Abstract
Over the past decade, the definition of self-healing to repair and restore mechanical properties is being popularized for engineering applications. The investigation of self-healing composite materials is inspired by biological or natural systems in which damage prompts the healing process. The present study focuses on the development of E-glass fiber reinforced self-healing composite materials and the investigation of self-healing efficiency using silica (SiO2) based hollow glass fibers (HGFs). The finite element methodology (FEM) based structural model is also developed to study analytical aspects of developed composite material. It identifies the stress distributions which are used to estimate the crack propagation inside the composite material. FEM results are also utilized to predict the damaged loads for triggering the self-healing mechanism by bursting out the HGFs. FEM results revealed that crack propagates from the point of loading and damages the silica (SiO2) based hollow fibers. The experimental investigation includes the fabrication of composites with E-glass as a reinforcement, HGFs as a healing agent carrier, and epoxy resin as a matrix binder. Virgin, damaged, and healed specimens are tested under Impact and Flexure loading to evaluate the restoration of mechanical properties in terms of healing efficiency. Experimental results revealed that restoration of mechanical properties with a percentage increase of 58% in impact strength and a percentage increase of 36% in flexural strength is observed when compared with virgin composite. A major advantage of this study is the fact that the healing is found to be localized which further allows multiple healing of the composite material in the presence of several cracks at a different location.
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References
Kessler MR (2012) Polymer matrix composites: a perspective for a special issue of polymer reviews. Polym Rev 52(3):229–233
Bleay SM, Loader CB, Hawyes VJ, Humberstone L, Curtis PT (2001) A smart repair system for polymer matrix composites. Compos Part A: Appl Sci Manufac 32(12):1767–1776
Brown EN, Kessler MR, Sottos NR, White SR (2003) In situ poly (urea-formaldehyde) microencapsulation of dicyclopentadiene. J Microencapsul 20(6):719–730
Pang JW, Bond IP (2005) A hollow fibre reinforced polymer composite encompassing self-healing and enhanced damage visibility. Compos Sci Technol 65(11–12):1791–1799
Bekas DG, Tsirka K, Baltzis D, Paipetis AS (2016) Self-healing materials: a review of advances in materials, evaluation, characterization and monitoring techniques. Compos Part B: Eng 87:92–119
Zhang L, Wang H, He F, Chen H, Xie G, Wei B, Wu Z (2022) Wear in-situ self-healing polymer composites incorporated with bifunctional microcapsules. Compos Part B: Eng 232:109566
Trask RS, Bond IP (2006) Biomimetic self-healing of advanced composite structures using hollow glass fibres. Smart Mater Struct 15(3):704
Xue C, Li W, Li J, Tam VW, Ye G (2019) A review study on encapsulation-based self‐healing for cementitious materials. Struct Concrete 20(1):198–212
Hansen CJ, Wu W, Toohey KS, Sottos NR, White SR, Lewis JA (2009) Self-healing materials with interpenetrating microvascular networks. Adv Mater 21(41):4143–4147
Shields Y, De Belie N, Jefferson A, Van Tittelboom K (2021) A review of vascular networks for self-healing applications. Smart Mater Struct 30(6):063001
Yuan YC, Rong MZ, Zhang MQ, Chen J, Yang GC, Li XM (2008) Self-healing polymeric materials using epoxy/mercaptan as the healant. Macromolecules 41(14):5197–5202
Khan NI, Halder S (2020) Self-healing fiber-reinforced polymer composites for their potential structural applications. In Self-healing polymer-based systems. Elsevier, Amsterdam, pp 455–472. https://doi.org/10.1016/B978-0-12-818450-9.00015-5
Ding Z, Yuan L, Guan Q, Gu A, Liang G (2018) A reconfiguring and self-healing thermoset epoxy/chain-extended bismaleimide resin system with thermally dynamic covalent bonds. Polymer 147:170–182
Idumah CI, Hassan A, Affam AC (2015) A review of recent developments in flammability of polymer nanocomposites. Rev Chem Eng 31(2):149–177
Kassner ME, Nemat-Nasser S, Suo Z, Bao G, Barbour JC, Brinson LC, Van Swol F (2005) New directions in mechanics. Mech Mater 37(2–3):231–259
Blaiszik BJ, Kramer SL, Olugebefola SC, Moore JS, Sottos NR, White SR (2010) Self-healing polymers and composites. Annu Rev Mater Sci 40:179–211
