Abstract
Fourteen water and sediment samples were collected from the Nakdong River Basin in Korea to evaluate the physico-chemical parameters (pH, dissolved oxygen, chemical oxygen demand, biological oxygen demand, total organic carbon) in water and total heavy metals (Cu, Zn, Pb, Cd, As) in surface sediments. The assessment of physico-chemical parameters indicates that river water and sediments in the study area were strongly impacted by industrial wastewater, irrigational effluents and domestic sewage. The overall average concentrations of metals in sediments were Cu (6.41 mg/kg), Cd (0.11 mg/kg), Pb (4.72 mg/kg), Zn (16.8 mg/kg), As (0.19 mg/kg), and the order of the concentrations was Zn > Cu > Pb > As > Cd. Geo-accumulation index (I geo) indicates that most of samples fall at unpolluted to medium category, while contamination factor values fall at the medium to very high pollution zone. Pollution load index also suggests that all samples fall at progressive pollution sector. Multivariate statistical analysis and pollution index methods were helpful for the classification on the basis of the contamination sources and origin of heavy metals. In conclusion, this study clearly infers the fact that the cause of metal pollution in this region is mainly due to the effluents discharged from factories, agricultural fields and sewers.
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Adamo P, Zampella M, Gianfreda L, Renella G, Rutigliano FA, Terribile F (2006) Impact of river overflowing on trace element contamination of volcanic soils in south Italy: part I. Trace element speciation in relation to soil properties. Environ Pollut 144:308–316
American Public Health Association (APHA) (1995) Standard methods for the examination of water and waste water, 19th edn. Public Health Association, Washington
Anithamary I, Ramkumar T, Venkatramanan S (2012) Distribution and accumulation of metals in the surface sediments of Coleroon River estuary, east coast of India. Bull Environ Contam Toxicol 88:413–417
Anithamary I, Ramkumar T, Venkatramanan S, Vasudevan S (2013) Assessment of heavy metal concentrations in surface sediments of Coleroon estuary of Tamilnadu, east coast of India. Carpathian J Earth Environ Sci 8:39–46
Astel A, Tsakovski S, Barbieri P, Simeonov V (2007) Comparison of self-organizing maps classification approach with cluster and principal components analysis for large environmental data sets. Water Res 41:4566–4578
Astel A, Tsakovski S, Simeonov V, Reisenhofer E, Piselli S, Barbieri P (2008) Multivariate classification and modeling in surface water pollution estimation. Anal Bioanal Chem 390:1283–1292
Ayyamperumal T, Jonathan MP, Srinivasalu S, Armstrong-Altrin JS, Ram-Mohan V (2006) Assessment of acid leachable trace metals in sediment cores from River Uppanar, Cuddalore, South east coast of India. Environ Pollut 143:34–45
Bryan GW, Langston WJ (1992) Bioavailability, accumulation and effects of heavy metals in sediments with special reference to United Kingdom estuaries: a review. Environ Pollut 76:89–131
Buccolieri A, Buccolieri G, Cardellicchio N, Atti AD, Leo AD, Maci A (2006) United States Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy). Mar Chem 99:227–235
Caboi R, Cidu R, Fanfani L, Lattanzi P, Zuddas P (1999) Environmental mineralogy and geochemistry of the abandoned Pb–Zn Montevecchio-Ingurtosu mining district, Sardinia, Italy. Chron Rech Min 534:21–28
Chun KC, Chang RW, Williams GP, Chang YS, Tomasko D, LaGory K, Ditmars J, Chun HD, Lee BK (2001) Water quality issues in the Nakdong River Basin in the Republic of Korea. Environ Eng Policy 2:131–143
Ficklin DJ, Plumee GJ, Smith KS, McHugh JB (1992) Geo-chemical classification of mine drainages and natural drainages in mineralized areas. In: Kharaka YK, Maest AS (eds) Water– rock interaction, vol 7. Balkema, Rotterdam, pp 381–384
Fukushima K, Saino T, Kodama Y (1992) Trace metal contamination in Tokyo Bay. Jpn Sci Total Environ 125:373–389
Gotelli NJ, Ellison AM (2004) A primer of ecological statistics, 1st edn. Sinauer Associates, Sunderland, p 492
