Abstract
Sediment cores from the Dashiwei Tiankeng reach of the Bailang underground river were collected and analyzed for polycyclic aromatic hydrocarbons (PAHs). The concentrations of total PAHs ranged from 35.34 to 280.17 ng/g (mean 107.65 ng/g), and the concentrations of benzo[a]pyrene ranged from 1.78 to 175.74 ng/g (mean 35.94 ng/g). Analyses on molecular markers inferred that the PAHs were sourced mainly from wood and coal combustion before 1998, but there were obvious petroleum and petroleum combustion inputs after 1999. The PAHs profile indicated that the Bailang underground river was polluted by two major events. One was steel smelting in the 1950s, and the other was rapid economic development in the 1990s. The relationship between the PAHs and the sediment organic matter (SOM) in the profile was negative. Factors that impacted the SOM contents in sediment core included vegetation, agriculture crops, wood and fossil fuel burning, and soil erosion caused by construction. The sediment cores from the Bailang underground river reflected the economic development of the region.
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References
Baumard P, Budzinski H, Garrigue P (1998) Polycyclic aromatic hydrocarbons in sediments and mussels of the western Mediterranean Sea. Environ Toxicol Chem 17:765–776
Budzinski H, Jones I, Bellocq C, Pie´rard C, Garrigues P (1997) Evaluation of sediment contamination by polycyclic aromatic hydrocarbons in the Gironde estuary. Mar Chem 58:85–97
Choi WW, Chen KY (1976) Associations of chlorinated hydrocarbons with fine particles and humic substances in nearshore surficial sediments. Environ Sci Technol 10(8):782–786
Guo-qing Liu, Gan Zhang, Jun Li, Ke-chang Li, Ling-li Guo, Xiang Liu, Ji-song Chi, Xian-zhi Peng, Shi-hua Qi (2005) Over one hundred year sedimentary record of polycyclic aromatic hydrocarbons in the Pearl River Estuary, South China. Environ Sci 26(3):141–145
He CH, Wang ZY (2008) Cave environments and cave tourist. In: Chen W, Zhu D, Zhu X (eds) Cave exploration, research, exploitation and protection. Geological Publishing Press, Beijing, pp 320–322
IARC (International Agency for Research on Cancer) (1991) Monographs on the evaluation of carcinogenic risks to humans. Lyon, 43–53
Kang Y, Sheng G, Li F, Wang Z, Fu J (2005) Depositional history record of polycyclic aromatic hydrocarbons in core sediments from Pearl River estuary China. Acta Scientiaecir Cumstantiae 25(1):63–69
Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprints for coke oven, diesel and gasoline engines, highway tunnel, and wood combustion emission. Atmos Environ 29:533–542
Kong X, Qi S, Oramah IT, Huang B, Zhang Y (2011) Contaminant and sources of polycyclic aromatic hydrocarbons in sediments from Bailang underground river in karst area, Guangxi. Environ Sci Technol 34(8):42–48
Kong X, Qi S, Huang B, Zhang Y, Li J (2012a) Atmospheric deposition of PAHs in Dashiwei Karst Tiankeng Group in Leye, Guangxi. Environ Sci 33(3):746–753
Kong X, Qi S, Jiang Z, Huang B (2012b) Environmental factors on distributions of polycycli aromatic hydrocarbons in soils from Dashiwei Karst Giant Doline (Tiankeng) in Guangxi, China. Environ Sci 33(11):221–231
Lin RF, Min YS, Wei KQ, Zhang G, Yu F, Yu Y (1998) 210Pb-dating of sediment cores from the Pearl River mouth and its environmental geochemistry implication. Geochimia 27(5):401–411
Liu J, Qi S, Zhang G, Donyinah SK, Liu X, Li J, Liu G (2004) Response of the n-alkanes and polycyclic aromatic hydrocarbons records in sediment from Lake Liangzi to environmental change. Geochemica 33(5):501–506
Luo X, Liu C, He M (2004) Sorption of polycyclic aromatic hydrocarbons (PAHs) by soils and sediments: a review. Ecol Environ 13(3):394–398
Menzie CA, Potocki BP, Santodonato J (1992) Ambient concentration and Exposure to carcinogenic PAHs in the environment. Environ Sci Technol 26(7):1278–1284
Song J, Yu C, Peng P, Huang W (2003) The characterization and structure of soil and sediments organic matter in pearl river delta. Acta Pedol Sin 40:335–343
Tang G (1993) Review on methods to identify sources of PAH in aerosol. Res Environ Sci 6(3):37–41
Wu Y, Zhang J (2001) Distribution of polycyclic aromatic hydrocarbon in core sediments of the Bohai straight. Environ Sci 22(3):74–77
Xu S, Liu W, Tao S (2006) Emission of polycyclic aromatic hydrocarbons in China. Environ Sci Technol 40(3):702–708
Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Org Geochem 33:489–515
Zhu L (2002) Leye County annals. Guangxi People Publishing Press, Nanning
Zhu XW, Huang BJ, Zhu DH, Chen WH (2003) Dashiwei, tiankenggroup, LeYe, Guangxi discoveries exploration, definition and research. Guangxi Science and Technology Publishing Press, Nanning, pp 1–17
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This study was funded by the China Geological Survey (Grant No.1212011121166) and the National Natural Science Foundation of China (Grant No. 40473043).
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Kong, Xs., Luan, Rj., Miao, Y. et al. Polycyclic aromatic hydrocarbons in sediment cores from the Dashiwei Tiankeng reach in the Bailang underground river, South China. Environ Earth Sci 73, 5535–5543 (2015). https://doi.org/10.1007/s12665-014-3807-3
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DOI: https://doi.org/10.1007/s12665-014-3807-3