Skip to main content
Log in

Chaotic Transport in Three-Dimensional Reactors Operating in Open Flows for Continuous Biodiesel Production from Rapeseed Oil: Numerical and Experimental Comparative Study

  • Original Paper
  • Published:
Waste and Biomass Valorization Aims and scope Submit manuscript

Abstract

The present study aims to investigate a suitable biodiesel production process. Two reactors called serpentin-3D (S-3D) and New-Serpentin-3D (NS-3D), operating in continuous mode, are used to produce biodiesel. The thermal and dynamic characterizations of both reactors are numerically examined for several Reynolds number values. In addition, the conversion of the rapeseed oil to biodiesel is experimentally performed by the transesterification reaction. Numerical results showed a better quality of thermal mixing using NS-3D geometry where the degree of mixing is close to 1 for miscible and immiscible fluids. The experimental study illustrates that the conversion rate, using the reactor based on NS-3D geometry, is about 99%. Moreover, the properties of the biodiesel are in compliance with the required standard EN14214 (MG = 0.7 20 % m/m, DG = TG = 0.2 % m/m). Therefore, the NS-3D geometry could present a better alternative for the continuous production of biodiesel.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

Data Availability

Enquiries about data availability should be directed to the authors.

Reference

  1. Noureddini, H., Zhu, D.: Kinetics of transesterification of soybean oil. J. Am. Oil Chem. Soc. 74, 1457–63 (1997). https://doi.org/10.1007/s11746-997-0254-2

    Article  Google Scholar 

  2. Stamenković, O.S., Lazić, M.L., Todorović, Z.B., Veljković, V.B., Skala, D.U.: The effect of agitation intensity on alkali-catalyzed methanolysis of sunflower oil. Bioresour. Technol. (2007). https://doi.org/10.1016/j.biortech.2006.09.024

    Article  Google Scholar 

  3. Thakur, R.K., Vial, C., Nigam, K.D.P., Nauman, E.B., Djelveh, G.: Static mixers in the process industriesða review. Chem. Eng. Res. Des. 81, 787–826 (2003)

    Article  Google Scholar 

  4. Sungwornpatansakul, P., Hiroi, J., Nigahara, Y., Jayasinghe, T.K., Yoshikawa, K.: Enhancement of biodiesel production reaction employing the static mixing. Fuel Process. Technol. 116, 1–8 (2013). https://doi.org/10.1016/j.fuproc.2013.04.019

    Article  Google Scholar 

  5. Likozar, B., Pohar, A., Levec, J.: Transesteri fi cation of oil to biodiesel in a continuous tubular reactor with static mixers : modelling reaction kinetics, mass transfer, scale-up and optimization considering fatty acid composition. Fuel Process. Technol. 142, 326–36 (2016). https://doi.org/10.1115/1.4030288

    Article  Google Scholar 

  6. Zhou, T., Xu, Y., Liu, Z., Joo, S.W.: An enhanced one-layer passive microfluidic mixer with an optimized lateral structure with the Dean effect. J. Fluids Eng. 137, 091102 (2015)

    Article  Google Scholar 

  7. Thompson, J.C., He, B.B.: Biodiesel production using static mixers. Trans. ASABE 50, 161–5 (2007). https://doi.org/10.13031/2013.22389

    Article  Google Scholar 

  8. Boucher, M.B., Weed, C., Leadbeater, N.E., Wilhite, B.A., Stuart, J.D., Parnas, R.S.: Pilot scale two-phase continuous flow biodiesel production via novel laminar flow reactor: separator. Energy and Fuels 23, 2750–6 (2009). https://doi.org/10.1021/ef9000049

    Article  Google Scholar 

  9. Somnuk, K., Smithmaitrie, P., Prateepchaikul, G.: Optimization of continuous acid-catalyzed esterification for free fatty acids reduction in mixed crude palm oil using static mixer coupled with high-intensity ultrasonic irradiation. Energy Convers. Manag. 68, 193–9 (2013). https://doi.org/10.1016/j.enconman.2013.01.016

    Article  Google Scholar 

  10. Mostafaei, M., Ghobadian, B., Barzegar, M., Banakar, A.: Optimization of ultrasonic assisted continuous production of biodiesel using response surface methodology. Ultrason. Sonochem. 27, 54–61 (2015). https://doi.org/10.1016/j.ultsonch.2015.04.036

    Article  Google Scholar 

  11. Somnuk, K., Prasit, T., Prateepchaikul, G.: Effects of mixing technologies on continuous methyl ester production: comparison of using plug flow, static mixer, and ultrasound clamp. Energy Convers. Manag. 140, 91–7 (2017). https://doi.org/10.1016/j.enconman.2017.02.066