Hokanson L (1980) Ecological risk index for aquatic pollution control, a sedimentological approach. Water Res 14:975–1001
Holloway JM, Dahlgren RA, Hansen B, Casey WH (1998) Contribution of bedrock nitrogen to high nitrate concentrations in stream water. Nature 395:785–788
Hongyi NIU, Wenjing D, Qunhe WU, Xingeng C (2009) Potential toxic risk of heavy metals from sediment of the Pearl River in South China. J Environ Sci 21:1053–1058
Howitt D, Cramer D (2005) Introduction to SPSS in psychology: with supplement for releases 10, 11, 12 and 13. Pearson, Harlow
Imperato M, Adamo P, Naimo D, Arienzo M, Stanzione D, Violante P (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy). Environ Pollut 124:247–256
Iticescu C, Georgescu LP, Topa CM (2013) Assessing the Danube water quality index in the city of Galati, Romania. Carpathian J Earth Environ Sci 8:155–164
Jayaprakash M, Jonathan MP, Srinivasalu S, Muthuraj S, Ram-Mohan V, Rajeshwara-Rao N (2007) Acid-leachable trace metals in sediments from an industrialized region (Ennore Creek) of Chennai city, SE coast of India: an approach towards regular monitoring. Estuar Coast Shelf Sci 76:692–703
Jonathan MP, Ram Mohan V, Srinivasalu S (2004) Geochemical variations of major and trace elements in recent sediments, off the Gulf of Mannar, the southeast coast of India. Environ Geol 45:466–480
Jonathan MP, Roy PD, Rodriguez-Espinosa PF, Sarkar SK, Munoz-Sevilla NP, Navarrete-Lopaz M, Srinivasalu S, Thangadurai N (2013) Evaluation of trace elements concentration (acid leachable) in sediments from River Panuco and its adjacent lagoon areas, NE Mexico. Environ Earth Sci 68:2239–2252
Krishna AK, Satyanarayanan M, Govil PK (2009) Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area: a case study from Patancheru, Medak District, Andhra Pradesh, India. J Hazard Mater 167:366–373
Le Cloarec MF, Bonte PH, Lestel L, Lefevre L, Ayrault S (2009) Sedimentary record of metal contamination in the Seine River during the last century. Phys Chem Earth 36:515–529
Li S, Xu Z, Cheng X, Zhang Q (2008) Dissolved trace elements and heavy metals in the Danjiangkou Reservoir, China. Environ Geol 55:977–983
Long ER, MacDonald DD, Smith SL, Calder FD (1995) Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments. Environ Manage 19:81–97
Lu S, Wang H, Bai S (2009) Heavy metal contents and magnetic susceptibility of soils along an urban-rural gradient in rapidly growing city of eastern China. Environ Monit Assess 58:91–101
Mendil D, Unal TF, Tuzen M, Soylak M (2010) Determination of trace metals in different fish species and sediments from the River Yeşilirmak in Tokat, Turkey. Food Chem Toxicol 48:1383–1392
Ministry of Construction and Transportation (1998) An investigation on the status of Nakdong River water utilization. Ministry of Construction and Transportation, Kwachon, Republic of Korea. p 18
Muller G (1969) Index of geo-accumulation in the sediments of the Rhine River. Geo-journal 2:108–118
Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49
Nriagu JO (1996) A history of global metal pollution. Science 272:223–224
Nriagu JO, Pacyna JM (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace-metals. Nature 333:134–139
Oh GH (1994) The paleoenvironment of the northern part of the Nakdong River delta. Korean J Quat Res 8:33–42
Pache T, Brockamp O, Clauer N (2008) Varied pathways of river-borne clay minerals in a near-shore marine region: a case study of sediments from the Elbe- and Weser rivers, and the SE North Sea. Estuar Coast Shelf Sci 78:563–575
Panda UC, Sundaray SK, Rath P, Nayak BB, Bhatta D (2006) Application of factor and cluster analysis for characterization of river and estuarine water systems—a case study: Mahanadi River (India). J Hydrol 331:434–445
Peierls BL, Caraco NF, Pace ML, Cole JJ (1998) Human influence on river nitrogen. Nature 350:386–387
Pekey H, Karakas D, Ayberk S, Tolun L, Bakoglu M (2004) Ecological risk assessment using trace elements from surface sediments of Izmit Bay (Northeastern Marmara Sea) Turkey. Mar Pollut Bull 48:946–953