Islam S, Bhat G (2021) Progress and challenges in self-healing composite materials. Mater Adv 2(6):1896–1926
Vijay K, Murmu M, Deo SV (2017) Bacteria based self-healing concrete–A review. Constr Build Mater 152:1008–1014. https://doi.org/10.1016/j.conbuildmat.2017.07.040
Pappupreethi K, Ammakunnoth R, Magudeaswaran P (2017) Bacterial concrete: a review. Int J Civil Eng Technol 8(2):588–594
Nodehi M, Ozbakkaloglu T, Gholampour A (2022) A systematic review of bacteria-based self-healing concrete: biomineralization, mechanical, and durability properties. J Building Eng 49:104038. https://doi.org/10.1016/j.jobe.2022.104038
Dry C (1990) Alteration of matrix permeability, pore and crack structure by the time release of internal chemicals. In: Proceedings of the ACS/NIST Conference on Advances in Cementitious Material, American Ceramic Society, co-sponsored by National Institute of Standards and Technology, Gaithersburg, Maryland, vol. 768
Dry C (1994) Matrix cracking repair and filling using active and passive modes for smart timed release of chemicals from fibers into cement matrices. Smart Mater Struct 3(2):118
Dry C, McMillan W (1996) Three-part methyl methacrylate adhesive system as an internal delivery system for smart responsive concrete. Smart Mater Struct 5(3):297
Kshirsagar P, Jarali CS, Raja S. Investigation on flexural and impact strength of hollow glass fabric and e-glass fiber reinforced self-healing polymer composites. Compos: Mech Comput Appl Int J 13(4):41–56. https://doi.org/10.1615/CompMechComputApplIntJ.2022043799
Motuku MJGM, Vaidya UK, Janowski GM (1999) Parametric studies on self-repairing approaches for resin infused composites subjected to low velocity impact. Smart Mater Struct 8(5):623
Escobar MM, Vago S, Vázquez A (2013) Self-healing mortars based on hollow glass tubes and epoxy–amine systems. Compos Part B: Eng 55:203–207. https://doi.org/10.1016/j.compositesb.2013.06.023
Li VC, Lim YM, Chan YW (1998) Feasibility study of a passive smart self-healing cementitious composite. Compos Part B: Eng 29(6):819–827
Burgman JA (1965), September Hollow glass fibers. In: Symposium on polymers in construction. American Chemical Society, Atlantic City, pp 12–17
Trask RS, Williams GJ, Bond IP (2007) Bioinspired self-healing of advanced composite structures using hollow glass fibres. J R Soc Interface 4(13):363–371. https://doi.org/10.1098/rsif.2006.0194
Rajput V, Goud M, Samir S (2017) A review of developments in the self-healing approaches of composite materials. Int J Mech Eng Technol 8:1699–1709
Nagori I, Goud M, Rajput V (2019) Self-Healing Composite Materials: a review on Preceding and Perspective Research. Int J Tec Innov Mod Eng Sci 5(5):687–697
Pang JWC, Bond IP (2005) Bleeding composites’—damage detection and self-repair using a biomimetic approach. Compos Part A: Appl Sci Manufac 36(2):183–188
Fu SY, Lauke B, Mai YW (2019) Science and engineering of short fibre-reinforced polymer composites. Woodhead Publishing, Sawston
Manera M (1977) Elastic properties of randomly oriented short fiber-glass composites. J Compos Mater 11(2):235–247
El Messiry M (2013) Theoretical analysis of natural fiber volume fraction of reinforced composites. Alexandria Eng J 52(3):301–306
Tan PS, Somashekar AA, Casari P, Bhattacharyya D (2019) Healing efficiency characterization of self-repairing polymer composites based on damage continuum mechanics. Compos Struct 208:367–376
Scheiner M, Dickens TJ, Okoli O (2016) Progress towards self-healing polymers for composite structural applications. Polymer 83:260–282
Acknowledgements
The authors acknowledge the support and assistance given by the Punjab Engineering College & SAIF/CIL, Panjab University Chandigarh, India.
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Viveksheel Rajput & Imran Nagori performed the experimentation, performed significant analysis, and wrote the manuscript. Mudimallana Goud & Narendra Mohan Suri contributed towards the manuscript conception and methodology, Jasdeep Bhinder contributed in the preparation of the results & conclusions, Ganga Ram Chaudhary contributed towards the final editing & proof reading of the manuscript.
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Rajput, V., Nagori, I., Goud, M. et al. Development and Analysis of Polymer-Based Self-Healing Composite Embedded with Silica (SiO2) Hollow Glass Fibers. Silicon 15, 7279–7292 (2023). https://doi.org/10.1007/s12633-023-02574-5
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DOI: https://doi.org/10.1007/s12633-023-02574-5