    Article  Google Scholar 

  12. Kobayashi, J., Mori, Y., Kobayashi, S.: Multiphase organic synthesis in microchannel reactors. Chem.-An Asian J. 1, 22–35 (2006). https://doi.org/10.1002/asia.200600058

    Article  Google Scholar 

  13. Wen, Z., Yu, X., Tu, S.T., Yan, J., Dahlquist, E.: Intensification of biodiesel synthesis using zigzag micro-channel reactors. Bioresour. Technol. (2009). https://doi.org/10.1016/j.biortech.2009.01.022

    Article  Google Scholar 

  14. Boukhalkhal, A.L., Kadi, M.E.A., Lasbet, Y., Loubar, K., Awad, S., Makhlouf, M., et al.: A continuous biodiesel production process using a chaotic mixer-reactor. Waste and Biomass Valorization (2019). https://doi.org/10.1007/s12649-019-00880-x

    Article  Google Scholar 

  15. Kadi, M.E.A., Awad, S., Loubar, K., Akkouche, N., Tazerout, M.: Experimental study on the esterification of fat trap grease in a continuous reactor. Waste and Biomass Valorization (2019). https://doi.org/10.1007/s12649-019-00905-5

    Article  Google Scholar 

  16. Hirt, C.W.: Volume of fluid (VOF) method for the dynamics of free boundaries. J. Comput. Phys. 225, 201–25 (1981)

    Article  MATH  Google Scholar 

  17. Lasbet, Y., Auvity, B., Castelain, C., Peerhossaini, H.: Thermal and hydrodynamic performances of chaotic mini-channel: application to the fuel cell cooling. Heat Transf. Eng. 28, 795–803 (2007). https://doi.org/10.1080/01457630701328908

    Article  Google Scholar 

  18. Liu, Y.Z., Kim, B.J., Sung, H.J.: Two-fluid mixing in a microchannel. Int. J. Heat Fluid Flow (2004). https://doi.org/10.1016/j.ijheatfluidflow.2004.03.006

    Article  Google Scholar 

  19. Cook, K.J., Fan, Y.F., Hassan, I.: Mixing evaluation of a passive scaled-up serpentine micromixer with slanted grooves. J. Fluids Eng. Trans. ASME 135, 1–12 (2013). https://doi.org/10.1115/1.4024146

    Article  Google Scholar 

  20. Boukhalkhal, A.L., Lasbet, Y., Makhlouf, M., Loubar, K.: A publication of IIETA numerical study of the chaotic flow in three-dimensional open geometry and its effect on the both fluid mixing and heat performances. Int. J. Heat Technol. 35, 1–10 (2017). https://doi.org/10.18280/ijht.350101

    Article  Google Scholar 

  21. Lasbet, Y., Aidaoui, L., Loubar, K.: Effects of the geometry scale on the behaviour of the local physical process of the velocity field in the laminar flow. Int. J. Heat Technol. 34, 439–45 (2016). https://doi.org/10.18280/ijht.340313

    Article  Google Scholar 

  22. Kadi, M.A., Akkouche, N., Awad, S., Loubar, K., Tazerout, M.: Heliyon kinetic study of transesterification using particle swarm optimization method. Heliyon 5, e02146 (2019). https://doi.org/10.1016/j.heliyon.2019.e02146

    Article  Google Scholar 

  23. Billo, R.E., Oliver, C.R., Charoenwat, R., Dennis, B.H., Wilson, P.A., Priest, J.W., et al.: A cellular manufacturing process for a full-scale biodiesel microreactor. J. Manuf. Syst. 37, 409–16 (2015). https://doi.org/10.1016/j.jmsy.2014.07.004

    Article  Google Scholar 

  24. Lopes, M.G.M., Santana, H.S., Andolphato, V.F., Russo, F.N., Silva, J.L., Taranto, O.P.: 3D printed micro-chemical plant for biodiesel synthesis in millireactors. Energy Convers. Manag. 184, 475–87 (2019). https://doi.org/10.1016/j.enconman.2019.01.090

    Article  Google Scholar 

Download references

Funding

The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

Author information

Authors and Affiliations

Authors

Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by MEAK and ALB. The first draft of the manuscript was written by MEAK, ALB and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to A. L. Boukhalkhal.

Ethics declarations

Competing Interests

The authors have no relevant financial or non-financial interests to disclose.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kadi, M.E.A., Boukhalkhal, A.L., Loubar, K. et al. Chaotic Transport in Three-Dimensional Reactors Operating in Open Flows for Continuous Biodiesel Production from Rapeseed Oil: Numerical and Experimental Comparative Study. Waste Biomass Valor 14, 2285–2298 (2023). https://doi.org/10.1007/s12649-022-02025-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12649-022-02025-z

Keywords

Navigation