Ryu CK, Kang S, Chung SG, Jeon YM (2011) Late Quaternary depositional environmental change in the northern marginal area of the Nakdong River delta, Korea. J Geol Soc Korea 47:213–233
Salomons W, Forstner U (1984) Metals in hydro-cycle. Springer, Berlin, pp 63–98
Santhiya G, Lakshumanan C, Jonathan MP, Roy PD, Navarrete-Lopaz M, Srnivasalu S, Uma-Maheswari B, Krishnakumar P (2011) Metal enrichment in beach sediments from Chennai Metropolis, SE coast of India. Mar Pollut Bull 62:2537–2542
Savvides C, Papadopoulos A, Haralambous KJ, Loizidou M (1995) Sea sediments contaminated with heavy metals: metal speciation and removal. Water Sci Technol 32:65–73
Simeonova P, Simeonov V (2007) Chemometrics to evaluate the quality of water sources for human consumption. Microchim Acta 156:315–320
Soylak M, Yilmaz S (2006) Heavy metal levels in sediment samples from Lake Palas, Kayseri-Turkey. Fresenius Environ Bull 15:340–344
Tariq SR, Shaheen N, Khalique A, Sha MH (2010) Distribution, correlation, and source apportionment of selected metals in tannery effluents, related soils, and groundwater—a case studies from Multan, Pakistan. Environ Monit Assess 166:303–312
Taylor SR, McLennan SM (1995) The geochemical evolution of the continental crust. Rev Geophys 58:241–265
Tomlinson DL, Wilson JG, Harris CR, Jeffrey DW (1980) Problems in the assessment of heavy metal levels in estuaries and the formation of a pollution index. Helgol Meeresunters 63:566–575
Tuzen M, Sari H, Soylak M (2004) Microwave and wet digestion procedures for atomic absorption spectrometric determination of trace metals contents of sediment samples. Anal Lett 37:1925–1936
United States Environmental Protection Agency (USEPA) (2001) The role of screening-level risk assessments and refining contaminants of concern in Baseline ecological risk assessments, Publication 9345 0–14, EPA 540/F-01/14, June 2001
Venkatramanan S, Ramkumar T, Anithamary I, Vasudevan S (2012) Heavy metal distribution in surface sediments of the Tirumalairajan river estuary and the surrounding coastal area, east coast of India. Arab J Geosci 7:123–130
Venkatramanan S, Chung SY, Lee SY, Park N (2014) Assessment of river water quality via environmentric multivariate statistical tools and water quality index: a case study of Nakdong River Basin, Korea. Carpathian J Earth Environ Sci 9:125–132
Venkatramanan S, Chung SY, Ramkumar T, Gnanachandrasamy G, Kim TH (2015) Evaluation of geochemical behavior and heavy metal distribution of sediments: the case study of the Tirumalairajan river estuary, southeast coast of India. Int J Sedim Res 30:28–38
Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59:1217–1232
Yalcin MG, Narin I, Solylak M (2008) Multivariate analysis of heavy metal contents of sediments from Gumusler creek, Nigde, Turkey. Environ Geol 54:1155–1163
Yang Z, Wang Y, Shen Z, Niu J, Tang Z (2009) Distribution and speciation of heavy metals in sediments from the mainstream, tributaries, and lakes of the Yangtze River catchment of Wuhan, China. J Hazard Mater 166:1186–1194
Zhang J, Liu CL (2002) Riverine composition and estuarine chemistry of particulate metals in China – weathering features, anthropogenic impact and chemical fluxes. Estuar Coast Shelf Sci 54:1051–1070
Acknowledgments
This research was supported by a grant (code 15AWMP-B066761-03) from AWMP Program funded by Ministry of Land, Infrastructure and Transport of Korean government. The chemical data of the Nakdong River water and sediment were supplied by the Busan Metropolitan City. The authors express a sincere gratitude to the Busan Metropolitan City.
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Chung, S.Y., Venkatramanan, S., Park, N. et al. Evaluation of physico-chemical parameters in water and total heavy metals in sediments at Nakdong River Basin, Korea. Environ Earth Sci 75, 50 (2016). https://doi.org/10.1007/s12665-015-4836-2
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DOI: https://doi.org/10.1007/s12665-015-4836-2