.1007/s12665-020-8838-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12665-020-8838-3

Keywords

Navigation